Determination of labile and strongly bound metals in lake water

Differential pulse anodic stripping voltammetry is applied to differentiate and determine the labile and strongly bound forms of Zn, Cd, Pb and Cu in lake water without preconcentration of the sample. The sensitivities as established for an oxidation peak current of 0·020 μA are: 0·2 ppb for Zn. 0·4 ppb Cd. 0·7 ppb Pb and 0·5 ppb for Cu. For the analysis of a lake water containing 5·0–24·5 ppb of the four metals, the relative S.D. ranged from 1·6 to 10 per cent. Interferences of cations and anions and the choice of a buffer system have been discussed. The method has been applied to study a number of small lakes in the Sudbury area. Ontario.     

Oxygen consumption and activity of the white sucker (Catostomus commersoni), in lethal and nonlethal levels of the organochlorine insecticide, methoxychlor

The survival, oxygen consumption and spontaneous activity of suckers were determined at 15°C in water containing different concentrations of methoxychlor in ethanol, ethanol, and no added substances. A dynamic bioassay was used to estimate the 96 h LC50, which was found to be 0·0345 ppm. Routine oxygen consumption was determined in a continuous-flow respirometer, and the activity was recorded in separate experiments by measuring the water disturbance using silver wire electrodes.After 24 h fish exposed to untreated, ethanol-treated and 0.01 ppm methoxychlor-treated water had oxygen uptake rates which were relatively constant and near standard levels. At 0.10 ppm methoxychlor (lethal to all fish within 85 h), oxygen consumption rates were 2–3.5 × as high as those of control fish. Activity also greatly increased. The fish lost their balance along with the coordination between opercular and locomotor movements. Suckers that died in 0.04 ppm methoxychlor showed oxygen uptake rates and poisoning symptoms similar to 0.10 ppm treated fish, while those that survived this treatment had rates similar to control fish. The increase in ventilation which accompanies this hyperactivity may result in increased uptake of insecticide and thereby explain the irreversible nature of the response.     

Permeability changes in granite with crack growth during immersion in hot water

Permeability tests and observation of induced, as well as inherent, cracks have been carried out to quantitatively explain permeability changes in granite taking place during a weathering test in terms of micro-structure by cracks. To this end, permeability tensors were estimated from observations of crack systems using the Replica Method and of the crack apertures with a scanning electron microscope. The following conclusions were reached: the drastic increase in permeability around an immersion of 1000 d in 90°C water could not be explained by the existence of a percolation threshold because all the specimens were percolative in the sense that the traces of crack tensor were above the critical density for percolation. On the other hand, SEM observation revealed that, with immersion, crack apertures widened and their distribution spread. Permeability estimated using the third (not the first) moment of observed apertures showed the increase in measured permeability well. When evaluating the connectivity parameter λ to give a quantitative accordance between measured and estimated permeability, it had a constant value as low as 0.17, irrespective of the immersion period, in spite of the higher density of micro-cracks than the percolation threshold. It can be said that, in considering the natural three-dimensional crack system, the third moment of physical apertures plays a more important role in predicting the permeability and λ is greatly affected by the spread of crack apertures.     

The development of macrolayer thickness of water in the pool boiling regime

ABSTRACT

The main purpose of this study is to analyse the phenomenon of pool boiling in water over a horizontally placed copper tube heater of 28?mm diameter. The experiment has been carried out to observe the bubble growth and departure characteristics for the heat flux range up to 40,000?W/m². The entire process is being recorded by a digital camera at different time intervals. The measured parameters have been used to determine the initial layer thickness, macro layer thickness and critical heat flux and validated with models proposed in the literature.     

Classic and novel brominated flame retardants (BFRs) in common sole (Solea solea L.) from main nursery zones along the French coasts

Brominated flame retardants (BFRs) were investigated in juvenile common sole from nursery zones situated along the French coast in 2007, 2008 and 2009. Extensive identification was performed with regard to PBDEs, novel BFRs 1,2-bis(2,4,6-tribromophenoxy)ethane (BTBPE) and decabromodiphenylethane (DBDPE), and other non-PBDE BFRs, namely, hexabromobenzene (HBB) and 2,2′,4,4′,5,5′-hexabromobiphenyl (BB-153). Polybrominated diphenyl ether (PBDE) concentrations (Σ 14 congeners) ranged from 0.01 ng/g to 0.16 ng/g wet weight (ww) in muscle, and 0.07 ng/g to 2.8 ng/g ww in liver. Concentrations were in the lower range of those reported in the literature in other European locations. Lower PBDE concentrations, condition indices and lipid contents were observed in the Seine estuary in 2009, possibly in relation to a lower water flow. The PBDE patterns and ratios we observed suggested that juvenile sole have a relative high metabolic degradation capacity. Non-PBDE BFRs were detected at lower levels than PBDEs, i.e., within the < method detection limit - 0.005 ng/g ww range in muscle, and < method detection limit - 0.2 ng/g ww range in liver. The data obtained is of particular interest for the future monitoring of these compounds in the environment.     

Particles and vegetation: implications for the transfer of particle-bound organic contaminants to vegetation

This paper presents a comprehensive review of the mechanisms responsible for the transfer of atmospheric particulate deposition and soil particulate re-suspension onto vegetation. The nature of atmospheric aerosols and dry/wet particulate deposition are reviewed, together with information from the literature on radionuclides as tracers of the air particle/soil particle to vegetation transfer processes. Information from these fields is used to make inferences about the potential significance of these pathways in supplying particle-bound semi-volatile organic chemicals (e.g. polycyclic aromatic hydrocarbons, polychlorinated dibenzo-p-dioxins and dibenzofurans, polychlorinated biphenyls) to vegetation. Retention of compounds on particles brought to the above-ground plant surfaces is discussed. In the absence of definitive field/experimental studies, calculations are made drawing on the literature data to estimate the contributions of atmospheric and soil particle-bound organic contaminants to the plant concentration. These show that depending on the site-specific, species-specific and compound-specific scenarios considered, particulate-bound inputs may be negligible or may dominate the supply of organic contaminants to the above-ground portion of plants. However, field/experimental studies and direct measurements are needed to provide reliable quantitative data on this topic.     

A Microcomputer Model for Flood Prediction with Applications

Abstract: A generally applicable mathematical model, tailored for use on a Personal Computer, as the design tool to simulate unsteady flood flow in a network of interconnected rivers has been developed and applied to the Sham Chun River along the border between Hong Kong and the People's Republic of China. The effect on the improved Sham Chun River due to the proposed river training in the River Indus, one of its tributaries, is evaluated. The one-dimensional unsteady flow model itself is broadly applicable to a wide range of hydrologic conditions and varying field situations. It incorporates real hydraulic features including branched channels and 'tidal flats' flooding and drying. The time history of water stages and discharges are computed at any desired location throughout the connected essentially one-dimensional channel network subject to initial and boundary conditions. Details are given of techniques adapted in using the computational scheme to quantify the unsteady flow condition and the means to assure an efficient numerical solution as well as to verify the accuracy of the computed outputs by subjection to carefully selected schematic simplified test cases and real prototype cases with numerical solution method is a useful predictive engineering tool in river design.