An experimental behaviour of concrete-filled steel tubular columns

In this paper results of tests conducted on 27 concrete-filled steel tubular columns are reported. The test parameters were the column slenderness, the load eccentricity covering axially and eccentrically loaded columns with single or double curvature bending and the compressive strength of the concrete core. The test results demonstrate the influence of these parameters on the strength and behaviour of concrete-filled steel tubular columns. A comparison of experimental failure loads with the predicted failure loads in accordance with the method described in Eurocode 4 Part 1.1 showed good agreement for axially and eccentrically loaded columns with single curvature bending whereas for columns with double curvature bending the Eurocode loads were higher and on the unsafe side. More tests are needed for the case of double curvature bending.     

Geochemistry of some rare earth elements in groundwater,Vierlingsbeek, The Netherlands

Groundwater samples were taken from seven bore holes at depths ranging from 2 to 41m nearby drinking water pumping station Vierlingsbeek, The Netherlands and analysed for Y, La, Ce, Pr, Nd, Sm and Eu. Shale-normalized patterns were generally flat and showed that the observed rare earth elements (REE) were probably of natural origin. In the shallow groundwaters the REEs were light REE (LREE) enriched, probably caused by binding of LREEs to colloids. To improve understanding of the behaviour of the REE, two approaches were used: calculations of the speciation and a statistical approach.For the speciation calculations, complexation and precipitation reactions including inorganic and dissolved organic carbon (DOC) compounds, were taken into account. The REE speciation showed REE(3+), REE(SO(4))(+), REE(CO(3))(+) and REE(DOC) being the major species. Dissolution of pure REE precipitates and REE-enriched solid phases did not account for the observed REEs in groundwater. Regulation of REE concentrations by adsorption-desorption processes to Fe(III)(OH)(3) and Al(OH)(3) minerals, which were calculated to be present in nearly all groundwaters, is a probable explanation.The statistical approach (multiple linear regression) showed that pH is by far the most significant groundwater characteristic which contributes to the variation in REE concentrations. Also DOC, SO(4), Fe and Al contributed significantly, although to a much lesser extent, to the variation in REE concentrations. This is in line with the calculated REE-species in solution and REE-adsorption to iron and aluminium (hydr)oxides. Regression equations including only pH, were derived to predict REE concentrations in groundwater. External validation showed that these regression equations were reasonably successful to predict REE concentrations of groundwater of another drinking water pumping station in quite different region of The Netherlands.     

Stability analysis of simply-supported rectangular plates under non-uniform uniaxial compression using rigorous and approximate plane stress solutions

The non-classical problem of buckling of a simply-supported rectangular plate due to various types of non-uniform compressive edge loads is analysed here. For each case, the elasticity solution for the internal in-plane stress field is obtained rigorously using a superposition of Airy's stress functions and also approximately using extended Kantorovich method. Subsequently, the convergent buckling loads are obtained using Galerkin's method. Results are presented to highlight the dependence of the total buckling load and the corresponding buckled shape on the edge load distribution, as well as to illustrate the applicability of the approximate plane stress solutions.     

Field measurement of the air flow characteristics of big mechanically ventilated spaces

Air speeds induced by mechanical ventilation systems in the occupied zone are studied experimentally in seven railway stations in Hong Kong. Values of air speed at different positions are measured. From these values, air speed contours and turbulence intensities are calculated. Macroscopic numbers describing airflow in a space including the Reynolds number and the jet momentum number are estimated and their potential uses are discussed.     

Method of Determining Strength and Deformation Characteristics of Soils from Results of Deep Impression of Rod Plates

The possibility of determining strength and deformation characteristics of soils under field conditions using rod plates is discussed. The mutual relationship between these characteristics is established from results of deep impression of these rods.     

Profiles of mean wind speeds and vertical turbulence intensities measured at seashore and two inland sites using Doppler sodars

The authors’ group has been conducting full-scale measurements of wind velocities with Doppler sodars. It is very important to accurately assess the profiles of mean wind speeds and turbulence intensities in relation to terrain roughness. In this study, the profiles were evaluated for all data measured over a long period at a seashore and two inland sites. It is confirmed that for strong winds the profiles can be approximated by a single power law at altitudes between 50 and 340 m. The power law exponents of the mean wind speed profiles are approximately 0.1 for wind from the sea and 0.2-0.3 for wind blown over land. Those of the turbulence intensity profiles are approximately 0 and −0.2 to 0.4, respectively.     

Chloroaromatic formation in incineration processes

The high-temperature reactions of chlorinated hydrocarbons are reviewed with a primary focus on the gas-phase molecular growth chemistry and elementary reaction mechanisms leading to the formation of chlorinated benzenes and chlorinated polycyclic aromatic hydrocarbons. Recent heterogeneous mechanistic studies of the chlorination and condensation of aliphatic hydrocarbons at lower temperatures are also summarized. Copper(II) valent species play an important role as catalyst and reagent. The main thermal pathways for chlorinated dibenzodioxins and furans have been deduced by these laboratory experiments, which try to model the complex reality of the post-incineration zone of municipal and hazardous waste incinerators.     

Use of toxicity test results and confrontation of some toxicity test methods with fire scenarios

The enormous, world wide research activity in the field of combustion toxicology has given rise to an impressive amount of toxicity data.

The first part of this paper discusses the problems which arise when such results are used to rank materials in an order of the relative toxicity of their combustion products or in attempting to relate them to toxicological hazard evaluation.

In the second part, after introducing the notion of fire scenarios and describing two such possible situations, existing test methods are compared in relation to their relevance to the scenario parameters. It is shown that none of the evaluated methods completely fulfills the considered conditions.

It is concluded by the authors that agreement on thoroughly described scenarios is necessary for further trials towards international harmonisation and development of test methods.