Leakage current in a Si-based nanopore structure and its influence on noise characteristics

We have measured leakage current in a silicon substrate-based nanopore membrane device immersed in an aqueous environment which typically shows the current level of few nA. This current level is compared with the measured current density (400 nA/cm² at 1 V) from the pristine Si wafer (p-type, 10¹⁶/cm³ boron doping) indicating that the exposed Si surface in a nanopore membrane device acts as an electrochemical reaction site. The leakage current is drastically reduced from >10 nA to <100 pA at 1 V by the deposition of a dielectric layer to the Si-based nanopore membrane device. We also noted that the root-mean-square noise of the ionic current is also reduced from 38 to 28 pA in correlation with the reduction of leakage current, indicating that electrochemical reaction provides one of the major sources of noise.     

A strain based topology optimization method for compliant mechanism design

The Energy based topology optimization method has been used in the design of compliant mechanisms for many years. Although many successful examples from the energy based topology optimization method have been presented, optimized configurations of these designs are often very similar to their rigid linkage counterparts; except using compliant joints in place of rigid links. These complaint joints will endure large strain under the applied forces in order to perform the specified motions which are very undesirable in a compliant mechanism design. In this paper, a strain based topology optimization method is proposed to avoid a localized high strain of the compliant mechanism design, which is one of the drawbacks using strain energy formulation. Therefore, instead of minimizing the strain energy for structural rigidity, a global effective strain function is minimized. This is done in order to distribute the strain within the entire mechanism while maximizing the structural rigidity. Furthermore, the physical programming method is adopted to accommodate both flexibility and rigidity design objectives. Design examples from both the strain energy based topology optimization and the strain based method are presented and discussed.     

Multiple categorizations of products: cognitive modeling of customers through social media data mining

As various forms of social media are spreading, we often witness that an idea of an individual user drives macroscopic changes. From the perspectives of product development and marketing, the opinions left by potential consumers in online social network can generate big ripple effects. This study analyzes the user opinions in online space to grasp preferences toward various products psychologically categorized by users. We also suggest an aspect of the market mentally configured by users using network modeling while following the framework of economic sociology. Existing analyses on online market place are mainly dealing with structural issues such as inter-actor relationships and status measurement. This study, however, analyzes complex preferences regarding diverse products and brands and derives a new model for inter-market connections. We expect that our study will provide important consequences on digital marketing and community design of corporations planning word of mouth effect in online space.     

Development of head detection and tracking systems for visual surveillance

This paper proposes a technique for the detection of head nod and shake gestures based on eye tracking and head motion decision. The eye tracking step is divided into face detection and eye location. Here, we apply a motion segmentation algorithm that examines differences in moving people’s faces. This system utilizes a Hidden Markov Model-based head detection module that carries out complete detection in the input images, followed by the eye tracking module that refines the search based on a candidate list provided by the preprocessing module. The novelty of this paper is derived from differences in real-time input images, preprocessing to remove noises (morphological operators and so on), detecting edge lines and restoration, finding the face area, and cutting the head candidate. Moreover, we adopt a K-means algorithm for finding the head region. Real-time eye tracking extracts the location of eyes from the detected face region and is performed at close to a pair of eyes. After eye tracking, the coordinates of the detected eyes are transformed into a normalized vector of x-coordinate and y-coordinate. Head nod and shake detector uses three hidden Markov models (HMMs). HMM representation of the head detection can estimate the underlying HMM states from a sequence of face images. Head nod and shake can be detected by three HMMs that are adapted by a directional vector. The directional vector represents the direction of the head movement. The vector is HMMs for determining neutral as well as head nod and shake. These techniques are implemented on images, and notable success is notified.     

A new CVD reactor for semiconductor film deposition

The concept and design of a new chemical vapor deposition (CVD) reactor is presented for both epitaxial and nonepitaxial film deposition in semiconductor processing. The reactor is designed in such a way that a stagnant semiconductor source fluid of uniform concentration is provided for the film deposition without causing free or forced convection. The supply of the source gas for the deposition is by diffusion through a porous material such as quartz or graphite. Compared to the low pressure CVD (LPCVD) reactor with mounted wafer configuration, the new reactor should give a better film thickness uniformity and about an order of magnitude reduction in the amount of the source gas required. Further, at least for polycrystalline silicon deposition, the deposition rate can be much higher than is currently practiced with the LPCVD reactor. Design equations for the reactor are given. Details on the design for the polycrystalline silicon deposition are also given.     

环氧氯丙烷的生产技术与市场分析

综述了环氧氯丙烷国内外生产现状 ,消费概况及生产技术 ,并对其发展前景作了初步预测     

The effects of Ni and Li doping on the performance of lithium manganese oxide material for lithium secondary batteries

Layered Li_0.7[M_1/6Mn_5/6]O₂ (M=Li, Ni) was synthesized using a sol-gel method. P2-Na_0.7[M_1/6Mn_5/6]O₂ precursor was first synthesized by a sol-gel method, and then O2-Li_0.7[M_1/6Mn_5/6]O₂ was prepared by an ion exchange of Li for Na in P2-Na_0.7[M_1/6Mn_5/6]O₂ precursor. From charge/discharge curves, it was seen that Li_0.7[Li_1/6Mn_5/6]O₂ has two plateaus similar to those observed from a spinel structure, but Li_0.7[Ni_1/6Mn_5/6]O₂ holds a single plateau as observed from a typical layered structure. It was considered that Li_0.7[Li_1/6Mn_5/6]O₂ undergoes a phase transformation from layered to spinel structure during the charge/discharge cycle, but Li_0.7[Ni_1/6Mn_5/6]O₂ maintains O2-layered structure after the cycles. Li_0.7[Ni_1/6Mn_5/6]O₂ was higher in discharge capacity and retention rate than Li_0.7[Li_1/6Mn_5/6]O₂.     

Damping of vinyl acetate–n‐butyl acrylate copolymers

A photopolymerization process at room temperature was devised to copolymerize vinyl acetate (VAc) and n‐butyl acrylate (BA) mainly to prepare rubber‐like damping sheet bearing pressure‐sensitive adhesive property in this study. The investigations using both the differential scanning calorimeter and rheometric dynamic analysis show the existence of two glass transition temperatures for each copolymer. The scanning electron microscopic pictures reveal that the degree of microphase separation increases with increasing annealing time at 70°C. It was suggested that the rubbery domain (formed by the PBA blocks) disperses in the glassy domain (constituted by the PVAc blocks), making an effective damping entity. Excellent damping was observed for the copolymer samples, with the tanδ peak values as high as 1.76–1.80 at a certain temperature range and with tanδ> 0.3 at quite wide temperature ranges. In addition, the copolymers containing more VAc tend to have the higher damping. © 2003 Wiley Periodicals, Inc. J Appl Polym Sci 91: 1396–1403, 2004     

Synthesis and free radical polymerization of 4-{1′-(2″-methacryloyloxyethoxy)-5′-naphthyliminomethylidene}-4′-nitrostilbene for nonlinear optical applications

4-{1′-(2″-Methacryloyloxyethoxy)-5′-naphthyliminomethylidene}-4′-nitro-stilbene 6 was prepared by the reactions of methacryloyl chloride with 4-{1′-(2″-hydroxyethoxy)-5′-naphthyliminomethylidene}-4′-nitrostilbene 5. Compound 5 was synthesized from 4′-methyl-4-nitrostilbene by several reaction steps. Monomer 6 was polymerized with DTBP as a radical initiator to obtain polymer with 4-(1′-oxy-5′-naphthyliminomethylidene)-4′-nitrostilbene, which is presumably effective chromophore for second-order nonlinear optical applications in the side chain. The resulting polymethacrylate 7 showed a thermal stability up to 300 °C in TGA thermogram, and the T_g value obtained from DSC thermogram was 120 °C, which is acceptable for NLO device applications. Received: 14 October 1996/Accepted: 11 December 1996     

Preparation and characterization of trilobal activated carbon fibers

The objective of this research was to evaluate the effectiveness of several different methods for controlling the pore size and pore size distribution in activated carbon fibers. Variables studied included fiber shape, activation time, and the addition of small amounts of silver nitrate. Pure isotropic pitch and the same isotropic pitch containing 1 wt.% silver were melt spun to form fibers with round and trilobal cross sections. These fibers were then stabilized, carbonized, and activated in carbon dioxide. Field emission scanning electron microscopy (FE SEM), electron dispersive spectra (EDS), and wavelength dispersive spectra (WDS) were used to monitor the size and distribution of the silver particles in the fibers before and after activation. Each of these analyses showed that the distribution of silver particles was extremely uniform before and after activation. The fibers were also weighed before and after activation to determine the percent burn-off. The BET specific surface areas of the activated fibers were determined from N₂ adsorption isotherms measured at −196 °C. The results showed that round and trilobal fibers with equivalent cross-sectional areas yielded similar burn-off values and specific surface areas after activation. Also, activation rates were found to be independent of CO₂ flow rate. The porosity of the activated fibers depended on the total time of activation and the cross-sectional area of fibers. The N₂ adsorption measurements showed that the activated fibers had extremely high specific surface areas (greater than 3000 m²/g) and high degrees of meso- and macro-porosity. FE SEM was also used to investigate surface texture and size of pore openings on the surfaces of the activated fibers. The photos showed that silver particles generated surface macro- and mesopores, in agreement with the inferences from N₂ adsorption measurements.