Study of nucleation activity and application of a nucleating agent to copolypropylene

The influences of nucleating agent content on crystallization peak temperature, crystallization curve shape, crystallization onset temperature, and crystallinity of a copolypropylene were studied in detail by differential scanning calorimetry. The results showed that crystallization onset temperature and crystallization peak temperature increased 17°C–22°C and 15°C–19°C, respectively, with increasing nucleating agent content. The behavior of the nucleating agent showed excellent efficiency. But the shape of the crystallization curve broadened with increasing nucleating agent content, and the crystallinity came to an extremum when the nucleating agent content was 0.2%. These results generally differed from those for crystallization of i‐PP by a nucleating agent. Modification of copolypropylene was studied by use of a nucleating agent, and the characteristics of the effects of the nucleating agent on copolypropylene were mastered. The results showed that the hardness of a copolypropylene improved observably. So the abrasion resistance of biaxially oriented polypropylene (BOPP) film for cigarette packaging was improved by adopting the modified copolypropylene as the skin‐layer heat‐seal material of BOPP film. © 2006 Wiley Periodicals, Inc. J Appl Polym Sci 101:3915–3919, 2006     

镍铬合金导线在电涡流位移传感器中的应用

基于电涡流的基本原理,以镍铬合金导线为涡流线圈,将导线绕制在陶瓷骨架上构成涡流探头,结合电源模块、放大模块和显示模块,设计制作了电涡流位移传感器。实验结果表明:该传感器能实现对金属位移的测量,具有结构简单、抗干扰能力强和测量精度较高等特点。     

磷渣制备高C3S熟料的烧成机理研究

利用ICP、DTA、XRD、SEM和EDXA测试方法,研究了磷渣在制备高C3_S熟料过程中的作用机理。研究结果表明,磷渣对高C_3S熟料烧成的促进作用主要是由于磷渣中CaSiO_3的“晶核作用”。     

Study on Jet Coflow Packing Tray

Experimental study on hydrodynamics and mass transfer efficiency of jet coflow packing tray (JCPT) was conducted in a φ285 mm column and a φ200 mm column, respectively. Compared with new vertical sieve tray which has been applied in the petrochemical industry since 1968, the JCPT has lower pressure drop, higher capacity and higher mass transfer efficiency, and seems promising in commercial application.     

Theoretical studies of displacement deposition of nickel into porous silicon with ultrahigh aspect ratio

A model is developed to address the uniformity of displacement deposition of nickel inside porous silicon with an ultrahigh aspect ratio as high as 200. The nickel distribution is treated as a current distribution issue as in electrodeposition. It is shown that the deposition distribution along the pore depth exhibits a strong dependence on a polarization parameter ξ. High values of ξ correspond to mass transport limitations and lead to non-uniform distributions, whereas small ξ values, representing interfacial reaction control, produce uniform distributions. Non-uniform deposition primarily occurs at an initial stage in which the reaction is dominated by mass transfer. As the deposition process continues, the deposition rate drops to a low value, and the deposition uniformity shifts from Ni²⁺ mass transport limitations to its interfacial reaction control, leading to uniform Ni²⁺ concentration and deposition rate distributions. It is predicted that the non-uniformity at the initial stage could be remedied by increasing the bulk concentration of the nickel ions and decreasing the plating bath pH. In addition, the uniformity of the deposition distribution can be significantly improved by introducing inhibiting additive coumarin to the plating solution.     

密闭条件下使用的氟硅密封剂的制备

讨论了硫化体系，硫化剂用量，填料种类对在密闭条件下使用的氟硅密封剂耐热性能的影响，结果表明，采用硅氮烷低聚物作硫化剂，TiO2为补强填料，硅氟密封，剂在密闭环境中180℃高温下降解不明显，硫化后的密封剂仍保持一定的硬度和良好的弹性。     

变化环境下河流健康评价研究进展

全球以温度升高为主要特征的气候变化耦合人类活动影响,造成了全球性变化环境背景下大范围的水资源危机、水环境污染和水生态退化问题,威胁河流健康,已成为当今世界各国急需解决的难题。针对变化环境背景,分别从河流健康的概念和内涵、河流健康评价的内容、方法及应用等方面,评述近年来国内外河流健康评价的研究进展。将河流健康定义为,特定时期一定的社会公众价值体系下,在保障河流自身基本生存需求的前提下,能够持续地为人类社会提供高效合理的生态服务功能,并实现服务功能综合价值最大化。在前人研究基础上,指出变化环境下河流健康评价研究存在的主要问题,如河流健康概念及内涵仍存在争议,河流健康变化的驱动机制尚不明确,河流健康评价的理论及方法有待完善,河流健康评价实践滞后及评价结果未能有效指导河流管理等。提出变化环境下河流健康评价的发展趋势:以流域为基本空间尺度结合多时间尺度开展河流健康评价与调控研究,因地制宜开展河流健康评价指标体系及评价标准研究,开展基于3S等技术的河流健康评价研究,建立长期且全面的河流健康监测网络,科学界定河流健康的"基准点",以及开展河流健康评价与水资源调控的集成研究等。     

全水发泡聚氨酯硬质泡沫降噪性能的研究

采用全水发泡工艺，通过对聚醚多元醇、泡沫稳定剂、交联剂、开孔剂及水加入量的凋节，研制了一种具有较高耐压强度的聚氨酯开孔硬质泡沫塑料。对制备原理，聚醚多元醇的选择，开孔剂的用量，水的用量、泡沫塑料厚度及声波频率等因素对降噪性能的影响进行了初步探讨。实验表明，采用芳香胺类聚醚多元醇A和低黏度聚醚多元醇B相配合，开孔剂的用量（相对于聚醚的质量分数）为3％，泡沫稳定剂用量为2％，水的添加量为4％和泡沫厚度为4～5cm时其降噪效果最好。     

地热供热系统腐蚀问题初探

地热是地球本身蕴藏的能源，储量极为丰富，我国在很多领域都大力开发和应用地热。但由于地热水本身的特点，地热系统在运行当中会出现严重的腐蚀现象，本文对地热系统腐蚀的形成及控制进行了初探。     

浅析手冢治虫对当今日本动漫创作的影响

手冢治虫的动漫作品对当时乃至现在都具有很深借鉴意义。手冢治虫在动画和漫画领域上创作的内容丰富,情节连续生动。文章通过解读他的作品灵感来源和有限动画的创举,从而进一步对比分析对后代动画工作者的深远影响。