Sea Buckthorn Oil Tocopherol Extraction's By‐Product Utilization in Green Synthesis of Polyurethane Coating

The focus of the present study is to utilize a by‐product obtained during extraction of tocopherols, a valuable vitamin E compound, from sea buckthorn (SBT) oil and in doing so find a reliable alternative to petrochemical based polyols. Bio‐based polyurethane (PU) is prepared by using SBT oil based fatty acid methyl ester polyesteramide polyols (SBTPEP) with toluene diisocyanate (TDI). The fatty acid methyl ester is converted to the corresponding fatty amide by reaction with diethanolamine. The formed fatty amide is then esterified with phthalic anhydride to synthesize polyesteramide polyol. Characterization techniques used to evaluate polyesteramide polyol are Fourier‐transform infrared spectroscopy (FTIR) and NMR. The cured PU coating is also put through various mechanical tests to analyze the physical properties. The cured PU coating shows good surface and mechanical properties. It shows a gloss value of 87.4 and passes impact, adhesion, and chemical resistance tests. It is hydrophobic which is evident from its contact angle of 100.2°. It has good thermal stability which is evident by its glass transition temperature of 53.9 °C. Use of phthalic anhydride contributes to the bio‐based characteristics of synthesized PU. Practical Application: The present study presents a synthesis route which has minimal dependence on hazardous feedstock by utilization of green feedstock. The results obtained from physical and mechanical evaluations favor the use of this PU formulation in the coating sector. The adhesion and impact strength test results show potential application in the industrial sector coatings where the applied coat must be able to withstand high levels of physical stress and strain. The presence of aromatic rings and oil‐based moiety, that is the fatty acid hydrocarbon chain, contributes to the hydrophobic nature of the PU coating. Hydrophobic coatings have tremendous application in various fields such as marine coatings, automotive, electronics, and decorative coatings. These are potential fields of application for the synthesized green PU coating obtained from tocopherol extraction by‐products.     

Removal of fluoride using some lanthanum(III)‐loaded adsorbents with different functional groups and polymer matrices

Although fluoride is beneficial for human beings in small quantities, it causes dental fluorosis when consumed in larger quantities over a period of time. In recent years, considerable work has been conducted for the purpose of developing new and low cost absorbents for adsorptive removal of fluoride, especially chelating resins loaded with metal ions. In the present study, several types of adsorbents with different functional groups loaded with lanthanum(III) were prepared to be used for fluoride removal from water. The optimum conditions for loading lanthanum(III) on the adsorbents and the effects of pH and initial fluoride concentration as well as shaking time and solid–liquid ratio on the removal of fluoride have been investigated. Based on these fundamental data, the removal of fluoride from actual hot spring water was also tested as a practical application by comparing the efficiency of different adsorbents for the removal of fluoride from hot spring water. The following conclusions were obtained. (1) The different chemical composition and chemical structure of the polymer matrix play the most important role in fluoride adsorption, (2) strongly acidic adsorbents are more effective on fluoride removal at neutral pH than weakly acidic adsorbents, (3) the order of fluoride removal in the neutral pH range of 4.5–8.0 by the different La(III)‐loaded adsorbents employed in the present work is as follows: 200CT resin > POJRgel > IR124resin > SOJR gel ≥ CPAgel ≥ WK11 resin. The column experiments showed that the 200CT resin loaded with lanthanum(III) at pH 6.0 can be successfully employed for the removal of fluoride ions from actual hot spring water. Copyright © 2003 Society of Chemical Industry     

理解并控制数字马达控制系统的量化误差

设计数字马达控制系统时需要考虑的主要问题是选择合适的处理器,同时,处理器字长也至关重要。设计人员需要关注定点处理器中因定点数表示法而引起的量化误差问题。这些误差将会降低控制系统的性能,使设计人员无法最大限度地发挥出高级算法的优势。     

Dynamic problem of fractional order thermoelasticity for a thick circular plate with finite wave speeds

This article is aimed at determining the thermoelastic displacement, stress, and temperature in a thick circular plate of finite thickness and infinite extent whose lower and upper surfaces are traction free, subjected to a given axisymmetric temperature distribution. The problem is formulated in the context of fractional order thermoelasticity theory with finite wave speeds. Integral transform technique is used to obtain the general solution in Laplace transform domain. Inversion of the Laplace transforms is done using a numerical scheme. A mathematical model is prepared for a copper material plate. Thermoelastic stresses, temperature and displacement are shown graphically and the effects of fractional-order parameters are discussed.     

Transient thermoelastic problem of a nonhomogeneous rectangular plate

This article deals with the determination of temperature distribution, displacement, and thermal stresses in a rectangular plate with inhomogeneous material properties. All the material properties except Poisson’s ratio and density are assumed to be given by a simple power law in y coordinate. The system of fundamental equations formulated has been solved by integral transform method. The effects of thermal and mechanical inhomogeneity on temperature and thermal stress distributions are examined. Numerical calculations are performed by taking into account the variation in inhomogeneous property of shear modulus of elasticity and depicted graphically.     

Studies of microstructural,dielectric, and impedance spectroscopic properties of Bi0.617Y0.05Cu3Ti4O12 ceramic synthesized through semi-wet route

Bi_0.617Y_0.05Cu₃Ti₄O₁₂(BYCTO) was successfully synthesized through an economically semi-wet route using metals nitrates, acetate, and TiO₂ precursor and sintered at 1173 K for 8 h. The single phase of ceramic was authorized by XRD analysis. The crystallite size of BYCTO ceramic was calculated to be 62.3 nm through XRD measurement. The particle size obtained by TEM analysis was to be in the range of 55?±?7 nm. The average grain size observed through the SEM technique was 0.783 μm. The route means square roughness, as well as average roughness, were determined to be 0.224 μm and 0.179 μm by atomic force microscope. The dielectric constant (?′) of BYCTO was measured to be 1481 at 307 K and 100 Hz. The tangent loss (tan δ) was observed to be in the range of 0.13–0.29 at all selected temperatures (307–487 K) and 10 kHz which is lower than that of Bi_2/3Cu₃Ti₄O₁₂. The oxidation state of all metal present in the ceramic material was verified by XPS analysis.

     

2D Black Phosphorus for Energy Storage and Thermoelectric Applications

Recent progress in the currently available methods of producing black phosphorus bulk and phosphorene are presented. The effective passivation approaches toward improving the air stability of phosphorene are also discussed. Furthermore, the research efforts on the phosphorene and phosphorene‐based materials for potential applications in lithium ion batteries, sodium ion batteries, and thermoelectric devices are summarized and highlighted. Finally, the outlook including challenges and opportunities in these research fields are discussed.     

Substrate quality impact on the carrier concentration of undoped annealed HgCdTe LPE layers

The impact of Te precipitates and impurities, in CdZnTe or CdTe substrates, on grown liquid phase epitaxy (LPE) HgCdTe layer hole concentrations was studied. The carrier concentrations in capped annealed LPE HgCdTe layers grown on CdZnTe substrates with large densities of Te precipitates are frequently significantly higher than those expected for HgCdTe annealed under Hg-deficient conditions. The carrier concentration in the LPE layer, due to the diffusion of copper ions from contaminated CdTe substrates into the layer, is strongly affected by the polarity of the (111)-oriented substrates. Layers grown on the (111)A face showed very high concentrations of Cu, whereas in those grown on the (111)B face normal carrier concentrations were achieved. These phenomena are discussed on the basis of defects formed either in the epilayer or in the layer-substrate interface.     

Continuum damage modeling of dynamic crack velocity,branching, and energy dissipation in brittle materials

This study is aimed at evaluating continuum scale predictions of dynamic crack propagation and branching in brittle materials using local damage modeling. Classical experimental results on crack branching in PMMA and the corresponding nonlocal modeling results by Wolff et al. (Int J Numer Meth Eng 101(12):933, 2015) are used as a benchmark. An isotropic damage model based on a frame-invariant effective strain is adapted. Mesh objectivity is achieved by calibrating the damage model for a suitable element size and subsequently retaining that mesh size in all subsequent analyses. Crack propagation and branching are predicted by simulating accurately the test conditions. It is found that a local, rate-independent damage model considerably overpredicts the dynamic crack velocity and the extent of crack branching. Subsequently, the effect of various strain rate-dependent phenomena, viz. material viscoelasticity, rate-dependent strength, fracture energy, and failure strain is evaluated. Incorporating the material strain rate effects is found to improve the predictions and match the test data. In this regard, radially scaling the damage law is found to work the best. Despite an overprediction of micro-branching, the macro-crack branching is found to occur in agreement with the Yoffe instability criterion. Overall, various experimentally observed aspects of dynamic cracks are reproduced, including acceleration of cracks to a steady state velocity, increased micro-branching and macro-branching with increased strain rates, and crack velocity dependence of energy dissipation and fracture surface area.