一氧化碳和二氧化碳加氢制乙醇热力学模拟

为验证一氧化碳(CO)和二氧化碳(CO2)加氢制乙醇的可行性,并为相关实验研究提供理论依据,采用HSC Chemistry软件对CO和CO2加氢制乙醇反应进行热力学分析,考察反应压力、反应温度和氢碳摩尔比对原料转化率和产物选择性等指标的影响.结果表明:该反应在最佳条件压力3 M Pa、温度150℃、氢碳摩尔比3:1(CO/CO2比1/1)时,乙醇选择性为60.87％,甲醇选择性26.33％,氢气转化率50％,CO2转化率100％,CO转化率100％.实验表明:乙醇选择性与热力学理论值还存在差距,后续对催化剂进行改性是下一步研究的重点.     

塔河碳酸盐岩油藏单井注水吞吐替油机理研究

目前塔河碳酸盐岩油藏存在着油藏产能下降快,地层压力保持水平低的问题。从分析缝洞型碳酸盐岩油藏的微观孔隙结构着手,通过地应力分析和岩心试验的方法来研究塔河油田部分油井初期产能很高,但很快就能量衰竭、产量递减快的原因。进一步探讨了这部分井注水、升压、闷井、回采机理。为研究缝洞型碳酸盐岩油藏提供一种思路,为合理制定进一步开发方案作参考。     

Generalized-Extended-State-Observer and Equivalent-Input-Disturbance Methods for Active Disturbance Rejection: Deep Observation and Comparison

Active disturbance-rejection methods are effective in estimating and rejecting disturbances in both transient and steady-state responses.This paper presents a deep observation on and a comparison between two of those methods:the generalized extended-state observer(GESO) and the equivalent input disturbance(EID) from assumptions,system configurations,stability conditions,system design,disturbance-rejection performance,and extensibility.A time-domain index is introduced to assess the disturbance-r...     

自动捕捉平衡系数试验电流工具设计

在电梯平衡系数传统测量方法中,存在电梯轿厢和对重平衡点难以判断、人为因素导致测量误差偏大、测量不准导致效率低等问题,为解决这些问题,设计出一款基于光电传感器和霍尔传感器的电流自动捕捉工具,除能够高效准确识别电梯轿厢和对重平衡点的位置外,还能通过无线信号传输处理,利用钳形电流表精确捕捉平衡点位置的电流值。经测试使用,该工具系统消除了在平衡系数测量过程中捕捉电流值的人为因素影响,并解决了无机房不能准确判断平衡点问题,有效的提高了检验工作的准确性和效率。     

乳化液浓度的自动配比和在线检测

提出了基于PLC控制技术的乳化液自动配液系统的新型结构和工作原理,把乳化液浓度的检测与自动配比有机结合起来,在自动配液的同时,能够实现对乳化液浓度的“在线检测”和“实时监控”,从而大大提高了乳化液配制的自动化水平。     

矿井矸石运输系统的改造及其设备应用

针对当前矿井矸石运输系统存在的缺陷及矸石山堆积对日常生产的影响,提出了闭环式排矸系统,以新义矿为实际模型,阐述了闭环式排矸系统处理矸石的方法及其关键设备.系统建成投入使用后,取得了良好的效果.     

Formation of Gold and Silver Nanoparticle Arrays and Thin Shells on Mesostructured Silica Nanofibers

Mesostructured silica nanofibers synthesized in high yields with cetyltrimethylammonium bromide as the structure‐directing agent in HBr solutions are used as templates for the assembly of Au and Ag nanoparticles and the formation of thin Au shells along the fiber axis. Presynthesized spherical Au and Ag nanoparticles are adsorbed in varying amounts onto the silica nanofibers through bifunctional linking molecules. Nonspherical Au nanoparticles with sharp tips are synthesized on the nanofibers through a seed‐mediated growth approach. The number density of nonspherical Au nanoparticles is controlled by varying the amount of seeded nanofibers relative to the amount of supplied Au precursor. This seed‐mediated growth is further used to form continuous Au shells around the silica nanofibers. Both the Au‐ and Ag‐nanoparticle/silica‐nanofiber hybrid nanostructures and silica/Au core/shell fibers exhibit extinction spectra that are distinct from the spectra of Au and Ag nanoparticles in solution, indicating the presence of new surface plasmon resonance modes in the silica/Au core/shell fibers and surface plasmon coupling between closely spaced metal nanoparticles assembled on silica nanofibers. Spherical Au‐ and Ag‐nanoparticle/silica‐nanofiber hybrid nanostructures are further used as substrates for surface‐enhanced Raman spectroscopy, and the enhancement factors of the Raman signals obtained on the Ag‐nanoparticle/silica‐nanofiber hybrid nanostructures are 2 × 10⁵ for 4‐mercaptobenzoic acid and 4‐mercaptophenol and 7 × 10⁷ for rhodamine B isothiocyanate. These hybrid nanostructures are therefore potentially useful for ultrasensitive chemical and biological sensing by using molecular vibrational signatures.     

QY200型直角切药机曲柄摇杆机构运动分析

通过对直角切药机结构的分析,得出切药长度与可调摇杆长度的关系,从而使切药长度的精确调节成为现实,因切药长度是衡量切药机性能的最重要指标之一,所以切药长度的理论分析对提高切药机的质量有重要意义.     

Experimental study on method of estimating strength of weld metal in steel structure

We conducted the welding experiment using three kinds of test piece, actual size, diaphragm and butt joint. Then, we examined the influence on strength, cooling time and carbon equivalent of weld metal by welding conditions on the different test pieces. We calculated an estimate of cooling time and chemical components. Consequently, we concluded that the strength of weld metal can be estimated by heat input, interpass temperature, carbon equivarent of welding wire and shape of test piece.     

Eliminating the Influence of the Perturbed Reference Wave in Electron Holography

Abstract

A method is developed to eliminate the influence of the perturbed reference wave when long-range electromagnetic fields are investigated by electron holography. Based on phase relationships between the reference wave and the object wave, with digital reconstruction and data processing, we can extract the phase of an object wave from the phase difference between the object wave and the perturbed wave, which is always obtained in normal reconstruction. An example of one-dimension electromagnetic fields is given to verify this method.