TETHER-LINKED [60]FULLERENE-DONOR DYADS

A series of [60]fullerene bis-adducts having a π-electron-rich aromatic ring as a donor in a face-to-face arrangement were synthesized by the bis-cyclopropanation of [60]fullerene with tether-linked bis-malonates. One of the bis-adducts showed a photoinduced intramolecular electron transfer which caused the dramatic quenching of its fluorescence in a polar solvent.     

黏滞阻尼器的优化布置及其在高层钢结构加固中的应用

阻尼器优化布置是结构减震设计过程中的重要环节,通常需要通过多次动力响应计算来完成。为此,提出了一种通过结构静力分析确定阻尼器合理布置位置的方法,并能够快速计算出优化方案的附加阻尼比。将该方法应用于一栋位于日本东京都新宿区29层钢结构建筑的减震加固设计中,分析了该建筑的强震观测系统在日本“311地震”中采集到的部分楼层加速度时程数据,并基于分析结果验证了所建立的非线性数值分析模型的可靠性。采用所提方法对结构进行减震加固,得到双向共64个阻尼器的优化布置方案及其附加阻尼比,并通过动力方法对结果进行了验证。同时针对长周期及长持时特性的地震波,对减震结构进行动力弹塑性时程分析,评估其抗震性能。分析结果表明：减震优化方案的减震效果明显,结构整体地震反应和构件损伤较非减震方案都大大减小;减震优化方案有效改善了高层钢结构楼层变形不均匀的情况,层间位移角均满足小于1/100的性能要求;通过减震优化后大部分钢支撑和钢梁的塑性率都降低至小于1。     

Study of performance characteristics of a small Stirling refrigerator

A prototype Stirling cycle refrigerator employing helium as a working fluid was investigated to determine whether a freon‐free machine was a viable alternative for the current household refrigerator. A displacer‐type or β‐type Stirling cycle machine of 100‐W capacity was designed and tested using varying design parameters such as dead volume ratio, working fluids, the ratio of the compression volume to the expansion volume, and the phase difference between a power piston and displacer. The detrimental effect of the dead space on the refrigeration capacity was confirmed. The refrigeration produced by nitrogen in an expansion space was 28% less than that produced by helium. The optimum volume ratio and the phase difference for maximum refrigeration was determined under the design operation conditions. Moreover, the refrigeration correlation formula as a function of these parameters was obtained. © 2002 Wiley Periodicals, Inc. Heat Trans Asian Res, 31(5): 344–361, 2002; Published online in Wiley InterScience ( www.interscience.wiley.com ). DOI 10.1002/htj.10033     

Evaluation of the possibility that free fatty acids cause false-positive result in diarrhetic shellfish poisoning mouse bioassay in actual use

Midgut glands of bivalves are used for the mouse bioassay of diarrhetic shellfish poison (DSP). A large quantity of free fatty acids (FFAs) causes a false positive outcome in the assay. To examine whether this is likely to occus under conditions of actual use, we analyzed the contents of the FFAs in the enlarged midgut glands during gametogenesis of Japanese scallops Patinopecten yessoensis that had been caught at two points in Hunka Bay on March 27, 2006, because the content of FFAs may increase with activation of lipogenesis for gametogenesis. Fatty acids (FAs) were measured with fluorometric high-performance liquid chromatography after derivatization with 9-anthryldiazomethane. The total FFAs (14 : 0, 16 : 0, 18 : 0, 16 : 1, 18 : 1, 18 : 4, 20 : 5 and 22 : 6) represented 3.3-4.2 wt% of the lipid. The toxic FFAs accounted for 40-43 wt% of the total FFAs. Content of each FFA (18 : 1, 2.7-5.0 mg/g lipid; 18 : 4, tr.-2.0 mg/g; 20 : 4, n.d.; 20 : 5, 8.0-9.1 mg/g and 22 : 6, 2.0-2.1 mg/g) was lower than the lethal dose tentatively calculated from the relative toxicity. It appears that the likelihood of FFAs causing false-positives in the mouse bioassay is low if the sample is fresh and is extracted immediately after homogenizing.     

Laboratory and field measurements of dry deposition of sulfur dioxide onto Chinese loess surfaces

Laboratory and field measurements were conducted to examine dry deposition of SO2 onto Chinese loess surfaces using native soil sampled in the loess plateau, China. The field tests were employed in Beijing and Lanzhou, China, by directly measuring the dry deposition of SO2 on soil, which uses soil put on a collector as an SO2 passive sampling medium. In the laboratory, a high rate of uptake to SO2 deposition for Chinese soil surfaces due to the highly alkalinity was found. The uptake of SO2 deposition was dependent on the pH soil and relative humidity. Furthermore, we evaluated some factors that affect the measurement precision: response of SO2 uptake, repeatability, recovery factor, and variability associated with the weight and the surface coverage on the collectors. As a result, it was shown that the measurement precision was primarily related to the ratio of the SO2 deposition amount relative to the sulfur content of the original soil. This result was consistent with the field observations. The laboratory and field results indicated an excellent agreement on the SO2 uptake inherent in the results from the soil surfaces in different regions.     

Effects of Smart Charging of Multiple Electric Vehicles in Reducing Power Generation Fuel Cost

The high penetration of variable sources of renewable power generation will lead to operational difficulties in supply/demand balancing in the entire power system. The mass deployment of electric vehicles (EVs) and plug‐in hybrid vehicles (PHEVs) will also cause significant changes in electricity demand. Therefore, controlling and managing the charging time of EVs/PHEVs are effective approaches that are imperative for improving balancing in power system operation. We assumed travel patterns for EVs in a model of the future Tokyo power system and analyzed the power system loads, including the charging load of the EVs, under several charging control scenarios. We verified that charging time controls are substantially effective for reducing the fuel costs in the power system. Further, we found that load leveling under a multicar charging management scenario gave the best results in terms of the fuel costs in all cases.     

Intensely irradiated steel components: Plastic and fracture properties, and a new concept of structural design criteria for assuring the structural integrity

In order to develop a systematic and reasonable concept assuring the structural integrity of components under intense neutron irradiation, two basic tensile properties, true stress-true strain (TS-TS) curves and fracture strain, were investigated on an austenitic stainless steel and martensitic steel. Application of Swift equation is confirmed to a large plastic strain range of TS-TS curves. Fracture strain ?_f data were well correlated as ?_f + ?₀ = const. where ?₀ is the pre-strain representing the irradiation hardening.Based on those formulations and available experimental information, several critical issues to be dealt with in developing the concept were identified possible reduction in ductility, significant change in mechanical properties, remarkable cyclic softening and other unique cyclic properties observed during a high-cycle fatigue testing, and the redundancy of the plastic collapse concept to bending. Existing structural codes are all based on the assumption that there will be no significant changes in mechanical properties during operation, and of high ductility. Therefore, a new concept for assuring structural integrity is required for application not only to components with high ductility but also components with reduced ductility. First, potential failure modes were identified, and a new and systematic concept was proposed for preventing these modes of failure, introducing a new concept of categorizing the loadings by stability of deformation process to fracture (as type F and M loadings). Based on the basic concept, a detailed concept of how to protect against ductile fracture was given, and loading type-dependent limiting parameters were set.Finally, application of the detailed concept was presented, especially on determination of loading type (in numerical approach, the formulation of TS-TS curves and fracture strain derived above are needed), and on how to determine the limiting parameters as allowable limits. Experiments were done to identify the loading type of a tensile loading acting on a structure with a discontinuity. Tensile loadings acting on an intensely neutron-irradiated flat plate with a hole in the center cause plastic tensile instability and necking at the minimum ligament section but do not initiate any surface crack at the initiation of necking.     

Air vent in water chamber and surface coating on liner slides concerning auxiliary cooling system for the high temperature engineering test reactor

Experimental study was made to confirm the validity of new designs of the auxiliary cooling system for the high temperature engineering test reactor (HTTR). First, it is necessary to vent residence air in outlet side of water chamber of the auxiliary heat exchanger for the HTTR. Accordingly, we have proposed to mount a proper bend duct in the outlet side of the water chamber. Air vent is done by difference between pressures at both ends of the bend duct caused by the forced water circulation using the water pumps. From flow tests, it was confirmed that it is capable of venting the air through the bend duct by circulating the water in maximum capacity of the water pumps. Second, it is essential to prevent seizure and excessive wear of the liner slides of the auxiliary concentric hot gas duct for the HTTR at a service temperature of 950°C. Therefore, we have put forward to coat titanium nitride (TiN) on the surface of the liner slides made of nickel-based superalloy Hastelloy XR using the thermochemical vapor deposition method. As a result of seizure and wear tests, it was confirmed that the TiN coating film of 3 μm on the surface of Hastelloy XR is sufficient.