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241.
本文采用粉末冶金法制备了不同成分的PSZ/Mo复合材料。并对其密度、弹性模量和热膨胀系数进行了测量和分析 ,用XRD进行了物相分析。实验结果表明 :纳米氧化锆的烧结性能比金属钼好 ;弹性模量估算选用简单混合法则进行计算时应进行修正 ;钼和氧化锆在烧结时不发生化学反应。通过热压PSZ/Mo功能梯度材料的断口扫描分析发现 :虽然金属钼和纳米氧化锆具有一定增韧作用 ,但材料断裂方式仍以脆性断裂为主 相似文献
242.
Qin‐Tao Liu Malcolm R Clench Judith L Kinderlerer 《Journal of the science of food and agriculture》2002,82(5):553-558
Structural isomers of monoacylglycerols (monoglycerides, MAGs) were identified and compared after degradation of butter oil by two strains of Penicillium roquefortii and a commercial lipase from P roquefortii (EC 3.1.1.3) at pH 7.0 and 10 °C. The conditions were selected as they were comparable with those used in the manufacture of blue mould‐ripened cheese. The commercial lipase was selected to compare with the fungal strains in terms of acyl migration. Results showed that the main isomers formed by lipolysis with the commercial lipase were sn‐2 MAGs (64 mol%), whilst spores and emerging mycelia of P roquefortii produced mainly sn‐1(3) MAGs (83–90 mol%). The work reported here may lead to further assessment of different MAG structural isomers as natural preservatives in foods and dairy products. © 2002 Society of Chemical Industry 相似文献
243.
The reduction of calcium sulfate to produce calcium sulfide is a part of the cyclic process for converting sulfur dioxide
to elemental sulfur that is described in Part I. The kinetics of the hydrogen reduction of nickel-catalyzed calcium-sulfate
pellets were investigated using a thermogravimetric analysis (TGA) technique at reaction temperatures between 1023 and 1088
K and hydrogen partial pressures between 12.9 and 86.1 kPa. The reactivity of nickel-catalyzed calcium-sulfate pellets was
demonstrated by the conversion of 70 pct fresh nickel-catalyzed calcium sulfate to calcium sulfide in 20 minutes at 1073 K
under a hydrogen partial pressure of 86.1 kPa. Furthermore, the reactivity remained relatively intact after ten cycles of
reactions and regenerations. This observed characteristic of the pellets is important because the solids must be reusable
for repeated cycles to avoid generating secondary pollutants. The nucleation and growth rate expression was found to be useful
in describing the kinetics of the reaction, which had an activation energy of about 167 kJ/mol (∼40 kcal/mol) in all reaction
cycles except for the first regenerated samples that were lower at 146 kJ/mol (35 kcal/mol). The reaction order with respect
to hydrogen partial pressure was 0.22 in all cycles with the exception of the first regenerated sample for which it was 0.37. 相似文献
244.
245.
246.
We have investigated the effect of extended dislocations (0.5-3 μm) on charge distribution in GaN epilayer grown by metalorganic chemical vapor deposition on (0001) sapphire using atomic force microscopy (AFM) and scanning surface potential microscopy (SSPM). It has been observed for the surface at the extended dislocations present in undoped GaN film to be negatively charged showing 0.04-0.2 V higher potential relative to regions that contain no dislocations. In addition to the higher potential at the dislocation core, the surrounding surfaces, including the edge of the dislocations, are also negatively charged in a symmetric way around the dislocations revealing crater-shaped higher potential regions (∼0.04 V) relative to surrounding dislocation-free area. The experimental results show that the protrusion-type of dislocation is also negatively charged and its potential is dependent on the size of dislocation. 相似文献
247.
基于公钥加密算法和PPCT动态图编码的软件指纹方案 总被引:1,自引:0,他引:1
提出了一种综合PPCT动态图编码方法和椭圆曲线加密算法的软件指纹方案,该方案将公钥加密技术和软件水印技术综合应用于软件版权的保护和验证过程中,充分利用两者的优势,具有安全性高和抗恶意篡改能力强的特点. 相似文献
248.
H.‐C. Su F.‐C. Fang T.‐Y. Hwu H.‐H. Hsieh H.‐F. Chen G.‐H. Lee S.‐M. Peng K.‐T. Wong C.‐C. Wu 《Advanced functional materials》2007,17(6):1019-1027
Highly efficient orange and green emission from single‐layered solid‐state light‐emitting electrochemical cells based on cationic transition‐metal complexes [Ir(ppy)2sb]PF6 and [Ir(dFppy)2sb]PF6 (where ppy is 2‐phenylpyridine, dFppy is 2‐(2,4‐difluorophenyl)pyridine, and sb is 4,5‐diaza‐9,9′‐spirobifluorene) is reported. Photoluminescence measurements show highly retained quantum yields for [Ir(ppy)2sb]PF6 and [Ir(dFppy)2 sb]PF6 in neat films (compared with quantum yields of these complexes dispersed in m‐bis(N‐carbazolyl)benzene films). The spiroconfigured sb ligands effectively enhance the steric hindrance of the complexes and reduce the self‐quenching effect. The devices that use single‐layered neat films of [Ir(ppy)2sb]PF6 and [Ir(dFppy)2sb]PF6 achieve high peak external quantum efficiencies and power efficiencies of 7.1 % and 22.6 lm W–1) at 2.5 V, and 7.1 % and 26.2 lm W–1 at 2.8 V, respectively. These efficiencies are among the highest reported for solid‐state light‐emitting electrochemical cells, and indicate that cationic transition‐metal complexes containing ligands with good steric hindrance are excellent candidates for highly efficient solid‐state electrochemical cells. 相似文献
249.
Yu‐Qing Cao Zhan Zhang Yan‐Xin Guo 《Journal of chemical technology and biotechnology (Oxford, Oxfordshire : 1986)》2008,83(10):1441-1444
A new efficient method for synthesising nitriles, important organic reagents, is reported in this paper. In an environmentally benign solvent‐free system, aryl carboxylic acids were converted into the corresponding nitriles via one‐pot reactions, by amidation with ethyl carbamate followed by dehydration with thionyl chloride, in excellent yields. The results showed that the method has the advantages of lower cost, higher yield, less pollution and greater ease of work‐up. Copyright © 2008 Society of Chemical Industry 相似文献
250.
The cooling and solidification of melted drops during their movement in an immiscible cooling medium is widely employed for granulation in the chemical industry, and a study of these processes to provides a basis for the design of the granulation tower height and the temperature of the cooling medium is reported. A physical model of the cooling and solidification of the drop is established and the numerical calculation is performed. The influences of the key factors in the solidification, i.e., Bi number, drop diameter, temperature of the cooling medium, etc. are presented. The cooling and solidification during wax granulation in a water‐cooling tower and during urea granulation in an air‐cooling tower (spraying tower) are described in detail. Characteristics of the solidification and temperature distribution within the particle at different times are shown. The model and calculations can be used for structure design of the granulation tower and optimization of the operation parameters. 相似文献