全文获取类型
收费全文 | 110607篇 |
免费 | 3253篇 |
国内免费 | 1526篇 |
专业分类
电工技术 | 2323篇 |
技术理论 | 4篇 |
综合类 | 3781篇 |
化学工业 | 16253篇 |
金属工艺 | 6039篇 |
机械仪表 | 4613篇 |
建筑科学 | 3986篇 |
矿业工程 | 1251篇 |
能源动力 | 1974篇 |
轻工业 | 5385篇 |
水利工程 | 1688篇 |
石油天然气 | 1801篇 |
武器工业 | 191篇 |
无线电 | 12808篇 |
一般工业技术 | 19931篇 |
冶金工业 | 3916篇 |
原子能技术 | 530篇 |
自动化技术 | 28912篇 |
出版年
2024年 | 66篇 |
2023年 | 387篇 |
2022年 | 688篇 |
2021年 | 1052篇 |
2020年 | 792篇 |
2019年 | 745篇 |
2018年 | 15092篇 |
2017年 | 14108篇 |
2016年 | 10688篇 |
2015年 | 1577篇 |
2014年 | 1594篇 |
2013年 | 1926篇 |
2012年 | 4804篇 |
2011年 | 11251篇 |
2010年 | 9784篇 |
2009年 | 7018篇 |
2008年 | 8225篇 |
2007年 | 9138篇 |
2006年 | 1509篇 |
2005年 | 2511篇 |
2004年 | 1988篇 |
2003年 | 2024篇 |
2002年 | 1334篇 |
2001年 | 807篇 |
2000年 | 889篇 |
1999年 | 793篇 |
1998年 | 700篇 |
1997年 | 583篇 |
1996年 | 547篇 |
1995年 | 397篇 |
1994年 | 368篇 |
1993年 | 271篇 |
1992年 | 223篇 |
1991年 | 182篇 |
1990年 | 147篇 |
1989年 | 112篇 |
1988年 | 96篇 |
1987年 | 53篇 |
1986年 | 47篇 |
1985年 | 39篇 |
1982年 | 37篇 |
1968年 | 44篇 |
1966年 | 43篇 |
1965年 | 45篇 |
1959年 | 35篇 |
1958年 | 38篇 |
1957年 | 36篇 |
1956年 | 34篇 |
1955年 | 63篇 |
1954年 | 68篇 |
排序方式: 共有10000条查询结果,搜索用时 15 毫秒
81.
82.
Production by N-nitroso compounds of O6-alkylguanine (O6-alkylG) in DNA directs the misincorporation of thymine during DNA replication, leading to G:C to A:T transition mutations, despite the fact that DNA containing O6-alkylG:T base pairs is less stable than that containing O6-alkylG:C pairs. We have examined the kinetics of incorporation by Klenow fragment (KF) of Escherichia coli DNA polymerase I of thymine (T) and of cytosine (C) opposite O6-MeG in the template DNA strand. Both T and C were incorporated opposite O6-MeG much slower than nucleotides forming regular A:T or G:C base pairs. Using various concentrations of dTTP, dCTP, or their phosphorothioate (Sp)-dNTP alpha S analogues, or a mixture of dTTP and dCTP, the progress of incorporation of a single nucleotide in a single catalytic cycle of a preformed KF-DNA complex was measured (pre-steady-state kinetics). The results were consistent with the kinetic scheme (Kuchta, R. D., Benkovic, P., & Benkovic, S. J. (1988) Biochemistry 27, 6716-6725): (1) binding of dNTP to polymerase-DNA; (2) conformational change in polymerase; (3) formation of phosphodiester between the dNTP and the 3'-OH of the primer; (4) conformational change of polymerase; (5) release of pyrophosphate. The results were analyzed mathematically to identify the steps at which the rate constants differ significantly between the incorporation of T and C. The only significant difference was the 5-fold difference in the rates of formation of the phosphodiester bond (for dTTP, kforward = 3.9 s-1 and kback = 1.9 s-1; for dCTP, kforward = 0.7 s-1 and kback = 0.9 s-1). These pre-steady-state progress curves were biphasic with a rapid initial burst followed by an apparently steady-state rise. Deconvolution of these curves gave direct evidence for the importance of the conformational change after polymerization by showing that the curves represented the sum of the rapid accumulation of the product of step 3 followed by the slow conversion of that to the product of step 5 (because of the rapidity of the release of pyrophosphate there was no significant accumulation of the product of step 4). The equilibrium constants for each step suggest that the greatest change in the Gibbs free energy occurs at the conformational change after polymerization and that while the formation of the phosphodiester bond to T is slightly exothermic, that to C is slightly endothermic.(ABSTRACT TRUNCATED AT 400 WORDS) 相似文献
83.
本文对采用区内C/I平衡的多区蜂窝CDMA系统下行链路的性能进行分析,给出两种区内C/I平衡算法并比较它们的性能,考虑呈对数正态分布的阴影和R^-4规律的路径损失的综合影响,采用与传统不同的小区平均中断概率来评价系统的性能。 相似文献
84.
锗γ能谱测量中的符合相加修正 总被引:4,自引:1,他引:3
本文介绍了锗γ能谱测量中符合相加修正的原理和方法,给出了修正公式。分别计算了不同几何条件下两个锗探测器对一些放射性核素的符合相加修正因子,估计了符合相加修正因子对活度测量结果的误差贡献。 相似文献
85.
Certain new sulfide-smelting processes and coal-gasification processes generate high-strength sulfur dioxide streams, for
which a new process for converting sulfur dioxide to elemental sulfur needs to be developed because no process exists that
is generally and economically applicable to the treatment of such streams. A thermodynamic and experimental investigation
to develop a new process for converting sulfur dioxide to elemental sulfur by a cyclic process involving calcium sulfide and
calcium sulfate without generating secondary pollutants was carried out. In this process, the starting raw material, calcium
sulfate, is reduced by a suitable reducing agent, such as hydrogen, to produce calcium sulfide, which is used to reduce sulfur
dioxide to elemental sulfur vapor and calcium sulfate. The latter is, in turn, reduced to regenerate calcium sulfide. In this
Part I, detailed experimental results are presented on the kinetics of the reaction between sulfur dioxide and calcium-sulfide
pellets, which produces elemental sulfur and calcium sulfate. The experiments were carried out at temperatures between 1023
and 1088 K and sulfur-dioxide partial pressures between 9 and 60 kPa by the use of a thermogravimetric analysis (TGA) technique.
The rate of this reaction was demonstrated by the conversion of 40 pct calcium-sulfide pellets obtained from the hydrogen
reduction of fresh calcium sulfate in 10 minutes at 1073 K under a sulfur-dioxide partial pressure of 43 kPa. The reactivity
decreased somewhat during the first three cycles but remained largely unchanged thereafter up to the tenth cycle. This characteristic
of the pellets is important because the solids must be reusable for repeated cycles to avoid generating secondary pollutants.
A pore-blocking model was found to fit the reaction rate. The reaction is first order with respect to sulfur-dioxide partial
pressure and has an activation energy of 101 to 134 kJ/mol (24 to 32 kcal/mol) for calcium-sulfide pellets reacted and regenerated
several different times. Sulfur dioxide-containing streams from certain sources, such as the regenerator off-gas from an integrated-gasification,
combined-cycle, desulfurization unit and new sulfide-smelting plants, contain much higher partial pressures of SO2. In these cases, the rate of the first reaction is expected to be proportionally higher than in the test conditions reported
in this article. The reduction kinetics of calcium-sulfate pellets with hydrogen gas is reported in the accompanying Part
II. 相似文献
86.
对国产加氢裂化热高分油管线的弯头开裂原因进行了分析 ,对预防连多硫酸腐蚀提出了相应的防范措施 :选用碳含量 <0 .0 3 %并含有稳定化元素Ti、Nb的奥氏体不锈钢或双相钢 ;控制焊缝硬度不大于HB2 0 0并焊后热处理 ;12CrMo和 15CrMo耐应力腐蚀性能好 ;设备停运后马上进行清洗并用碱液中和 相似文献
87.
Microbiological denitrification of red beet juice 总被引:1,自引:0,他引:1
Dorota Walkowiak-Tomczak 《European Food Research and Technology》2002,215(5):401-406
The purpose of study was the determination of optimal conditions for red beet juice denitrification by Paracoccus denitrificans bacteria as well as the evaluation of the usefulness of microbiologically treated juice for the production of a natural colouring preparation for foods. Total reduction of nitrates was found during bacterial culturing at 25 and 30 °C, at an initial pH of 7.0-8.0 and juice osmotic pressure of 900-1100 mOsm/kg. Microbiological denitrification procedure affected colour, taste and aroma of the juice. However, the use of juice as food colouring and component was made feasible by acidification and partial evaporation of water together with volatile substances. 相似文献
88.
89.
90.
George Ter-Stepanian 《Bulletin of Engineering Geology and the Environment》2002,61(3):197-205
The paper discusses the postulated suspension force, by which it is possible to explain some enigmatic phenomena observed
in different types of mass movements. This force is generated in thick suspensions as a result of friction between sinking
solid particles and static water. The suspension force is related to the seepage force but they have opposite directions.
Both forces form flow networks. Having explained the suspension force, the paper describes how this influences the movement
of material, particularly in debris flows. Enigmatic features and the mechanism of debris flows and lahars are explained by
virtue of the suspension force.
Electronic Publication 相似文献