Sheet forming process of carbon fiber reinforced plastics for lightweight parts

The use of carbon fiber reinforced plastics is increasing markedly, particularly in aircraft bodies, but the time required to manufacture CFRP parts should be shortened to realize mass production. The stamping of solidified CFRP sheets can reduce the production time and may increase the flexibility of the manufacturing process. A new sheet forming process for solidified CFRP, in which a CFRP sheet is sandwiched by dummy metallic sheets during stamping, is proposed. The dummy metallic sheets act as protective materials as well as media for heating the CFRP sheet. The results of applying the proposed process are presented.     

Fundamental research on the label-free detection of protein adsorption using near-infrared light-responsive plasmonic metal nanoshell arrays with controlled nanogap

In this work, we focused on the label-free detection of simple protein binding using near-infrared light-responsive plasmonic nanoshell arrays with a controlled interparticle distance. The nanoshell arrays were fabricated by a combination of colloidal self-assembly and subsequent isotropic helium plasma etching under atmospheric pressure. The diameter, interparticle distance, and shape of nanoshells can be tuned with nanometric accuracy by changing the experimental conditions. The Au, Ag, and Cu nanoshell arrays, having a 240-nm diameter (inner, 200-nm polystyrene (PS) core; outer, 20-nm metal shell) and an 80-nm gap distance, exhibited a well-defined localized surface plasmon resonance (LSPR) peak at the near-infrared region. PS@Au nanoshell arrays showed a 55-nm red shift of the maximum LSPR wavelength of 885 nm after being exposed to a solution of bovine serum albumin (BSA) proteins for 18 h. On the other hand, in the case of Cu nanoshell arrays before/after incubation to the BSA solution, we found a 30-nm peak shifting. We could evaluate the difference in LSPR sensing performance by changing the metal materials.     

Improvement mechanism of fatigue strength of weld joints by hammer peening on base metal

New peening technology is proposed to improve the fatigue strength of welded joints. By using this technology, compressive residual stress is introduced at weld toe by the developed peening procedure which plastic deformation is only applied to the base material near the weld toe. In this study, improvement mechanism of fatigue strength of weld joints by hammer peening on base metal was clarified by FEA. It was clarified that increasing of stress at weld toe is controlled by depression formed near the weld toe. Not only compressive residual stress at weld toe but also decreasing stress concentration at weld toe by plastic deformation on base metal was indicated as the factor of improving fatigue strength of weld joints.     

Characteristics of powder metallurgy pure titanium matrix composite reinforced with multi-wall carbon nanotubes

By using pure titanium powder coated with un-bundled multi-wall carbon nanotubes (MWCNTs) via wet process, powder metallurgy (P/M) titanium matrix composite (TMC) reinforced with the CNTs was prepared by spark plasma sintering (SPS) and subsequently hot extrusion process. The microstructure and mechanical properties of P/M pure titanium and reinforced with CNTs were evaluated. The distribution of CNTs and in situ formed titanium carbide (TiC) compounds during sintering was investigated by optical and scanning electron microscopy (SEM) equipped with EDS analyzer. The mechanical properties of TMC were significantly improved by the additive of CNTs. For example, when employing the pure titanium composite powder coated with CNTs of 0.35 mass%, the increase of tensile strength and yield stress of the extruded TMC was 157 MPa and 169 MPa, respectively, compared to those of extruded titanium materials with no CNT additive. Fractured surfaces of tensile specimens were analyzed by SEM, and the uniform distribution of CNTs and TiC particles, being effective for the dispersion strengthening, at the surface of the TMC were obviously observed.     

An amperometric detector formed of highly dispersed Ni nanoparticles embedded in a graphite-like carbon film electrode for sugar determination

We achieved improved detection limits for sugars by developing a novel thin film containing 0.8% highly dispersed Ni nanoparticles in disordered graphite-like carbon (Ni-NDC) as a detection electrode for high-performance liquid chromatography. The Ni-NDC film was prepared in one step by a simple radio frequency (rf) sputtering method at a temperature below 200 degrees C. We characterized the film by XPS, TEM, and AFM analysis and found that the average Ni nanoparticle size was 3 nm and that the film consisted of a mixture of Ni, NiO, Ni2O3, and Ni(OH)2. We studied the electrochemical detection of sugars using the 0.8% Ni-NDC film electrode. The film electrode had excellent electrocatalytic ability and good stability compared with a Ni-bulk electrode with regard to the electrooxidation of sugars. We employed the Ni-NDC film as an HPLC detection electrode. We achieved a good separation of four sugars (glucose, fructose, sucrose, lactose) at a relatively low constant detection potential (0.40 V vs Ag/AgCl) and a linearity of over 3 orders of magnitude. We obtained improved detection limits for the investigated sugars, namely, 20, 25, 50, and 37 nM for glucose, fructose, sucrose, and lactose, respectively. This is at least 1 order of magnitude lower than the detection limits obtained with a Ni-bulk electrode with the same measurement condition. The Ni-NDC film electrode also showed good reproducibility with a relative standard deviation of 1.75% for 40 consecutive injections of glucose in a flow system.     

Fast multiple electron capture dissociation in a linear radio frequency quadrupole ion trap

We developed a fast electron capture dissociation (ECD) device using a linear radio frequency-quadrupole (RFQ) ion trap. The device dissociated peptides and proteins using a focused electron beam with an intensity of 0.5 microA and a diameter of 1 mm. The electron capture rate was 13%/ms for doubly charged peptides, and the total amount of ECD products was identical to the theoretical limit, i.e., 50% of incident precursor ions were observed as maximum ECD products by electron irradiation of 7 ms in a pulse counting detection scheme. Coupling this ECD device to a time-of-flight mass spectrometer, we applied multiple ECD. Protonated ubiquitin precursor ions with a charge state of 10 were repeatedly cleaved by ECD, i.e., charge-reduced species and their highly charged fragments were cleaved again and again, creating lower charged products, leaving only singly to triply charged states among the final products. Meanwhile with the amount of electron irradiated, lower charged products increased. Applying an electron beam for 8 ms, we obtained 96% of the total sequence coverage using a 40 fmol sample except at three proline sites. This fast ECD device should be widely applicable to proteomics including post-translational modification analysis and top-down analysis.     

Delay discounting is associated with treatment response among cocaine-dependent outpatients.

Delay discounting (DD) describes the rate at which reinforcers lose value as the temporal delay to their receipt increases. Steeper discounting has been positively associated with vulnerability to substance use disorders, including cocaine use disorders. In the present study, we examined whether DD of hypothetical monetary reinforcers is associated with the duration of cocaine abstinence achieved among cocaine-dependent outpatients. Participants were 36 adults who were participating in a randomized controlled trial examining the efficacy of voucher-based contingency management (CM) using low-magnitude (N = 18) or high-magnitude (N = 18) voucher monetary values. DD was associated with the number of continuous weeks of cocaine abstinence achieved, even after adjusting for treatment condition during the initial 12-week, t(33) = 2.48, p = .045 and entire recommended 24-week of treatment, t(33) = 2.40, p = .022. Participants who exhibited steeper discounting functions achieved shorter periods of abstinence in the Low-magnitude voucher condition (12-week: t(16) = 2.48, p = .025; 24-week: t(16) = 2.68, p = .017), but not in the High-magnitude voucher condition (12-week: t(16) = 0.51, p = .618; 24-week: t(16) = 1.08, p = .298), although the interaction between DD and treatment condition was not significant (12-week: t(32) = ?1.12, p = .271; 24-week: t(32) = ?0.37, p = .712). These results provide further evidence on associations between DD and treatment response and extend those observations to a new clinical population (i.e., cocaine-dependent outpatients), while also suggesting that a more intensive intervention like the High-magnitude CM condition may diminish this negative relationship between DD and treatment response. (PsycINFO Database Record (c) 2011 APA, all rights reserved)     

Effective Bond Length of Carbon-Fiber-Reinforced Polymer Strips Bonded to Fatigued Steel Bridge I-Girders

After years in service, many steel girders have deteriorated to the point where fatigue cracks have initiated in the girders. In girders having cover plates that do not terminate in a compression region, a common type of crack initiates at the weld toe at the ends of the cover plate after being subjected to cyclic tensile loads due to traffic. The use of precured carbon-fiber-reinforced polymer (CFRP) laminates, adhered to the inside face of the girder tension flange, is one proposed method for repairing these cracked bridge girders. The main advantages of using CFRP laminates are their light weight and their durability, which result in ease of handling and maintenance. For the application of this rehabilitation method, it is important to determine the effective bond length for CFRP laminates adhered to the inside face of a cracked steel girder flange. Experimental tests using a new type of effective bond length test specimen were conducted in this research on several types of adhesives and precured CFRP laminates, in addition to several different bonding configurations. The minimum bond length required to achieve the maximum strength of the rehabilitation scheme for the materials investigated in this research was determined. The experimental results also indicated that an adhesive with relatively large ductility is required to redistribute the stresses successfully within the adhesive layer during increased loading. A simple analytical solution for the shear strain distribution in the adhesive layer was proposed for estimating the effective bond length, and the results were verified with computational analyses. Good agreement was found among the computational, analytical, and experimental results.