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11.
    
Chemical vapor deposition of a thin titanium dioxide (TiO2) film on lightweight native nanocellulose aerogels offers a novel type of functional material that shows photoswitching between water‐superabsorbent and water‐repellent states. Cellulose nanofibrils (diameters in the range of 5–20 nm) with native crystalline internal structures are topical due to their attractive mechanical properties, and they have become relevant for applications due to the recent progress in the methods of their preparation. Highly porous, nanocellulose aerogels are here first formed by freeze‐drying from the corresponding aqueous gels. Well‐defined, nearly conformal TiO2 coatings with thicknesses of about 7 nm are prepared by chemical vapor deposition on the aerogel skeleton. Weighing shows that such TiO2‐coated aerogel specimens essentially do not absorb water upon immersion, which is also evidenced by a high contact angle for water of 140° on the surface. Upon UV illumination, they absorb water 16 times their own weight and show a vanishing contact angle on the surface, allowing them to be denoted as superabsorbents. Recovery of the original absorption and wetting properties occurs upon storage in the dark. That the cellulose nanofibrils spontaneously aggregate into porous sheets of different length scales during freeze‐drying is relevant: in the water‐repellent state they may stabilize air pockets, as evidenced by a high contact angle, in the superabsorbent state they facilitate rapid water‐spreading into the aerogel cavities by capillary effects. The TiO2‐coated nanocellulose aerogels also show photo‐oxidative decomposition, i.e., photocatalytic activity, which, in combination with the porous structure, is interesting for applications such as water purification. It is expected that the present dynamic, externally controlled, organic/inorganic aerogels will open technically relevant approaches for various applications.  相似文献   
12.
    
The copolymerization and terpolymerization reactions of the vinyl‐substituted phenolic stabilizers, 6‐tert‐butyl‐2‐(1,1‐dimethylhept‐6‐enyl)‐4‐methylphenol, o‐allylphenol, 4‐methylstyrene‐2,6‐di‐tert‐butylphenol and 2,6‐di‐tert‐butyl‐4‐allylphenol, with propene and carbon monoxide, by using the solvent‐stabilized palladium(II ) phosphine complex [Pd(dppp)(NCCH3)2](BF4)2 (dppp, 1,3‐bis(diphenylphosphino)propane) as a catalyst precursor and methanol as a co‐catalyst, is described. The influence of functional α‐olefins/CO units, distributed statistically along the propene/carbon monoxide (P/CO) copolymer backbone, on the molecular weight, glass transition temperature (Tg), elastic behavior and stability of the high‐molecular‐weight P/CO copolymer has been investigated. Loss of both elasticity and transparency were observed upon incorporating o‐allylphenol as a termonomer. The terpolymers, which contain phenolic stabilizers, were shown to be more stable when compared to the stabilizer‐free polyketones. In contrast to the propene/carbon monoxide copolymer, no degradation was observed for the 2,6‐di‐tert‐butyl‐4‐allylphenol/P/CO terpolymer; instead, the molar masses increased. Copyright © 2004 Society of Chemical Industry  相似文献   
13.
Calorimetric low temperature detectors (CLTD’s) have been included in a B-ToF setup, that has already been used several times to perform energy loss measurements at the accelerator laboratory of the University of Jyväskylä. The new experimental setup enabled a precise determination of stopping power data for 0.05–1 MeV/u (^{131}) Xe ions in carbon, nickel and gold. The results are presented and compared to data from literature and theoretical predictions. As a by-product, due to the excellent energy resolution of CLTD’s for heavy ions at low energies, an observation of channeling effects in very thin polycrystalline targets and a determination of the channeling energy loss for 0.1–0.5 MeV/u (^{131}) Xe-ions in Ni- and Au-absorbers was possible.  相似文献   
14.
Fatigue behavior of polycrystalline copper of two different grain sizes was studied using constant and randomly varying plastic strain amplitude tests. The different regimes in the ess-curves of large-grained samples (d? 2.0 mm) were found to be reflected also in the measured fatigue lives in both test modes. The variable amplitude fatigue lives of the small-grained samples (d? 0.03 mm) seemed to follow the Coffin–Manson linear law. The damage accumulation rate in variable amplitude tests was found to be lower than in the corresponding constant amplitude tests, e.g. when expressed as cumulative plastic strains to failure. The fatigue life predictions based on the Palmgren–Miner rule, rain-flow analysis and the constant amplitude life data measured in this work were also conservative.  相似文献   
15.
We describe a general-purpose parallel code for computing accurate solutions to large computationally demanding, 3D, nonlinear magnetostatic problems. The code, CORAL, is based on a volume integral equation formulation. Using an IBM SP parallel computer and iterative solution methods, we successfully solved the dense linear systems inherent in such formulations. A key component of our work was the use of the PETSc library, which provides parallel portability and access to the latest linear algebra solution technology. Copyright © 1999 John Wiley & Sons, Ltd.  相似文献   
16.
This paper presents a method for generating tetrahedral meshes in three-dimensional primitives. Given a set of closed and convex polyhedra having non-zero volume and some mesh controlling parameters, the polyhedra are automatically split to tetrahedra satisfying the criteria of standard finite element meshes. The algorithm tries to generate elements close to regular tetrahedra by maximizing locally the minimum solid angles associated to a set of a few neighbouring tetrahedra. The input parameters define the size of the tetrahedra and they can be used to increase or decrease the discretization locally. All the new nodes, which are not needed to describe the geometry, are generated automatically.  相似文献   
17.
    
Software architecture contains, in addition to its structural part, interaction patterns that can be regarded as part of the architectural solution of the system. The interaction patterns define architecturally significant behavior of the software system. In this paper we propose a visual modeling language, behavioral profiles, for specifying architecturally significant behavioral rules for an application. The language is built on the Unified Modeling Language (UML), which is a visual language widely used in software development. We show how behavioral profiles can be used to support software designers in creating behavioral models that conform to some predefined rules and for ensuring that an application behaves correctly with respect to the rules given in the profiles. A tool called Bebop was built to support software engineers in behavioral profile‐based design and analysis of program behavior. To evaluate the approach and the tools in different application domains, they are utilized in three cases. The size of the applications used in the cases varies from small to quite large software systems, and from academic to industrial ones. The examples demonstrate how the approach presented can be used in practice for different steps in a software engineering process. The examples cover specializing an application framework and monitoring the program execution in run‐time. In addition, they show how behavioral profiles can be used to support guided program comprehension and to validate program execution by analyzing execution traces. Copyright © 2010 John Wiley & Sons, Ltd.  相似文献   
18.
Highly porous nanocellulose aerogels can be prepared by vacuum freeze-drying from microfibrillated cellulose hydrogels. Here we show that by functionalizing the native cellulose nanofibrils of the aerogel with a hydrophobic but oleophilic coating, such as titanium dioxide, a selectively oil-absorbing material capable of floating on water is achieved. Because of the low density and the ability to absorb nonpolar liquids and oils up to nearly all of its initial volume, the surface modified aerogels allow to collect organic contaminants from the water surface. The materials can be reused after washing, recycled, or incinerated with the absorbed oil. The cellulose is renewable and titanium dioxide is not environmentally hazardous, thus promoting potential in environmental applications.  相似文献   
19.
    
This paper introduces a geometric solution strategy for Laplace problems. Our main interest and emphasis is on efficient solution of the inverse problem with a boundary with Cauchy condition and with a free boundary. This type of problem is known to be sensitive to small errors. We start from the standard Laplace problem and establish the geometric solution strategy on the idea of deforming equipotential layers continuously along the field lines from one layer to another. This results in exploiting ordinary differential equations to solve any boundary value problem that belongs to the class of Laplace's problem. Interpretation in terms of a geometric flow will provide us with stability considerations. The approach is demonstrated with several examples. Copyright © 2015 John Wiley & Sons, Ltd.  相似文献   
20.
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