高级控制系统提高巴西水电站性能

巴西的一个重要电力公司COPEL最近开发了一个水电站高级控制系统，这是在电力部门经受重大变革时期，提高水电竞争力的里程碑。     

Structure and composition of guanidine acrylate, guanidine methacrylate, their homopolymers, and copolymers with diallyldimethylammonium chloride

Structures and compositions of the monomers guanidine acrylate and guanidine methacrylate, their homopolymers, and copolymers with diallyldimethylammonium chloride enriched in acrylate comonomer units were determined. It was shown that ampholytic copolymers, owing to their ionic nature, contained comonomeric guanidine acrylate or methacrylate units and diallyldimethylammonium chloride units, as well as the acrylate comonomer with the diallyl counterion and polymeric acrylate and diallyl ion pairs. It follows from IR and ¹H NMR data that guanidine methacrylate has the same structure (with two hydrogen bonds) in the solid state and in solutions. Guanidine acrylate structures in the solid state and in dimethylsulfoxide are identical and analogous to guanidine methacrylate structure in this solvent. In water, the guanidine acrylate structure has another type of hydrogen bonding (with one hydrogen bond, where the proton is shifted toward the guanidine group). These features of hydrogen bonding of guanidine acrylate and guanidine methacrylate are also retained in their homopolymers and copolymers with diallyldimethylammonium chloride. It was shown that the thermal stability of the copolymers was higher than that of their homopolymers, confirming the formation of intramolecular ion pairs of oppositely charged units of ampholytic copolymers. Moreover, the thermal stability of guanidine methacrylate-diallyldimethylammonium chloride copolymers is higher than that of guanidine acrylate-diallyldimethylammonium chloride copolymers.     

On the nonuniformity of a capillary flow

It is established that the capillary rise of a liquid has an oscillatory character, in contrast to the commonly accepted opinion that a vertical capillary is filled at a monotonically varying velocity. The value of the tangential shear stress arising in an ascending liquid is evaluated for ethyl alcohol and distilled water.     

Experimental Electronuclear Setup at the Institute of Theoretical and Experimental Physics

The purpose and current construction status, at the Institute of Theoretical and Experimental Physics, of an experimental electronuclear setup, combining a pulsed proton linear accelerator (36 MeV, 0.5 mA) and a subcritical blanket thermal-power assembly 100 kW, are discussed. The main equipment is already available or is being built in industry. The setup can be used to investigate the dynamics of the interaction of a linac–driver and a subcritical reactor and problems concerning the accelerator–driver and the target–blanket assembly. The proton beams and neutron fluxes will be used for applied purposes. In the future it will be possible to increase substantially the current and energy of the proton beam.     

Future increase in harmful algal blooms in the North Sea due to climate change.

In temperate seas such as the North Sea harmful (toxic) algal blooms will probably increase as a result of climate change. This conclusion was reached after investigating the projected effect of climate change for the year 2100 in Dutch coastal waters (4 degrees C temperature rise and increased water column stratification) on the growth rates of six harmful and two non-harmful phytoplankton species. Micro algae form the basis of the marine food chain. However, toxin-producing species may seriously disrupt the food web and lead to fish kills and human intoxication. Two species with estimated doubled growth rates in 2100, F. japonica and C. antiqua, entered Europe via ship's ballast water or shellfish imports. This stresses the need to legally regulate such invasion routes in order to prevent the import of novel species. Future toxic phytoplankton blooms may further devaluate ecosystem deliverables such as fish production or recreational use. This devaluation can be estimated by monetary value assessments that are needed in cost-benefit analyses for policy guidance. The lack of understanding of future climate, ecosystem functioning and its response to climate change calls for a scientific effort to improve our knowledge on present day coastal ecosystem functioning and its resilience.     

Addition of pectolytic enzymes: an enological practice which improves the chromaticity and stability of red wines

Summary The effect of the addition of four commercial pectolytic preparations on the visual characteristics (colour and turbidity) of red wines has been evaluated. The effect of both clarifying and colour extracting enzymes and the effect of different doses used, were evaluated and compared. All the red wines treated enzymatically, independent of the type of enzyme and dose, present chromatic characteristics which can be considered better than those of the control wines. Also, those wines treated with enzymes had greater stability during 2 years storage in bottles, in particular the turbidity was better than untreated wines.     

Structure and properties of CE/CTBN/EP blends: II. Effect of EP on the mechanical properties and thermostability of the CE/CTBN system

Carboxyl‐terminated butadiene‐acrylonitrile rubber (CTBN) has often been used to improve the toughness of cyanate ester (CE) resin while sacrificing modulus and thermostability. In this paper, the addition of the appropriate amount of epoxy resin (EP) to the CE/CTBN system is shown to not only increase the modulus and thermostability of the blend, but also improve the toughness. The values of impact strength showed a maximum for the CE/CTBN/EP 100/5/5 blend. The temperature of 10 % weight loss (T₁₀) improves from 376 °C for CE/CTBN 100/5 to 407 °C for the CE/CTBN/EP 100/5/2.5 blend. It is proposed that addition of the appropriate amount of EP can decrease the mobility and increase the stability of CTBN via the reaction between the terminal carboxyl group of CTBN and the hydroxyl group of EP. But a very high EP concentration will decrease the crosslinking density of CE, consequently reducing the mechanical properties and thermostability of the blends. Copyright © 2004 Society of Chemical Industry