Continuous Synthesis of Device‐Grade Semiconducting Polymers in Droplet‐Based Microreactors

A method is reported for the controlled synthesis of device‐grade semiconducting polymers, utilizing a droplet‐based microfluidic reactor. Using poly(3‐hexylthiophene) (P3HT) as a test material, the reactor is shown to provide a controlled and stable environment for polymer synthesis, enabling control of molecular weight via tuning of flow conditions, reagent composition or temperature. Molecular weights of up to 92 000 Da are readily attainable, without leakage or reactor fouling. The method avoids the usual deterioration in materials quality that occurs when conventional batch syntheses are scaled from the sub‐gram level to higher quantities, with a prototype five‐channel reactor producing material of consistent molecular weight distribution and high regioregularity (>98%) at a rate of ≈60 g/day. The droplet‐synthesized P3HT compares favorably with commercial material in terms of absorption spectrum, polydispersity, regioregularity, and crystallinity, yielding power conversion efficiencies of up to 4% in bulk heterojunction solar cells with [6,6]‐phenyl‐C61‐butyric acid methyl ester.     

Characteristics of students who enroll and succeed in psychology Web-based classes.

This study compared the cognitive-motivational and demographic characteristics of students enrolled in 3 Web-based sections of Psychological Statistics with their counterparts in 3 conventional (face-to-face) sections of this course. No demographic differences were found, however, cyberstudents exhibited a greater external locus of control than conventional students. The authors also investigated whether there were any predictors of student performance in Web courses. Measures of on-line course activity (e.g., homepage hit rate), a high need for cognition, and an internal locus of control were predictive of cyberstudent success. The authors discuss the implications of these results for instructors who are considering the design and implementation of Web-based classes. (PsycINFO Database Record (c) 2010 APA, all rights reserved)     

Reactive magnetron sputtering of indium tin oxide films on acrylics – morphology and bonding state

Indium tin oxide (ITO) films were deposited on acrylics by low temperature reactive magnetron sputtering. The effects of oxygen flow and bias voltage on the microstructure, surface morphology and bonding state of films were evaluated. In this investigation, X-ray photoelectron spectroscopy, X-ray diffraction, Atomic force microscope were used. It was found that the grain size of ITO films increased and surface roughness decreased with the increase of oxygen flow rate. The XPS spectra of In 3d and Sn 3d indicated that the oxygen flow had little effect on the binding energy of ITO films. The relative strength of O²⁻_II increased, while that of O²⁻_I decreased with increasing oxygen flow rate. The grain size increased with the bias voltage. However, at a maximum voltage of −90 V fine grains were detected due to the formation of numerous nuclei resulting from bombardment of high energy particles. The bias voltage had little effect on the bonding state of In, Sn and O ions.     

An Experimental Low-Cost, Low-Data-Rate Rapid Structural Assessment Network

In this paper, we present the design, implementation, and experimental evaluation of a wireless sensor network for real-time structural ldquohealthrdquo monitoring. We use simple custom-built gages to detect cracks in critical structural elements. The main data reports require no structural analysis for interpretation, have a low data rate, and are naturally resilient to loss. We show how a variety of low-cost, off-the-shelf data acquisition/communication devices can be used to support remote monitoring by a control center. The heterogeneous hardware is accommodated by the use of open technology standards and a software architecture that is portable, modular, and highly configurable. We present an experimental evaluation of our structural-assessment network done using a full-scale three-story reinforced concrete building that was tested under lateral forces emulating forces induced by earthquakes. Our results show that a set of 12 strategically positioned sensors achieved a 100% detection rate for cracks crossing sensors and a zero false-alarm rate (in the sense that all signals exceeding a preset threshold were traced to cracks exceeding a specified total width).     

How much do I tell thee? Strategies for managing information to parents among American adolescents from Chinese, Mexican, and European backgrounds.

Strategies for managing information about activities to parents, including partial disclosure, avoidance, lying, and full disclosure, were examined in 479 American adolescents (M = 16.38 years, SD = 0.77) varying in generational status and from Mexican, Chinese, and European backgrounds. Information management strategies for personal, prudential, and overlapping (multifaceted) activities as defined within social domain theory were examined. With age, parental education, and generational status controlled, Chinese American adolescents partially disclosed more to mothers about personal and multifaceted activities than did Mexican American adolescents and more to fathers about personal activities than did European American teens. In contrast, European and Mexican American adolescents fully disclosed more to mothers about personal activities than did Chinese-origin adolescents. Strategies varied by generation among Chinese American youth; second-generation adolescents avoided discussing activities with parents more than did immigrants. Adolescents who fully disclosed about all activities and lied less about multifaceted and personal activities reported stronger endorsement of obligations to assist their families, more trust in parents, and less problem behavior. More depressed mood was associated with more lying about personal activities. (PsycINFO Database Record (c) 2010 APA, all rights reserved)     

Generating NC tool paths from random scanned data using point-based models

This paper presents a new approach for the generation of NC tool paths from random scanned data. Instead of using smooth or triangulated surfaces reconstructed from raw data, which is usually a time-consuming reverse engineering approach, the point-based surfel models computed by a GPU (graphics processing unit) are used to generate NC tool paths. The tool-path generation is highly efficient and still maintains the advantage of having accurate and smooth machining result. The word “surfel” itself is the combination of the two words “surface” and “element”. It is originally applied to the rendering of scanned data. In this paper, the point-based model is created using an elliptical Gaussian re-sampling filter that is based on a signal re-sampling algorithm. Since the input scanned data is of discrete and random nature, the warping process is utilized to transform the input data into a continuous surface and then re-sample the continuous surface by using GPU. Because the re-sampled data can accurately represent the original surface, tool paths can be generated based on the point data set. For cutting tools with various sizes, adaptive re-sampling schemes are employed to generate sufficient sampled points for the generation of accurate and smooth tool-paths.     

Suprathermal plasma analyzer for the measurement of low-energy electron distribution in the ionosphere

It is commonly believed that an energy transfer from thermal to suprathermal electrons (相似文献   

On Radiant Network Models of Thermocouple Error in Pre and Post Flashover Compartment Fires

Thermocouples are often used to obtain gas temperature measurements in compartment fires. Such measurements are subject to a thermal lag during fire growth, but the main problem is a steady-state error induced by radiant heat transfer at the thermocouple surface. This error is sensitive to thermal parameters of the flame, compartment structure, thermocouple surface and combustion products; and is also influenced by the size and position of both the flame and thermocouple. The literature contains models of varying sophistication to enable an assessment of steady-state error. A model is now proposed that makes use of the concept of radiosity. Developed from radiant network theory, the model can be applied to both pre-flashover and post-flashover conditions. Experiments have been performed using different sizes of thermocouple and the models compared. The simpler models pre-date the more sophisticated and predict much larger errors than the latest published and current versions.     

多病床非典病房的气流分布研究

到2003年8月7日止，在全球34个国家和地区相继出现了严重急性呼吸系统综合症(SARS或者非典)，其中，共报告有8422例疑似案例，916例死亡案例。2002年11月到2003年6月间的非典流行中，医院医护人员受感染情况最为严重，世界范围内20％的感染群体为医护人员，香港地区22％的确诊案例为医护人员。因此，为减少交叉感染，加强有关工程控制，特别是在非典病房里进行通风设计是非常必要的。本文总结了非典病房气流分布的最新研究。这项研究由非典特工队于2003年4～7月间完成。非典特工队是由香港工程师协会组织，来自7个专家协会的工程师组成的研究小组。在对香港治疗非典医院的现有空调系统进行了解后，非典特工队首先运用计算流体力学模拟确定了在6个床位的病房里减少交叉感染和改善污染物稀释的通风设计；接着，对新设计在香港大学屋宇设备实验室里的全尺寸非典病房里进行了测试。测试表明，新设计方案在这个接近现实的全尺寸非典病房里运行良好。采用床头回风口回风设计可有效地对病人产生的含病毒颗粒进行局部捕获。根据这项研究，作者提出了原则性的设计建议。2003年里，香港政府和医院管理局医院采纳了非典特工队提出的设计基本原理建造了1200多个床位的可用于非典治疗的新病房。另外，气流分布是复杂的紊流过程，送风格栅结构如导流器或散流器的微小改动以及送风参数如风速、温度和风向的微小变化都会引起气流的改变。适当的设计对于减少病人间、病人与医护人员之间的交叉感染以及有效稀释和排除含病菌颗粒都是至关重要的。     

退火热处理对等径角挤压回收Ti-6Al-4V合金微观结构和显微硬度的影响

采用等径角挤压法回收Ti-6Al-4V合金切屑,并研究了回收样品和退火处理样品的微观结构和显微硬度。结果表明:在回收样品中,切屑之间的边界依然存在,而由于剧烈塑性变形,超细晶结构和较强的纤维织构得以形成。退火处理后,切屑边界部分消失,超细晶组织部分再结晶;而与此同时,退火处理样品展现出更宽泛的织构,再结晶晶粒并不存在择优取向。值得注意的是,退火处理样品的显微硬度较回收样品略有升高。