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951.
Ali Md Showkat Kwang‐Pill Lee Anantha Iyengar Gopalan Sang‐Ho Kim Seong‐Ho Choi Sang‐Ho Sohn 《应用聚合物科学杂志》2006,101(6):3721-3729
Composites based on poly(diphenyl amine) (PDPA) and multiwall carbon nanotubes (MWNTs) were prepared by chemical oxidative polymerization through two different approaches: in situ polymerization and intimate mixing. In in situ polymerization, DPA was polymerized in the presence of dispersed MWNTs in sulfuric acid medium for different molar composition ratios of MWNT and DPA. Intimate mixing of synthesized PDPA with MWNT was also used for the preparation of PDPA/MWNT composites. Transmission electron microscopy revealed that the diameter of the tubular structure for the composite was 10–20 nm higher than the diameter of pure MWNT. Scanning electron microscopy provided evidence for the differences in the morphology between the MWNTs and the composites. Raman and Fourier transform IR (FTIR) spectroscopy, thermogravimetric analysis, X‐ray diffraction, and UV–visible spectroscopy were used to characterize the composites and reveal the differences in the molecular level interactions between the components in the composites. The Raman and FTIR spectral results revealed doping‐type molecular interactions and coordinate covalent‐type interactions between MWNT and PDPA in the composite prepared by in situ polymerization and intimate mixing, respectively. The backbone structure of PDPA in the composite decomposed at a higher temperature (>340°C) than the pristine PDPA (~300°C). This behavior also favored the molecular level interactions between MWNT and PDPA in the composite. © 2006 Wiley Periodicals, Inc. J Appl Polym Sci 101: 3721–3729, 2006 相似文献
952.
A nanosized silica particle was used as the support to prepare an Et[Ind]2ZrCl2/MAO catalyst for propylene polymerization of polypropylene. The catalyst and the polymer produced were characterized with nitrogen adsorption, ICP, DSC, SEM, TEM, XRD, solution viscometer, 13C NMR and optical microscopy. The effects of polymerization temperature and [Al]/[Zr] ratio on catalyst activity and polymer melting point were investigated. Under identical reaction conditions, nanosized catalyst exhibited better polymerization activity than the microsized catalyst (e.g., the former had 64% higher activity than the latter at the optimum polymerization temperature (50°C) and [Al]/[Zr] = 570). DSC results indicated that polymer melting point increased with the increase of [Al]/[Zr] ratio and with the decrease of polymerization temperature. XRD results showed that the percentage of γ crystals increased with decreasing [Al]/[Zr] ratio. Electron microscopic results showed that the polymer particle size increased with increasing polymerization temperature. © 2006 Wiley Periodicals, Inc. J Appl Polym Sci 101: 2573–2580, 2006 相似文献
953.
A series of well‐defined and property‐controlled polystyrene (PS)‐b‐poly(ethylene oxide) (PEO)‐b‐polystyrene (PS) triblock copolymers were synthesized by atom‐transfer radical polymerization, using 2‐bromo‐propionate‐end‐group PEO 2000 as macroinitiatators. The structure of triblock copolymers was confirmed by 1H‐NMR and GPC. The relationship between some properties and molecular weight of copolymers was studied. It was found that glass‐transition temperature (Tg) of copolymers gradually rose and crystallinity of copolymers regularly dropped when molecular weight of copolymers increased. The copolymers showed to be amphiphilic. Stable emulsions could form in water layer of copolymer–toluene–water system and the emulsifying abilities of copolymers slightly decreased when molecular weight of copolymers increased. © 2006 Wiley Periodicals, Inc. J Appl Polym Sci 101: 727–730, 2006 相似文献
954.
Hotmelt pressure sensitive adhesives (PSAs) usually contain styrenic block copolymers like styrene–isoprene–styrene (SIS), SBS, SEBS, tackifier, oil, and additives. These block copolymers individually reveal no tack. Therefore, a tackifier is a low molecular weight material with high glass transition temperature (Tg), and imparts the tacky property to PSA. The SIS block copolymer with different diblocks was blended with hydrogenated dicyclopentadiene (H‐DCPD tackifier), which has three kinds of Tg. PSA performance was evaluated by probe tack, peel strength, and shear adhesion failure temperature. PSA is a viscoelastic material, so that its performance is significantly related to the viscoelastic properties of PSAs. We tested the viscoelastic properties by dynamic mechanical analysis and the thermal properties by differential scanning calorimeter to investigate the relation between viscoelastic properties and PSA performance. © 2006 Wiley Periodicals, Inc. J Appl PolymSci 102: 2839–2846, 2006 相似文献
955.
The promoting effect of ultrasonic wave on the hydrodynamics and mass transfer characteristics of the loop airlift reactor was studied. The gas holdup, liquid circulation velocity, mixing time and overall volumetric mass transfer coefficient were examined and compared, with and without ultrasonic wave in the reactor. The experimental results show that ultrasound has almost no notable effect on the gas holdup, but has a tendency to decrease gradually the liquid circulation velocity and increase the overall volumetric mass transfer coefficient; and the effect on the mixing time is relatively complex. At low superficial gas velocity, the low powered ultrasound promotes the radial mixing of fluid; with the ultrasonic power increasing, ultrasonic vibration obstructs the axial mixing of fluid. Moreover, the effect of ultrasonic wave on the mixing time gradually decreases with the increase in the superficial gas velocity. Therefore there exists an optimal ultrasonic power for hydrodynamics and mass transfer. Correlations were also proposed for the hydrodynamics and mass transfer characteristics of the reactor. 相似文献
956.
4,4′‐bis(Phenoxy)diphenyl sulfone (DPODPS) was synthesized by reaction of phenol with bis(4‐chlorophenyl) sulfone in tetramethylene sulfone in the presence of NaOH. Two poly(aryl ether sulfone ether ketone ketone)s (PESKKs) with high molecular weight were prepared by low temperature solution polycondensation of DPODPS and terephthaloyl chloride (TPC) or isophthaloyl chloride (IPC), respectively, in 1,2‐dichloroethane and in the presence of aluminum chloride (AlCl3) and N‐methylpyrrolidone (NMP). The resulting polymers were characterized by various analytical techniques, such as FT‐IR, 1H‐NMR, DSC, TG, and WAXD. The results show that the Tg and Td of PESEKKs are much higher, but its Tm is lower than those of PEKK. The other results indicate that PESEKKs exhibit excellent thermostabilities at 300 ± 10°C. © 2005 Wiley Periodicals, Inc. J Appl Polym Sci 96: 489–493, 2005 相似文献
957.
Ming Li Zbigniew Twardowski Felix Mok Norbert Tam 《Journal of Applied Electrochemistry》2007,37(4):499-504
Sodium dichromate is commonly used in sodium chlorate production to maintain high current efficiency; however, it is also
a well documented carcinogen. To reduce the environmental impact, identification of a suitable alternative with similar buffering
characteristics to dichromate and without adverse effect on the electrolytic performance of sodium chlorate production is
important; sodium molybdate is a good candidate. Molybdate ion and its conjugated acid work as a buffer pair at pH 5–6, a
lower and slightly narrower pH window than the typical buffer region of dichromate. Nonetheless, the molybdate buffer works
effectively during the electrolytic process by maintaining pH at 5.9. Although the use of molybdate buffer will lower the
overpotential of hydrogen evolution reaction (HER) by 100 mV, the average off-gas oxygen content is noticeably compromised
at 3.6–4.6%, measured using a pilot cell operated at 3 kA m−2and 80 °C during a 3-day trial. The resulting current efficiency of 91 92% is significantly lower than when dichromate is
employed as the process additive (> 96%). Mixtures of different dichromate and molybdate ratio were also investigated in terms
of the resulting cathode surface potential. 相似文献
958.
A simple solid state technique for electrochemical micromachining of metal substrates using a metal ion conductor (Na-β″-Al2O3) was proposed. The fundamental solid electrochemical cell consists of a (anode) metal substrate (M = Ag, Cu, Zn, and Pb)/pyramidal Na-β″-Al2O3/Ag (cathode) system, where the contact diameter between M/Na-β″-Al2O3 was extremely small, on the order of a few micrometer. Under an applied electric field, the metal substrate was electrochemically oxidized to metal ions (Mn+) at the M/Na-β″-Al2O3 microcontact. These Mn+ ions migrated into the Na-β″-Al2O3. As a result of continuous electrolysis, the metal substrate was locally consumed at the microcontact, and thus solid state electrochemical micromachining was accomplished. As expected, the machining size or depth depended on the electrolysis conditions (current, operating time) and the apex configuration of pyramidal Na-β″-Al2O3. Moreover, the scanning of the Na-β″-Al2O3 pyramid during electrolysis produced a fine patterned metal substrate. In the present paper, solid state electrochemical micromachining was performed for several metal substrates, and its advantages and disadvantages vis-a-vis the conventional electrochemical micromachining method are discussed in detail. 相似文献
959.
Deformation and fracture toughness of high‐density polyethylene (HDPE) in plane‐stress tension was studied using the concept of essential work of fracture (EWF). Strain range for necking was determined from uniaxial tensile test, and was used to explain the deformation transition for 2‐staged crack growth in double‐edge‐notched tensile test. Through work‐partitioning, EWF values for HDPE were determined for each stage of the crack growth. Appropriateness of these EWF values to represent the material toughness is discussed. The study concludes that the EWF values for ductile polymers like HDPE may not be constant, but vary with the deformation behaviour involved in the crack growth process. POLYM. ENG. SCI., 47:1327–1337, 2007. © 2007 Society of Plastics Engineers 相似文献
960.
Sang Hern Kim Won Keun Son Yong Joo Kim Eu‐Gene Kang Dong‐Won Kim Chang Woo Park Whan‐Gi Kim Hyung‐Joong Kim 《应用聚合物科学杂志》2003,88(3):595-601
A polystyrene (PS)/poly(butyl acrylate) (PBA) composite emulsion was produced by seeded emulsion polymerization of butyl acrylate (BA) with PS seed particles which were prepared by emulsifier‐free polymerization of styrene with potassium persulfate (KPS) under a nitrogen atmosphere at 70°C for 24 h with stirring at 60 rpm and swelled with the BA monomer in an ethanol/water medium. The structure of the PS/PBA composite particles was confirmed by the presence of the characteristic absorption band attributed to PS and PBA from FTIR spectra. The particles for pure PS and PS/PBA with a low content of the BA monomer were almost spherical and regular. As the BA monomer content was increased, the particle size of the PS/PBA composite particles became larger, and more golf ball‐like particles were produced. The surface morphology of the PS/PBA composite particles was investigated by AFM and SEM. The Tg's attributed to PS and PBA in the PS/PBA composite particles were found at 110 and ?49°C, respectively. The thermal degradation of the pure PS and PS/PBA composite particles occurred in one and two steps, respectively. With an increasing amount of PBA, the initial thermal decomposition temperature increased. On the contrary the residual weight at 450°C decreased with an increasing amount of PBA. © 2003 Wiley Periodicals, Inc. J Appl Polym Sci 88: 595–601, 2003 相似文献