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111.
Joel A. Paulson Edward A. Buehler Richard D. Braatz 《International journal of control》2020,93(1):126-139
ABSTRACTThis article investigates model predictive control (MPC) of linear systems subject to arbitrary (possibly unbounded) stochastic disturbances. An MPC approach is presented to account for hard input constraints and joint state chance constraints in the presence of unbounded additive disturbances. The Cantelli–Chebyshev inequality is used in combination with risk allocation to obtain computationally tractable but accurate surrogates for the joint state chance constraints when only the mean and variance of the arbitrary disturbance distributions are known. An algorithm is presented for determining the optimal feedback gain and optimal risk allocation by iteratively solving a series of convex programs. The proposed stochastic MPC approach is demonstrated on a continuous acetone–butanol–ethanol fermentation process, which is used in the production of biofuels. 相似文献
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In biology, structural design and materials engineering is unified through formation of hierarchical features with atomic
resolution, from nano to macro. Three molecular building blocks are particularly prevalent in all structural protein materials:
alpha helices (AHs), beta-sheets (BSs) and tropocollagen (TC). In this article we present a comparative study of these three
key building blocks by focusing on their mechanical signatures, based on results from full-atomistic simulation studies. We
find that each of the basic structures is associated with a characteristic material behavior: AH protein domains provide resilience
at large deformation through energy dissipation at low force levels, BS protein domains provide great strength under shear
loading, and tropocollagen molecules provide large elasticity for deformation recovery. This suggests that AHs, BSs, and TC
molecules have mutually exclusive mechanical signatures. We correlate each of these basic properties with the molecule’s structure
and the associated fundamental rupture mechanisms. Our study may enable the use of abundant protein building blocks in nanoengineered
materials, and may provide critical insight into basic biological mechanisms for bio-inspired nanotechnologies. The transfer
towards the design of novel nanostructures could lead to new multifunctional and mechanically active, tunable, and changeable
materials. 相似文献
114.
Starcke Katrin; Wolf Oliver T.; Markowitsch Hans J.; Brand Matthias 《Canadian Metallurgical Quarterly》2008,122(6):1352
Recent research has suggested that stress may affect memory, executive functioning, and decision making on the basis of emotional feedback processing. The current study examined whether anticipatory stress affects decision making measured with the Game of Dice Task (GDT), a decision-making task with explicit and stable rules that taps both executive functioning and feedback learning. The authors induced stress in 20 participants by having them anticipate giving a public speech and also examined 20 comparison subjects. The authors assessed the level of stress with questionnaires and endocrine markers (salivary cortisol and alpha-amylase), both revealing that speech anticipation led to increased stress. Results of the GDT showed that participants under stress scored significantly lower than the comparison group and that GDT performance was negatively correlated with the increase of cortisol. Our results indicate that stress can lead to disadvantageous decision making even when explicit and stable information about outcome contingencies is provided. (PsycINFO Database Record (c) 2010 APA, all rights reserved) 相似文献
115.
Donor Atom‐Stabilized Aluminum Alkyls as Cocatalysts for the Ziegler–Natta Polymerization of Propene
Andrea Eisenhardt Bjrn Heuer Walter Kaminsky Katrin Khler Herbert Schumann 《Advanced Synthesis \u0026amp; Catalysis》2003,345(12):1299-1304
A number of organoaluminum compounds, stabilized with intramolecular nitrogen‐ or oxygen‐donor functions, have been used as cocatalysts for the MgCl2/TiCl4‐catalyzed homopolymerization of propene as well as for the copolymerization of ethene with propene. The polymerization behavior of these aluminum alkyls was examined at different Al/Ti ratios within the range of 2 to 50 and compared with the reference of triethylaluminum (TEA). Especially the alkyls [2‐(N,N‐dimethylaminomethyl)phenyl]dimethylaluminum ( 1 ) and [2‐(N,N‐dimethylaminomethyl)phenyl]diethylaluminum ( 2 ) show the highest activities at very low Al/Ti ratios in the homopolymerization of propene, whereas TEA is almost inactive. The species [8‐(N,N‐dimethylamino)naphthyl]dimethylaluminum ( 4 ) reaches the highest activity of all examined alkyls and is very close to the highest value obtained with TEA. Bulky iso‐butyl groups at the aluminum center are responsible for the very poor performance of the nitrogen stabilized cocatalysts [8‐(N,N‐dimethylamino)naphthyl]diisobutylaluminum ( 5 ) and [2‐(N,N‐dimethylaminomethyl)phenyl]diisobutylaluminum ( 3 ). The properties of the polypropenes synthesized with the stabilized organoaluminum species are similar to those produced with TEA but with a distinctly higher molar mass. In the case of 1 , it was possible to increase the molar mass by a factor of three. For the copolymerizations, the compounds [2‐(N,N‐diethylaminomethyl)phenyl]diethylaluminum ( 7 ) and (2‐methoxybenzyl)diisobutylaluminum ( 8 ) were found to be most suitable, producing polymers with significantly higher activities than TEA. For all copolymers two fractions were obtained, one crystalline fraction with a low and an amorphous part with a high amount of comonomer. In both fractions, 7 and 8 provide a higher comonomer incorporation than TEA. 相似文献
116.
María J. Unzu Harold A. S. Schoonbrood Jos M. Asua Amaia Montoya Goi David C. Sherrington Katrin Sthler Karl-Heinz Goebel Klaus Tauer Marie Sjberg Krister Holmberg 《应用聚合物科学杂志》1997,66(9):1803-1820
Several polymerizable surfactants (surfmers) have been used in the semi-continuous emulsion copolymerization of styrene, butyl acrylate, and acrylic acid. Three of the (anionic) surfmers (sodium 11-crotonoyl undecan-1-yl sulfate, sodium 11-methacryloyl undecan-1-sulfate, and sodium sulfopropyl tetradecyl maleate) were prepared in house with purities between 53 and 82%. Physicochemical properties such as the critical micelle concentration, the adsorption isotherm, and the specific adsorption area were determined. The surfmers were then used with constant addition profiles in semicontinuous reactions, and the instantaneous conversions of the main monomers determined. The particle size, amount of coagulum, surface tension, and stability against electrolyte solutions of the latices were evaluated. Films were cast of some of the latices, and the visual appearance and water adsorption were assessed. © 1997 John Wiley & Sons, Inc. J Appl Polym Sci 66: 183–1820, 1997 相似文献
117.
Isothiazole 1,1-dioxides – From Sweeter to Chiral Auxiliar in the Stereoselective Synthesis This review gives a report of the last ten years on the new synthetic methods, reactions and biological applications of isothiazole 1,1-dioxide derivatives. the formation of monocyclic and heterocyclic annelated isothiazole 1,1-dioxides by oxidation of isothiazoles, cyclocondensation of sulfonamides and cycloaddition of isothiazol-3(2H)-one 1,1-dioxides are discussed in more detail. Furthermore, the preparation of pharmacologically important N-substituted saccharines is reported. New saccharine-derived chiral N-enoyl-and N-acyl-2,3-dihydro-1,2-benzisothiazole 1,1-dioxides serve as advantageous stereoface-directing dienophile and dipolarophile auxiliaries in Diels-Alder-reactions and 1,3-dipolar cycloadditions. Asymmetric alkylations, acylations and aldolizations are also described. 相似文献
118.
Christian Pahl Eberhard Hartung Anne Grothmann Katrin Mahlkow-Nerge Angelika Haeussermann 《Journal of dairy science》2014
Monitoring rumination behavior serves multiple purposes in feeding and herd management of dairy cows. The process of calving is a major event for cows, and a detailed understanding of alterations in behavioral patterns of animals in the time around calving is important in calving detection. The objective of this study was to describe the short-term changes in rumination patterns in dairy cows immediately before and after parturition. In total, 17 cows were fitted with rumination sensors that were able to monitor rumination time, number of rumination boli, and number of rumination jaw movements. Rumination time was decreased in the last 4 h antepartum and in the first 8 h postpartum. Cows stopped ruminating 123 ± 58 min (mean ± standard deviation) before calving and resumed ruminating 355 ± 194 min after calving. The number of rumination jaw movements and boli per day were decreased in the 24-h period postpartum. Rumination rate, the number of rumination jaw movements per rumination minute, and the number of boli per rumination minute changed little around calving. The calving event primarily influenced the duration and frequency of various rumination characteristics but not rumination intensity. Among detected characteristics, rumination time showed the greatest potential for monitoring of calving events. 相似文献
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