Effect of pre-oxidation on reactivity of chars in steam

The effects of pre-oxidation of char from Taiheiyo coal, a non-caking bituminous coal, in the 400–550 °C temperature range on its gasification reactivity with N₂-H₂O at 0.1 MPa (steam partial pressure of 13.2 kPa) have been investigated. The pre-oxidation of char markedly enhances gasification rates at temperatures between 800 and 900 °C. Reactivity is found to parallel the burn-off level during preoxidation at low temperatures (400–430 °C), whereas at relatively high temperatures (480–550 °C), the burn-off level only affects the reactivity slightly. The amount of CO and CO₂ evolved from the preoxidized char by heat treatment is proportional to the burn-off level at low temperatures (400–430 °C), being closely related to the enhancement of the gasification reactivity in steam.     

First nuclear transmutation of 237Np and 241Am by accelerator-driven system at Kyoto University Critical Assembly

This study demonstrates, for the first time, the principle of nuclear transmutation of minor actinide (MA) by the accelerator-driven system (ADS) through the injection of high-energy neutrons into the subcritical core at the Kyoto University Critical Assembly. The main objective of the experiments is to confirm fission reactions of neptunium-237 (²³⁷Np) and americium-241 (²⁴¹Am), and capture reactions of ²³⁷Np. Subcritical irradiation of ²³⁷Np and ²⁴¹Am foils is conducted in a hard spectrum core with the use of the back-to-back fission chamber that obtains simultaneously two signals from specially installed test (²³⁷Np or ²⁴¹Am) and reference (uranium-235) foils. The first nuclear transmutation of ²³⁷Np and ²⁴¹Am by ADS soundly implemented by combining the subcritical core and the 100 MeV proton accelerator, and the use of a lead-bismuth target, is conclusively demonstrated through the experimental results of fission and capture reaction events.     

Dual-Mode Space-Temporal Simultaneous Processing Equalizer

A tapped delayed line adaptive array antenna (TDL-AAA) and a space-temporal simultaneous processing equalizer (ST-SPE) are proposed as simple space-temporal equalizers based on minimum mean square error (MMSE) criterion. The ST-SPE has a compact hardware with a small number of taps compared to that of the TDL-AAA. The ST-SPE can reduce the computational complexity of the space-temporal joint equalization and it works effectively under the minimum phase condition such as appeared at line-of-sight (LOS) propagation environments at a high antenna height base station. However the ST-SPE cannot work under a non-minimum phase condition caused under N-LOS (non-line-of-sight). On the other hand, the TDL-AAA whose reference signal is synchronized at the center tap (TDL-AAA_C) can work even in the non-minimum phase condition. In this paper, we propose a dual-mode space-temporal simultaneous processing equalizer (Dual-mode ST-SPE) which has a simple configuration and also works in non-minimum phase condition. The Dual-mode ST-SPE can reduce the computational complexity compared to the TDL-AAA_C. Yoshihiro Ichikawa received the B.E. degree in department of communication engineering, in National Defense Academy in 1995, and M.E. and D.E. degree from Ibaraki University in 2001 and 2004, respectively. He joined the Japan Air Self Defense Force in 1995. His research interests are an adaptive algorithm, an antenna design, and an adaptive array antenna. Shigeki Obote received his B.E., M.E. and D.E. degrees in electrical and electronic engineering from Tottori University, Tottori, Japan, in 1996, 1998 and 2000, respectively. Since 2000, he has been with department of media and telecommunications engineering, faculty of engineering, Ibaraki University, Ibaraki, Japan, where he is currently a associate professor. His research interests are in adaptive array antenna and wireless communications systems. Kenichi Kagoshima received the B.E., M.E. and D.E. degrees in electronics engineering from the Tokyo Institute of Technology, Tokyo, Japan, in 1969, 1971, and 1974, respectively. He joined the Nippon Telegraph and Telephone Corporation (NTT) Laboratory in 1974 and researched and developed many kinds of radio communication antennas. Since 1997, he has been a professor at Ibaraki University, Ibaraki, Japan. Dr. Kagoshima was a Secretary and Treasure, Vice Chairman, and Chairman of the IEEE AP-S Tokyo Chapter in 1992, 1993, and 1994, respectively. He was a chair of antennas and propagation professional group of IEICE in 1999 and 2000. In 1973, he received the Yonezawa Prize for Young Engineers and 1998, best paper award from IEICE, respectively.     

The effect of chemical reaction on the mixing flow between aqueous solutions of acetic acid and ammonia

The basic characteristics of the reacting mixing flow of two streams were investigated. The reaction between aqueous solutions of ammonia and acetic acid, which produces ammonium acetate, was investigated in terms of the effect on the fluid–fluid interface of the mixing flow relative to fluids that did not react. The reaction between these solutions was negligibly exothermic, and there were minimal differences in density. The velocity field in the reacting mixing flow was quantitatively measured using high-speed time-resolved particle image velocimetry (PIV) and the behavior of the mixing flow was qualitatively investigated using laser-induced fluorescence (LIF). The jet width, the velocity field, the kinetic energy and the turbulent intensities are qualitatively estimated and discussed. It was found that the chemical reaction resulted in the suppression of the mixing flow.     

Component-based robot system design for grasping tasks

The paper presents a robot system design with highly reusable components for a component-based robot system for manipulation tasks. The robot system is designed based on the analysis of manipulation tasks using a unified modeling language use case diagram. For a service robot with locomotion and manipulation mechanisms, reusability of robot system components is improved by adopting the proposed design. Our structure consists of scenario, task, robot information management server, data analyzer, sensor hardware controller, skill, and motion hardware controller on a component-based robot system. Based on the proposed robot system, we implemented a component-based robot system and subsequently realized a grasping motion by a service robot.     

Mixing speed-controlled gold nanoparticle synthesis with pulsed mixing microfluidic system

Gold nanoparticles with diameters of a few tens of nanometer and a narrow size distribution were synthesized using a pulsed mixing method with a microfluidic system which consists of a Y-shaped mixing microchannel and two piezoelectric valveless micropumps. This mixing method enables control of the mixing speed of gold salts and reducing agent by changing the switching frequency of the micropumps, which was our focus to improve the particle size distribution, which is an essential parameter in gold nanoparticle synthesis. In the proposed method, the mixing time was inversely proportional to the switching frequency and the minimum mixing time was 95 ms at a switching frequency of 200 Hz. During synthesis experiments, the mean diameter of the synthesized gold nanoparticles was found to increase, and the coefficient of variation of particle size was found to decrease with decreasing mixing time. We successfully improved the coefficient of variation to less than 10% for a mean diameter of around 40 nm.     

Viscoelastic behavior of poly(butyl methacrylate) densely grafted on silica nanoparticles

A series of poly(butyl methacrylate)s (PBMAs) with various molar masses (33 000–270 000 g mol^?1), which were densely grafted on fumed silica nanoparticles (PBMA–SiO₂), were synthesized by surface‐initiated atom transfer radical polymerization. The dynamic viscoelastic behavior of PBMA–SiO₂ was systematically investigated in the solid and molten states with oscillatory strains, and compared to that of a conventional nanocomposite (PBMA/SiO₂). The storage moduli of PBMA–SiO₂ and PBMA/SiO₂ are equivalent in the solid state, whereas the storage modulus of PBMA–SiO₂ is lower than that of PBMA/SiO₂ in the molten state, especially at high silica loading. This is because the formation of a network structure composed of the silica nanoparticles in PBMA–SiO₂ is strongly suppressed by the polymer brushes on the particles. In contrast, even at low silica loading, the PBMA–SiO₂ system exhibits a gel‐like behavior resulting from a steric repulsion between the composite particles, because all of the tethered polymers behave as bound polymers. Copyright © 2011 Society of Chemical Industry     

Flight Model Performance of 640-GHz Superconductor–Insulator–Superconductor Mixers for JEM/SMILES Mission

Performances of 640-GHz Superconductor–Insulator–Superconductor (SIS) mixers developed for the Superconducting Submillimeter-Wave Limb-Emission Sounder (SMILES) mission are described. SMILES, launched in September 2009, is the first mission to observe atmosphere from space using superconducting mixers. Ground test performances of the SIS mixers show very flat gain and noise characteristics in their observation bands in compliance with the specifications required for SMILES.