全文获取类型
收费全文 | 712篇 |
免费 | 86篇 |
国内免费 | 1篇 |
专业分类
电工技术 | 3篇 |
综合类 | 11篇 |
化学工业 | 289篇 |
金属工艺 | 5篇 |
机械仪表 | 12篇 |
建筑科学 | 41篇 |
矿业工程 | 10篇 |
能源动力 | 32篇 |
轻工业 | 77篇 |
水利工程 | 4篇 |
石油天然气 | 1篇 |
无线电 | 42篇 |
一般工业技术 | 132篇 |
冶金工业 | 23篇 |
原子能技术 | 2篇 |
自动化技术 | 115篇 |
出版年
2024年 | 1篇 |
2023年 | 37篇 |
2022年 | 41篇 |
2021年 | 78篇 |
2020年 | 29篇 |
2019年 | 36篇 |
2018年 | 29篇 |
2017年 | 32篇 |
2016年 | 38篇 |
2015年 | 51篇 |
2014年 | 50篇 |
2013年 | 49篇 |
2012年 | 53篇 |
2011年 | 67篇 |
2010年 | 36篇 |
2009年 | 41篇 |
2008年 | 28篇 |
2007年 | 22篇 |
2006年 | 9篇 |
2005年 | 15篇 |
2004年 | 6篇 |
2003年 | 7篇 |
2002年 | 6篇 |
2001年 | 8篇 |
2000年 | 3篇 |
1999年 | 5篇 |
1998年 | 2篇 |
1997年 | 2篇 |
1996年 | 3篇 |
1995年 | 1篇 |
1994年 | 4篇 |
1993年 | 1篇 |
1992年 | 1篇 |
1991年 | 1篇 |
1989年 | 2篇 |
1986年 | 2篇 |
1976年 | 2篇 |
1936年 | 1篇 |
排序方式: 共有799条查询结果,搜索用时 0 毫秒
61.
Katharina O. Barros Flávia B. M. Alvarenga Giulia Magni Gisele F. L. Souza Maxwel A. Abegg Fernanda Palladino Sílvio S. da Silva Rita C. L. B. Rodrigues Trey K. Sato Chris Todd Hittinger Carlos A. Rosa 《Yeast (Chichester, England)》2023,40(2):84-101
This study investigated the diversity of yeast species associated with rotting wood in Brazilian Amazonian rainforests. A total of 569 yeast strains were isolated from rotting wood samples collected in three Amazonian areas (Universidade Federal do Amazonas-Universidade Federal do Amazonas [UFAM], Piquiá, and Carú) in the municipality of Itacoatiara, Amazon state. The samples were cultured in yeast nitrogen base (YNB)-d -xylose, YNB-xylan, and sugarcane bagasse and corncob hemicellulosic hydrolysates (undiluted and diluted 1:2 and 1:5). Sugiyamaella was the most prevalent genus identified in this work, followed by Kazachstania. The most frequently isolated yeast species were Schwanniomyces polymorphus, Scheffersomyces amazonensis, and Wickerhamomyces sp., respectively. The alpha diversity analyses showed that the dryland forest of UFAM was the most diverse area, while the floodplain forest of Carú was the least. Additionally, the difference in diversity between UFAM and Carú was the highest among the comparisons. Thirty candidates for new yeast species were obtained, representing 36% of the species identified and totaling 101 isolates. Among them were species belonging to the clades Spathaspora, Scheffersomyces, and Sugiyamaella, which are recognized as genera with natural xylose-fermenting yeasts that are often studied for biotechnological and ecological purposes. The results of this work showed that rotting wood collected from the Amazonian rainforest is a tremendous source of diverse yeasts, including candidates for new species. 相似文献
62.
Katharina Holeczek Uwe Gbureck Tomasz Jungst Csaba Gergely Lisa Galaba Juliane C. Kade 《Advanced Engineering Materials》2023,25(8):2201330
Digital light processing (DLP) enables the fabrication of complex 3D structures based on a photopolymerizable resin usually containing a photo initiator and an UV or photo absorber. The resin and thus the final properties of the printed structures can be adjusted by adding fillers like bioceramic powders relevant for bone-regeneration applications. Herein, a water-based and biocompatible poly(ethylene glycol diacrylate) (PEGDA) resin containing the photo initiator lithium-phenyl-2,4,6-trimethylbenzoylphosphinate (LAP) enables the production of 3D structures via DLP. The addition of calcium magnesium phosphate cement (CMPC) powder, acting as photo absorber, leads to higher accuracy of the final structures. After curing the printed construct in a diammonium–hydrogen phosphate (DAHP) bath for hardening, the resulting mechanical properties can be adjusted without post-process sintering. Solid loading of up to 40 wt% CMPC powder is possible, and the resins are investigated regarding their rheological behavior and printability. The resulting constructs are analyzed in respect to their surface morphology using scanning electron microscope (SEM), porosity, phase composition using X-ray diffraction (XRD) methods, as well as mechanical properties influenced by the hardening process using DAHP for different durations. 相似文献
63.
Katharina Sommer Paul Rieger Stefanie Monika Müller Romana Schwarz Gregor Trimmel Michael Feuchter Thomas Griesser 《Advanced Engineering Materials》2023,25(7):2200901
In recent years, dual-cure chemistry has been exploited to realize interpenetrating networks (IPNs) that provide enhanced thermo-mechanical properties. In this contribution, photoinduced curing of (meth)acrylates is used to build the desired 3D structure, whereas the thermally triggered polymerization reaction of 2H-chromene functionalized building blocks is utilized to create the IPN. This strategy combines the advantages of traditional UV-curable monomers with high-performance thermosets. After the successful synthesis of the bispropargyl ether derivative, i.e., 4,4′-(propane-2,2-diyl)bis((ethynyloxy)benzene), its thermally induced conversion to the corresponding 2H chromene functionalized prepolymer is studied by Fourier-transform infrared spectroscopy and gel permeation chromatography. The network formation as well as the printability of various formulations containing different amounts of the thermo-curable building block is investigated. The obtained IPNs provide enhanced thermo-mechanical properties making these resins suitable for the additive manufacturing of functional 3D parts for high-performance applications. 相似文献
64.
Véronique B. Schwartz Franck Thétiot Sandra Ritz Sabine Pütz Lars Choritz Alexandros Lappas Renate Förch Katharina Landfester Ulrich Jonas 《Advanced functional materials》2012,22(11):2376-2386
Despite multiple research approaches to prevent bacterial colonization on surfaces, device‐associated infections are currently responsible for about 50% of nosocomial infections in Europe and significantly increase health care costs, which demands development of advanced antibacterial surface coatings. Here, novel antimicrobial composite materials incorporating zinc oxide nanoparticles (ZnO NP) into biocompatible poly(N‐isopropylacrylamide) (PNIPAAm) hydrogel layers are prepared by mixing the PNIPAAm prepolymer with ZnO NP, followed by spin‐coating and photocrosslinking. Scanning electron microscopy (SEM) characterization of the composite film morphology reveals a homogeneous distribution of the ZnO NP throughout the film for every applied NP/polymer ratio. The optical properties of the embedded NP are not affected by the matrix as confirmed by UV‐vis spectroscopy. The nanocomposite films exhibit bactericidal behavior towards Escherichia coli (E. coli) for a ZnO concentration as low as ≈0.74 μg cm?2 (1.33 mmol cm?3), which is determined by inductively coupled plasma optical emission spectrometry. In contrast, the coatings are found to be non‐cytotoxic towards a mammalian cell line (NIH/3T3) at bactericidal loadings of ZnO over an extended period of seven days. The differential toxicity of the ZnO/hydrogel nanocomposite thin films between bacterial and cellular species qualifies them as promising candidates for novel biomedical device coatings. 相似文献
65.
Kayla Fallon Sean Hughes Katharina Zeissler William Legrand Fernando Ajejas Davide Maccariello Samuel McFadzean William Smith Damien McGrouther Sophie Collin Nicolas Reyren Vincent Cros Christopher H. Marrows Stephen McVitie 《Small (Weinheim an der Bergstrasse, Germany)》2020,16(13)
Magnetic skyrmions are particle‐like deformations in a magnetic texture. They have great potential as information carriers in spintronic devices because of their interesting topological properties and favorable motion under spin currents. A new method of nucleating skyrmions at nanoscale defect sites, created in a controlled manner with focused ion beam irradiation, in polycrystalline magnetic multilayer samples with an interfacial Dzyaloshinskii–Moriya interaction, is reported. This new method has three notable advantages: 1) localization of nucleation; 2) stability over a larger range of external field strengths, including stability at zero field; and 3) existence of skyrmions in material systems where, prior to defect fabrication, skyrmions were not previously obtained by field cycling. Additionally, it is observed that the size of defect nucleated skyrmions is uninfluenced by the defect itself—provided that the artificial defects are controlled to be smaller than the inherent skyrmion size. All of these characteristics are expected to be useful toward the goal of realizing a skyrmion‐based spintronic device. This phenomenon is studied with a range of transmission electron microscopy techniques to probe quantitatively the magnetic behavior at the defects with applied field and correlate this with the structural impact of the defects. 相似文献
66.
Katharina Großmann Thomas Dellermann Marius Dillig Jürgen Karl 《International Journal of Hydrogen Energy》2017,42(16):11150-11158
This paper proposes partial steam reforming of natural gas as a chemical storage option for excess electricity. Thermodynamic simulations with Aspen Plus® show that highest process efficiencies are reached at low steam-to-carbon (S/C) ratios in the feed. However, coke deposition due to unwanted side or follow-up reactions and thus catalyst deactivation is likely in this operation range. In an experimental evaluation three catalysts were selected to test their resistance towards coking: two nickel based and one rhodium based noble metal catalyst. They were tested regarding their long-term stability at S/C ratios as low as 0 to 0.1 and reaction temperatures between 450 and 500 °C. A different reaction and deactivation behavior was observed for nickel and the noble metal catalysts. The measured life times of the noble metal catalyst were by a factor of at least 100 higher than for the two selected nickel catalysts at the applied reforming conditions. Furthermore, after each reforming experiment, a temperature-programmed oxidation (TPO) analysis was performed for the spent catalysts. Based on literature data, the measured CO2 peaks at corresponding temperatures were related to the different forms of solid carbon depositions. Main carbonaceous species found on the nickel catalysts were of filamentous nature, whereas one or two more reactive C species with monoatomic or polymeric structure at much lower amount were detected on the noble metal catalyst. Further SEM analysis confirmed these findings. 相似文献
67.
Papendorf B Nonnenmacher K Ionescu E Kleebe HJ Riedel R 《Small (Weinheim an der Bergstrasse, Germany)》2011,7(7):970-978
The present study focuses on the synthesis and ceramization of novel hafnium-alkoxide-modified silazanes as well as on their microstructure evolution at high temperatures. The synthesis of hafnia-modified polymer-derived SiCN ceramic nanocomposites is performed via chemical modification of a polysilazane and of a cyclotrisilazane, followed by cross-linking and pyrolysis in argon atmosphere. Spectroscopic investigation (i.e., NMR, FTIR, and Raman) shows that the hafnium alkoxide reacts with the N-H groups of the cyclotrisilazane; in the case of polysilazane, reactions of N-H as well as Si-H groups with the alkoxide are observed. Consequently, scanning and transmission electron microscopy studies reveal that the ceramic nanocomposites obtained from cyclotrisilazane and polysilazane exhibited markedly different microstructures, which is a result of the different reaction pathways of the hafnium alkoxide with cyclotrisilazane and with polysilazane. Furthermore, the two prepared ceramic nanocomposites are unexpectedly found to exhibit extremely different high-temperature behavior with respect to decomposition and crystallization; this essential difference is found to be related to the different distribution of hafnium throughout the ceramic network in the two samples. Thus, the homogeneous distribution of hafnium observed in the polysilazane-derived ceramic leads to an enhanced thermal stability with respect to decomposition, whereas the local enrichment of hafnium within the matrix of the cyclotrisilazane-based sample induces a pronounced decomposition upon annealing at high temperatures. The results indicate that the chemistry and architecture of the precursor has a crucial effect on the microstructure of the resulting ceramic material and consequently on its high-temperature behavior. 相似文献
68.
Katharina Nekolla Sabine Sellner Marc Praetner Karina Mildner Dagmar Zeuschner Fritz Krombach 《Small (Weinheim an der Bergstrasse, Germany)》2016,12(14):1882-1890
So‐called membrane nanotubes are cellular protrusions between cells whose functions include cell communication, environmental sampling, and protein transfer. It has been previously reported that systemically administered carboxyl‐modified quantum dots (cQDs) are rapidly taken up by perivascular macrophages in skeletal muscle of healthy mice. Expanding these studies, it is found, by means of in vivo fluorescence microscopy on the mouse cremaster muscle, rapid uptake of cQDs not only by perivascular macrophages but also by tissue‐resident cells, which are localized more than 100 μm distant from the closest vessel. Confocal microscopy on muscle tissue, immunostained for the membrane dye DiI, reveals the presence of continuous membranous structures between MHC‐II‐positive, F4/80‐positive cells. These structures contain microtubules, components of the cytoskeleton, which clearly colocalize with cQDs. The cQDs are exclusively found inside endosomal vesicles. Most importantly, by using in vivo fluorescence microscopy, this study detected fast (0.8 μm s?1, mean velocity), bidirectional movement of cQDs in such structures, indicating transport of cQD‐containing vesicles along microtubule tracks by the action of molecular motors. The findings are the first to demonstrate membrane nanotube function in vivo and they suggest a previously unknown route for the distribution of nanomaterials in tissue. 相似文献
69.
70.
Katharina Resch Gernot M. Wallner Christian Teichert Günther Maier Markus Gahleitner 《Polymer Engineering and Science》2006,46(4):520-531
Polypropylene homopolymers and ethylene/propylene‐random‐copolymers formulated with and without anti‐blocking additives were extruded to cast films with an industrial scale extruder equipped with a soft box, a specific air knife that expels a higher volume of air at lower velocity. The films were analyzed as to their optical properties haze and clarity. A comprehensive topographical characterization was performed using atomic force microscopy (AFM) and confocal microscopy. To obtain morphological information on a nanometer scale AFM phase imaging, micro‐thermal analysis and small angle X‐ray scattering (SAXS) were done. A significant effect of additives and processing conditions on the film topography and the optical properties was revealed. The films without anti‐blocking and antacid aids showed the best optical properties and lowest vertical roughness fluctuations. In contrast, the addition of anti‐blocking and antacid aids reduced the optical properties associated with an increase in surface roughness. While for films without anti‐blocking aids an enhanced soft box condition resulted in lower vertical fluctuations of roughness and better optical properties, the behavior was in reverse for films with anti‐blocking aid. By means of SAXS crystalline lamellae with a thickness of about 2.5 nm were detected. High‐resolution phase imaging AFM yielded thicker crystal lamellae on the film surface. POLYM. ENG. SCI., 46:520–531, 2006. © 2006 Society of Plastics Engineers. 相似文献