On control of adaptation in parallel mesh generation

A black-box methodology of a parallel generation of adaptive anisotropic meshes is described. A control of mesh adaptation, important for robustness and flexibility, may effect parallel properties of the methodology. This is demonstrated with a 3D example.     

Katalytischer wasserstoff-/sauerstoff-rekombinator mit selbstbegrenzung

Lead-acid cells evolve hydrogen and oxygen gasses during the charging mode, which results in a water loss. Gas recombination devices extend the water refilling periods due to the recombination reactionH₂ + $\text{1}\text{2}$O₂ → H₂O The recombination devices consist of: aerosol retainer, charcoal filter, catalyst, condenser, gas storage and vents. Theoretical models describing the self-limiting behaviour of the catalyst and the heat flow conditions in the device were developed.Design specifications of component requirements for a 435-W recombination device, which is capable of recombining 182 l/h stoichiometric oxyhydrogen gas, were also developed. Tests with the system (recombination device-lead-acid cell) showed that a maintenance-free and nearly gastight operation was achieved. The use of catalytic recombination devices improves the economy and safety of battery operation.     

Phase Equilibria in the Mg – Al – Ca System (Region 50-100 mass% Mg)

Phase equilibria in the ternary system Mg – Al – Ca in the composition range 50-100 mass% Mg were studied by the methods of differential thermal, xray diffraction, electron-probe and microscopic analysis. The projection of the liquidus surface on the concentration triangle, isothermal section at 150°C and polythermal sections at 4.5, 8.5, and 16 mass% Al were constructed. It was determined that additions of Al and Ca decrease the liquidus temperature of magnesium alloys (from 650 to 438°C). It is shown that the three-phase region + 2Ca> + 17Al₁₂> exists at 150°C with the corresponding two-phase fields. The temperature dependence of the homogeneity range of the Mgbased solid solution was determined, and also the temperatures of the phase transformations which occur in the investigated range of compositions in the system.     

The influence of alteration on the engineering properties of dolerites: The examples from the Pindos and Vourinos ophiolites (northern Greece)

The influence of alteration on the physico-mechanical properties of dolerites from the Pindos and Vourinos ophiolites, northern Greece, is investigated. Quantitative petrographic analysis shows that the samples display various percentages of secondary minerals. Two new micropetrographic indices are calculated from the results of petrographic modal analysis for the engineering assessment of dolerites: the micropetrographic strength index I_ps and the replacement index I_rep. The samples are also tested to determine water absorption, apparent density, total porosity, sand equivalent, uniaxial compressive strength, Los Angeles abrasion value, aggregate impact value, aggregate abrasion value and polished stone value. The influence of alteration on the rock quality and especially the relationships between the proposed micropetrographic indices and the engineering parameters are determined using regression analysis and the derived equations were verified by the t-test and the F-test. The relationships between the I_ps and I_rep indices and the engineering properties show that alteration products generally result in mechanically weaker rocks. However, the results of the physico-mechanical tests indicate that dolerites retain their strength and durability due to the low proportions of soft minerals and microcracks, along with the preservation of their igneous textures. The polishing resistance is the only engineering parameter that is positively affected by alteration processes, as expressed by the I_ps index. Particularly, the replacement of the primary mafic minerals by secondary minerals, expressed by the I_rep index, can enhance the polishing resistance of dolerites when used in the wearing surface of a road. The results also indicate strong positive correlations between the chlorite content and the water absorption and total porosity values.     

Silica and Magnesia Dopant Distributions in Alumina by High-Resolution Scanning Secondary Ion Mass Spectrometry

Trace SiO₂ and MgO additive distributions in sintered alumina have been studied using high-resolution scanning secondary ion mass spectrometry (SIMS). When doped with each additive individually, evidence is seen for both strong silicon segregation to grain boundaries ( C _gb/ C _grain similar/congruent 300) in SiO₂-doped alumina and strong magnesium segregation to grain boundaries ( C _gb/ C _grain similar/congruent 400) in MgO-doped alumina. When codoped with both SiO₂ and MgO, segregation of both ions to grain boundaries is reduced by a factor of 5 or more over single doping. The additive concentrations increase proportionally in the grains, and both dopants become more uniformly distributed throughout the bulk. It is concluded that codoping with these additives increases their mutual bulk solid solubility and decreases their interfacial segregation over single doping. The beneficial effect of MgO additions in controlling microstructure development in alumina and improving corrosion resistance to aqueous HF stems from its ability to redistribute silicon ions from grain boundaries into the bulk.     

Isothermal Section of Er-Ag-Sn System at 873 K

The isothermal section of the Er-Ag-Sn system at 873 K was constructed with the use of scanning electron microscopy, energy-dispersive x-ray microanalysis and x-ray powder diffraction. Two ternary compounds were confirmed at this temperature: ErAgSn (LiGaGe structure type, P6₃mc, Z = 2, a = 4.6595(2) Å, c = 7.2872(3) Å) and non-stoichiometric phase ErAg_1?xSn_2+x (Cu₃Au structure type, Pm-3m, Z = 1). For the last one homogeneity range was established (0.08 < x < 0.24) and lattice parameters were determined (a = 4.5007(4), 4.5040(2), 4.5107(1), 4.5412(1) Å for the compositions Er_25.4Ag_23.4Sn_51.2, Er_25.7Ag_23.0Sn_51.3, Er_25.7Ag_21.7Sn_52.6, Er_25.2Ag_18.6Sn_56.2 (at.%) respectively). Melting point of the phase Er_25.7Ag_21.7Sn_52.6 (at.%) was determined to be 1199 K by differential thermal analysis.     

Aryl Bis‐Sulfonamide Inhibitors of IspF from Arabidopsis thaliana and Plasmodium falciparum

2‐Methylerythritol 2,4‐cyclodiphosphate synthase (IspF) is an essential enzyme for the biosynthesis of isoprenoid precursors in plants and many human pathogens. The protein is an attractive target for the development of anti‐infectives and herbicides. Using a photometric assay, a screen of 40 000 compounds on IspF from Arabidopsis thaliana afforded symmetrical aryl bis‐sulfonamides that inhibit IspF from A. thaliana (AtIspF) and Plasmodium falciparum (PfIspF) with IC₅₀ values in the micromolar range. The ortho‐bis‐sulfonamide structural motif is essential for inhibitory activity. The best derivatives obtained by parallel synthesis showed IC₅₀ values of 1.4 μm against PfIspF and 240 nm against AtIspF. Substantial herbicidal activity was observed at a dose of 2 kg ha^?1. Molecular modeling studies served as the basis for an in silico search targeted at the discovery of novel, non‐symmetrical sulfonamide IspF inhibitors. The designed compounds were found to exhibit inhibitory activities in the double‐digit micromolar IC₅₀ range.