Physicochemical principles of preparation of emulsion fuels

The basic physicochemical principles of preparation of emulsion fuel compositions based on heavy and extra-heavy crude cuts were analyzed with consideration of the nature and content of the phases constituting the emulsion, type of chemical additives — emulsifiers and stabilizers, and type of equipment for production of emulsion fuels. __________ Translated from Khimiya i Tekhnologiya Topliv i Masel, No. 5, pp. 51–56, September–October, 2007.     

Influence of halide ions and alloy microstructure on the passive and localized corrosion behavior of alloy 22

Alloy 22 (N06022) is the current candidate alloy used to fabricate the external wall of the high-level nuclear waste containers for the Yucca Mountain repository. It was of interest to study and compare the general and localized corrosion susceptibility of Alloy 22 in fluoride and chloride solutions at 90 °C. Standard electrochemical tests such as cyclic potentiodynamic polarization, amperometry, and electrochemical impedance spectroscopy were used. Studied variables included the solution pH and the alloy microstructure (thermal aging). Results show that Alloy 22 is highly resistant to general corrosion in all the solutions tested. Thermal aging is not detrimental and even seems to be slightly beneficial for general corrosion at the higher solution pHs. Pitting corrosion was never observed. Crevice corrosion was found only for high chloride-containing solutions after anodic polarization. The presence of fluoride ions together with chloride ions seems to increase the susceptibility of Alloy 22 to crevice corrosion compared to pure chloride solutions. This article is based on a presentation made in the symposium “Effect of Processing on Materials Properties for Nuclear Waste Disposition,” November 10–11, 2003, at the TMS Fall meeting in Chicago, Illinois, under the joint auspices of the TMS Corrosion and Environmental Effects and Nuclear Materials Committees.     

Vibration cavitation behaviour of selected Ni-Mn-Ga alloys

Vibration cavitation erosion tests were carried out on Ni-Mn-Ga alloys of three different crystal structures: (1) the cubic austenite, (2) the non-modulated tetragonal martensite (T) and (3) the five-layered martensite (5M). All Ni-Mn-Ga alloys exhibited cavitation behaviour characterized by a step-wise curve of mass loss versus test time. This behaviour is correlated to the microstructural nature of the alloys as well as the surface conditions of the pre-test samples. The type and concentration of the defects at the surfaces were critical to the cavitation resistance of the alloys. The best cavitation resistant alloy was of a cubic austenitic structure, followed with the alloy of a tetragonal T-martensite. The largest material loss was found in the alloy with a 5M martensite. All the studied Ni-Mn-Ga alloys had an excellent cavitation resistance compared to that of the reference stainless steel, and they even excelled some NiTi alloys found in literature. This may be due to the superelasticity of the cubic austenite and the twinning of the martensitic phases.     

Generation of Gas Discharge Plasma by an Arc Source with a Cold Hollow Cathode

The results from a study of an arc plasma source with a cold hollow cathode are presented. The source generates plasma with a density of ∼10¹⁰ cm⁻³ in a volume of ∼0.2 m³ at discharge currents of up to 150 A, an arc discharge operating voltage of 30–40 V, and a low pressure of 0.1–1 Pa. The motion of the cathode spot in the crossed electric and magnetic fields inside the hollow cathode and the cathode’s special design make it possible to eliminate almost completely the penetration of the sputtered cathode material into the working vacuum chamber.__________Translated from Pribory i Tekhnika Eksperimenta, No. 3, 2005, pp. 62–66.Original Russian Text Copyright © 2005 by Schanin, Koval, Akhmadeev.     

Effects of low radiation on the power quality of a distributed PV-grid connected system

We have previously investigated effects of radiation levels on power quality of a number PV-grid interactive systems in Thailand, in terms of harmonics and voltage variation at the point of common coupling (PCC). In this paper, we focus on the nature of components of complex power (actual, reactive and apparent power) of inverter output of a PV-grid interactive system due to low radiation, below 400 W/m². The system being investigated has an array of 4.2 kWp and representative of roof top units. It is observed that a PV array supplies increasing real power, in magnitude and as percentage of complex power, at high values of radiation. At low radiation level when the array does not provide enough output power, reactive power is drawn from distribution transformer and fed into an inverter and loads. Based on results from the test site and long term radiation data of Bangkok, we then estimate energy available from low radiation from a hypothetical PV-grid interactive unit in Bangkok of a similar size. It can be seen that for a tropical climate like Thailand a significant amount of energy, 20–30% of radiation energy, is in the form of reactive power. Methods must be devised to capture this low radiation energy and converted into real power form.     

横向各向同性介质中的初至波旅行时计算

本文直接采用Thomsen导出的横向各向同性介质中的相速度、群角与相角、群速度与相速度的精确函数关系,提出了一种新的具有任意各向异性强度的横向各向同性介质中的初至波旅行时计算方法,它不同于Faria等人给出的采用群速度近似公式(Byun)的仅适应弱各向异性的初至波旅行时计算方法。该新算法在计算具有任意各向异性强度的横向各向同性介质中的初至波旅行时时,并不显著地增大计算时间。分析对比由新算法得到的初至波旅行时的等值线图和由交错网格有限差分波场模拟得到的波场快照表明,无论是对弱各向异性还是对强弱各向异性,新算法都具有较高的精度;随着各向异性强度的增大,新算法的计算结果与采用近似公式计算结果的差值也随之增大。     

Ascorbins?ure in Citronen- und Apfelsinenschalen

Ohne ZusammenfassungMitteilung aus der chemischen Untersuchungsstelle beim Wehrkreissanitätspark IX.