Preparation,characterization, and swelling and drug release properties of a crosslinked chitosan‐polycaprolactone gel

For applications in biotechnology to prepare biopolymers containing functional groups is essential. In addition, these materials have to be strong to provide physical support for practical applications. Recently, chitosan, polycaprolactone (PCL), and their various combinations were used for this purpose. In this work, we described the preparation and characterization of a new biodegradable polymeric gel containing chitosan and PCL. The gel preparation reactions were performed in suitable acetic acid solutions to obtain the products in high yields. A crosslinking agent was added to produce crosslinked gels. Swelling behavior of chitosan/PCL gels in different compositions was studied, and the results were compared. The chitosan/PCL gels show a rather large equilibrium swelling in water and in the phosphate buffered saline solution. Acrylic acid (AA) was added to these gels during preparation process to obtain a stable material for various applications. These polymeric gels were characterized by Fourier transform infrared. Their physical and morphological properties were investigated by using differential scanning calorimeter and scanning electron microscope techniques, respectively. Cell growth experiments indicate that chitosan, a positively charged polysaccharide, is not suitable for cell proliferation studies. On the other hand, the drug release studies were successful and, 59% of lidocaine, was released from a chitosan/PCL/AA hydrogel in buffer solution at pH = 7.4 at 37°C. © 2010 Wiley Periodicals, Inc. J Appl Polym Sci, 2010     

Zinc and tin xanthates in the coordination polymerization of propylene oxide

The polymerization of propylene oxide with zinc and tin xanthates was studied. Polymerization with both systems was found to be a zeroth‐order, nonterminating process, where the molecular weight was controlled by transfer reactions. It is discussed that these observations were consistent with a mechanism in which the rate‐determining step was the addition of monomer on the growing chain rather than the coordination of the monomer to active sites. These catalysts turned out to be quite stable, even under semiclosed conditions. With zinc isopropyl xanthate, high conversions in short polymerization times could be obtained. The product had a very broad molecular weight distribution and could be split into crystallizable and amorphous fractions. The crystallizable fractions consisted of stereoregular segments separated from each other by stereoirregularities or regioirregularities. The degrees of polymerization of stereoregular segments (S₁'s) were estimated from melting point measurements. It was found that the melting points and, hence, average S₁ values changed in different fractions. It was concluded that there was only one type of active center; however, the rates of wrong additions (e.g., head‐to‐head addition) of incoming monomer controlled the average S₁ value of the chain. © 2011 Wiley Periodicals, Inc. J Appl Polym Sci, 2011     

Effect of Compaction Pressure on Structural and Superconducting Properties of Bi-2223 Superconductors

In this work, effects of compaction pressure on the structural and superconducting properties of BSCCO ceramic superconductors were investigated. The study was carried out on two systems which were, System I: Bi_1.7Pb_0.3Sr₂Ca₂Cu₃O _y and System II: Bi_1.6Pb_0.3Ag_0.1Sr₂Ca₂Cu₃O _y , respectively. Ceramic powders were prepared by conventional solid-state reaction method and sintered at 850°C after compaction at five different pressures in the 150–750 MPa range. Critical temperatures of samples were determined by resistivity-temperature determinations made by four-point probe method in liquid nitrogen conditions. XRD analysis was conducted by powder X-ray diffraction method. Morphology of the grains present in the samples were determined by using scanning electron microscope (SEM) photographs at 2 K× and 2.5 K× magnifications for System I and System II, respectively. Sintered densities of the superconducting ceramics were measured by Archimedes water displacement method and unit cell parameters were additionally obtained from XRD data. T _c values for System I was determined to be in the 109–115 K with sample D having the highest T _c of 115 K while T _c varied in the 104–109 K range and sample B had the highest T _c value of 109 K for System II. The transition width, which is a sign of the purity of the samples, was determined to be narrow for both systems. The data obtained from X-ray diffraction measurements have shown that 2223 high-T _c phase was dominant in both systems. The determination of the optimum pellet compaction pressure for BSCCO ceramic superconductors was the main purpose of this work. The results of this work indicated that compaction at around 450 MPa improves the superconducting and structural properties of the BSCCO ceramic superconductors.     

Ion chromatographic determination of perchlorate in foods consumed in Hatay region

Recently, the exposure to perchlorate was emphasised as an important risk factor for human and especially newborn health. A number of studies were focused on this matter. In this study, samples of soil, vegetable (cabbage, spinach, lettuce, carrot, tomato, red cabbage), fruit (orange, mandarin, lemon, grapefruit), water, milk and fish were taken from 8 different regions of Hatay (Samanda?, K?r?khan, Reyhanl?, Amik Plain, Dörtyol, Yaylada??, Alt?nözü, Erzin). An ion chromatography system (Shimadzu C196-E039A model) was used to determine the concentrations of perchlorate in the samples. 2.5 mM Phthalic acid and 2.4 mM tris (hydroxymethyl)aminomethane solutions (pH = 4) were used as the mobile phase. A flow rate of 1.5 ml min⁻¹ and oven temperature of 40 °C were used during the analysis. The foods had perchlorate concentrations in the range of 0.236–1.218 μg kg⁻¹. The perchlorate concentration varied from 0.30 ± 0.01 to 0.94 ± 0.02 μg l⁻¹ in milk samples. Perchlorate concentrations were determined to be lower in the drinking waters (0.44 ± 0.03 μg l⁻¹) compared to irrigation waters (0.59 ± 0.03 μg l⁻¹). Perchlorate concentrations of the fish samples were ranged from 0.38 ± 0.01 to 0.61 ± 0.01 μg kg⁻¹.     

Nonlinear static response of laminated composite plates by discrete singular convolution method

In this paper, large deflection analysis of laminated composite plates is analysed. Nonlinear governing equation for bending based on first-order shear deformation theory (FSDT) in the von Karman sense is presented. These equations have been solved by the method of discrete singular convolution (DSC). Regularized Shannon’s delta (RSD) kernel and Lagrange delta sequence (LDS) kernel are selected as singular convolution to illustrate the present algorithm. The effects of plate aspect ratio, fiber orientation, boundary conditions, thickness-to-side ratio, and applied load on the nonlinear static response of the laminated plate are investigated.     

Effect of cation contamination and hydrated pressure loading on the mechanical properties of proton exchange membranes

Perfluorosulfonic acid (PFSA) polymer membranes are widely used as electrolyte thin films to transport protons in proton exchange membrane (PEM) fuel cells. The mechanical degradation of the membrane represents a common failure mode that limits the operational life of the fuel cells. In the present work, effect of contamination related to cation exchange on the mechanical reliability of PEMs was investigated. We applied the bulge test technique to assess the mechanical properties of Nafion^® PFSA membranes simulating pressure loading on hydrated PEMs in fuel cells. The corresponding elastic moduli of Nafion^® before and after cation exchange were analyzed and compared with the results measured by uniaxial tension experiments at selected humidity conditions, showing increasing stiffness with the increase of cation radius. We also used the out-of-plane tearing test method to characterize the fracture behaviors of PEMs. The effects of cation exchange and water absorption on mechanical and fracture properties of PEMs at different temperatures are discussed in terms of cation and water interactions with the molecular structure of PFSA polymers.     

3D Path Planning for Multiple UAVs for Maximum Information Collection

This paper addresses the problem of path planning for multiple UAVs. The paths are planned to maximize collected amount of information from Desired Regions (DR) while avoiding Forbidden Regions (FR) violation and reaching the destination. The approach extends prior study for multiple UAVs by considering 3D environment constraints. The path planning problem is studied as an optimization problem. The problem has been solved by a Genetic Algorithm (GA) with the proposal of novel evolutionary operators. The initial populations have been generated from a seed-path for each UAV. The seed-paths have been obtained both by utilizing the Pattern Search method and solving the multiple-Traveling Salesman Problem (mTSP). Utilizing the mTSP solves both the visiting sequences of DRs and the assignment problem of “which DR should be visited by which UAV”. It should be emphasized that all of the paths in population in any generation of the GA have been constructed using the dynamical mathematical model of an UAV equipped with the autopilot and guidance algorithms. Simulations are realized in the MATLAB/Simulink environment. The path planning algorithm has been tested with different scenarios, and the results are presented in Section 6. Although there are previous studies in this field, this paper focuses on maximizing the collected information instead of minimizing the total mission time. Even though, a direct comparison of our results with those in the literature is not possible, it has been observed that the proposed methodology generates satisfactory and intuitively expected solutions.     

The effects of planting time on fatty acids and tocopherols in chickpea

In Turkey, as an important producer, chickpea is generally planted in March and April during spring. However, spring plantings have the disadvantage of unstable yield and quality from year to year due to irregularity in spring precipitation. In this research, fatty acids and tocopherol contents in different chickpea genotypes were investigated for consecutive 2 years with both autumn and spring plantings. Tocopherol analyses were carried out by using a high performance liquid chromatography. Gamma tocopherol was the major component of total tocopherol content and it ranged between 15.34 and 42.09 mg kg⁻¹. Alpha tocopherol content ranged between 4.55 and 10.69 mg kg⁻¹. Depending on planting time, the values of tocopherol components changed significantly. The mean values for alpha tocopherol were 6.77 mg kg⁻¹ for autumn and 7.55 mg kg⁻¹ for spring plantings; while the mean values for gamma tocopherol were 33.32 mg kg⁻¹ for autumn and 22.50 mg kg⁻¹ for spring plantings, respectively. Fatty acids, quantified using a gas chromatography, indicated that differences among the genotypes were significant. The values for autumn planting were generally higher than those of spring planting. The values of major fatty acids changed between 18.57 and 35.23% for oleic acid and 47.15 and 63.44% for linoleic acid. According to planting time the mean values for oleic acid changed between 21.23 and 30.52% and for linoleic acid between 51.77 and 60.79%.     

Some empirical equations for oxypolymerization of linseed oil

In this study, oxypolymerization of linseed oil was investigated. The reaction was carried out at 80, 120 and 200 °C with the airflow of 2 and 5 L/min. Changes in viscosity, density, refractive index, iodine and peroxide values were determined during reaction and some empirical equations were obtained. Additionally, a kinetic investigation was achieved and, the reaction order and the rate constant were determined for each reaction. Change in the reaction order with the temperature could be explained with different reaction mechanism for each temperature. Rheological behavior of the final product was investigated using Bingham, Power-law and Casson equations. It was found that the sample behaved as non-Newtonian fluid at high temperature.