Efficiency enhancement of dye-sensitized solar cells with addition of additives (single/binary) to ionic liquid electrolyte

The effect of addition of single and binary additives on the performance of dye-sensitized TiO₂ solar cells based on electrolytes containing an ionic liquid (IL), 1,2-dimethyl-3-propylimidazolium iodide (DMPII) has been studied. Among the seven additives used, the addition of 2-(dimethylamino)-pyridine (DMAP) to IL resulted in best cell efficiency, which showed further enhancement with the addition of 5-chloro-1-ethyl-2-methylimidazole (CEMI) as second additive. The efficiency of the dye-sensitized solar cell (DSC) based on an electrolyte containing binary additives (DMAP and CEMI in equal molar ratios) has been found to increase by 62·5% from 4·35 to 7·07%. The dependence of different photovoltaic performance parameters (V _oc, J _sc, ff, η) of DSC upon temperature has been studied over a 30–120°C range and only a small decrease in conversion efficiency has been observed. The electrolyte containing binary additives (DMAP and CEMI) shows best cell performance up to 120°C.     

SMT production scheduling: a generalized transportation approach

A generalized transportation model is first formulated for the scheduling of Surface Mount Technology (SMT) production. Its dual form is next discussed. By specially coding the SMT scheduling problem, it is unnecessary to develop the constraint matrix for the dual. The simplex method is not applicable for this problem due to its sparse data structure. An efficient algorithm for the dual model is then developed from the idea of the revised simplex method. To illustrate the algorithm, a numeric example is presented.     

URBAN BUILT ENVIRONMENTS,ACCESSIBILITY, AND TRAVEL BEHAVIOR IN A DECLINING URBAN CORE: THE EXTREME CONDITIONS OF DISINVESTMENT AND SUBURBANIZATION IN THE DETROIT REGION

The research explores the impact of socioeconomic and racial variables on accessibility to urban amenities and travel in compact urban built environments that have traditionally been viewed as improving access to daily destinations and promoting nonmotorized travel: urban environments characterized by high densities, mixed land uses, and high connectivity. The study focuses on six neighborhoods in the Detroit region. Two neighborhoods are within the city itself, and predominantly poor and Black, and four of the neighborhoods are in the region surrounding the city, and they are predominantly wealthy and White. This study at the neighborhood scale enables an analysis into how class and race affect accessibility and travel in neighborhoods experiencing urban disinvestment and decline. The research shows that the traditional relationship between high densities, mixed land uses, high connectivity, greater accessibility, and pedestrian activity is significantly weaker in declining inner cities.     

Reactive wetting phenomena of MgO-C refractories in contact with CaO-SiO2 slag

Wetting phenomena between MgO C and CaO SiO2 slags were investigated by varying carbon content.A sessile drop technique was adopted to study the wetting phenomena in conjunction with a high speed camera for the observation of intrinsic wetting phenomena.The results show that the high content of SiO2 and the presence of Al2O3 in slags enhance the diffusion of Mg2+,leading to the promotion of reactive wetting.The carbon in MgO C refractory impedes the penetration of slags by repelling the slag and slowing the diffusion of Mg2+.This accounts for the non-wetting behavior of the slag on MgO C refractory with 17% (mass fraction) carbon similar to that of graphite.     

HR-TEM and FIB-SEM characterization of formation of eutectic-like structure from amorphous GdAlO3-Al2O3 system

The crystallization process of the eutectic composition of GdAlO_3-Al_2O_3 from the amorphous phase prepared by rapid-quenching of melt that leads to the formation of a cantaloupe skin-like microstructure was investigated using focused ion-beam scanning electron microscopy (FIB-SEM) and high-resolution transmission electron microscopy (HR-TEM).The amorphous films were heat-treated at temperatures between 1000 °C and 1500 °C for up to 30min to form the eutectic phases of GdAlO_3 and Al_2O_3.The GdAlO_3 and Al_2O_3 crystal phases that formed from the amorphous phase were identified by FIB-SEM and HR-TEM.Both components began to crystallize and grow from the amorphous phase separately at different temperatures.The formation process of these crystal phases was different from that of the ordinary eutectic microstructure solidified from the GdAlO_3-Al_2O_3 system.Therefore,the observed structure is termed "eutectic-like" for distinction.The microstructures formed from the amorphous phases at sufficiently high temperatures consisted of ultra-fine microstructures of individually crystallized components and were similar to ordinary eutectic microstructures.By heat-treating the amorphous films at 1500 °C for either 2 min,8min or 30min,the ultra-fine components of GdAlO_3 and Al_2O_3 were found to crystallize following a eutectic-like stage after 8min of heat treatment.     

Computed tomographic evaluation of gas hole formation and structural quality in Gouda‐type cheese

Computed tomography (CT) was performed on Gouda‐type cheese during ripening to evaluate gas hole formation and structural quality. The cheese was exposed to different ripening conditions, including variations in ripening temperature and concentration of butyric acid bacteria. Computed tomography images were obtained every 2 weeks for 16 weeks to assess the volume, shape and location of gas holes. The results demonstrate that CT makes the nondestructive monitoring of cheese gas hole formation and evaluation of the structural features of cheese possible throughout the ripening period.     

Effective parameters on diameter of carbon nanotubes by plasma enhanced chemical vapor deposition

The effective parameters on the diameter of carbon nanotubes (CNTs) by plasma enhanced chemical vapor deposition (PECVD) were presented.Among lots of influential parameters,the effects of the catalytic film thickness and the pretreatment plasma power on the growth of CNTs were investigated.The results show that the size of catalytic islands increases by increasing the thickness of catalytic layer,but the density of CNTs decreases.The pretreatment duration time of 30 s is the optimal condition for growing CNTs with about 50 nm in diameter.By increasing the pretreatment plasma power,the diameter of CNTs decreases gradually.However,the diameter of CNTs does not change drastically from 80 to 120 W.The uniformly grown CNTs with the diameter of 50 nm are obtained at the pretreatment plasma power of 100 W.