铝电解用TiB_2阴极涂层固化、炭化的升温制度

采用DTG ,DDTA等热分析手段 ,研究了高温固化、炭化过程中 ,铝电解用TiB2 阴极涂层糊料的质量和能量的变化速率 ,制定了涂层的变速固化、炭化升温制度 ;在此基础上 ,研究了升温制度对TiB2 阴极涂层性能的影响。结果表明 :变速升温制度优于匀速升温制度 ,采用变速固化、炭化升温制度所制备的涂层形变小、无裂纹 ,其抗拉强度达 3.13MPa,电阻率为 2 3.2 μΩ·m ;而采用升温速度为 10 .3℃ /h的匀速固化、炭化升温制度制备的涂层形变大、裂纹多 ,抗拉强度小 (2 .6 9MPa) ,电阻率大 (2 8.6 μΩ·m)。     

Study on sintering process and characteristic of nanosized soft magnetic MnZn ferrite powders

The effect of sintering process (especially the sintering temperature) on the magnetic property and microstructure of sintered sample of nanosized soft magnetic MnZn ferrite powder was investigated. The sintered sample of MnZn ferrite was prepared by both traditional pressing and cool isostatic pressing on MnZn ferrite nanoparticals. The sintering process of which was segmented. Thedensity, microstructure and phase composition of sintered sample were analyzed by Archimedes'law, scanning electron microscopy (SEM) and X-ray diffraction (XRD). The grain growth and densification in sintering process of MnZn ferrite were investigated. The magnetic property was measured by vibrating sample magnetometer (VSM) and Nim2000 magnetic material testing system. The results show that the better sintering temperature is 850 ℃, at which the better magnetic property and microstructure of sintered compact were obtained.     

(ZrAl3+ZrB2)/Al复合材料的制备和微观组织结构

采用混合盐反应法,以KBF4和K2ZrF6粉剂为原料在铝熔融体中制备了(ZrAl3 ZrB2)/Al复合材料.借助于X射线衍射仪、电子探针和透射电镜对复合材料的物像和增强相进行了观察,结果表明ZrB2颗粒呈等轴或等轴颗粒状,为六方结构,尺寸大部分小于1μm,ZrAl3相大部分呈长条状,两种增强相整体分布较为均匀,且与Al的界面光滑洁净,没有其它界面生成物.对复合材料的硬度做了测试,原位合成增强相的引入显著提高了复合材料的HRB硬度.     

LaNi5的电子结构

采用总体能量平面波赝势方法, 并结合超软赝势技术, 计算了金属La、 Ni及合金LaNi5的总体能量、能带结构、电子态密度以及Mulliken布居值. 根据计算结果, 分析了La、 Ni和LaNi5的电子结构. 结果表明: 形成合金后费米面能量位置漂移, 介于Ni和La的费米面之间, 费米面上主要是Ni 3d电子; 费米面附近导带的电子结构变化较大; 合金中La和Ni间存在电子转移, 形成了弱的La-Ni键, 且带部分离子性; 与纯金属相比, 形成合金后La的稳定性增强, 而Ni的稳定性减弱. 计算了LaNi5的理论生成热, 结果能较好地符合实验值.     

Wear resistance of ceramic coating on AZ91 magnesium alloy by micro-arc oxidation

The ceramic coating formed on AZ91 magnesium alloy by micro-arc oxidation （MAO） was characterized. The results show that the ceramic coating （3.4-23 μm in thickness）on the surface ofAZ91 alloy was attained under different micro-arc oxidation treatment conditions, which consist mainly of MgO, Mg2SiO4 and MgSiO3 phases. Nano-hardness in a cross-sectional specimen was determined by nano-indentation experiment. The MAO coatings exhibit higher hardness than the substrate. Dry sliding wear tests for the MAO coatings and AZ91 alloy were also carded out using an oscillating friction and wear tester in a ball-on-disc contact configuration. The wear resistance of the MAO coatings is improved respectively under different treatment time as a result of different structures of ceramic coatings formed on AZ91 alloy.     

剪切变形方向特征对高纯铝箔轧制织构的影响

运用取向分布函数(ODF)研究了每个轧制道次的剪切变形特征对高纯铝箔轧制织构的影响.提出用中性角的相对大小来量化轧制剪切变形作用方向改变的位置,运用Taylor晶体塑性变形理论模拟计算了中性角的相对大小对轧制织构演变的影响.实测与模拟的轧制织构特征表明:中性角靠近轧制变形区的中心位置有利于形成{001}<110>剪切织构,从而证实了除剪切变形的程度外,剪切变形方向改变的位置也是影响高纯铝箔轧制织构的重要因素.     

冷精锻试样内部等效应变与硬度关系的研究

通过对钢制试样的冷态平面镦粗变形试验研究,同时结合数值模拟软件Deform-2D,得到在室温、一定变形速率条件下的等效应变与硬度关系的拟合曲线;并对比各种拟合曲线从中找出了最佳的曲线求出了其拟合公式.从而为科学地预测相似变形条件下冷挤压工件的内部硬度分布提供了实用参考.     

ANN valuation model of material LCIA profile

Weighting model is the only valuation model of life cycle impact assessment(LCIA) profile now. It simplifies evaluation function into linear function, and makes the determination of weighting factor complicated. Therefore the valuation of LCIA profile is the most critical and controversial step in life cycle assessment(LCA). Development on valuation models, which are understood easily and accepted widely, is urgently needed in the field of LCA.The modeling approaches for the linear evaluation function were summed up. The modeling approaches for the nonlinear evaluation function were set up by function approximation theory, which include choosing preference products, forming preference data, establishing artificial neural network(ANN) and training ANN by preference data.By selecting 7 material products as preference product, experience was done with modeling approaches of the nonlinear evaluation function. The results show that the modeling approaches and valuation model of the nonlinear evaluation function are more practical than the weighting model.     

固溶处理对电解制备的A356合金硅颗粒的影响

以电解低钛铝基合金为原料制备了A356合金,研究了在535℃下固溶处理时间对合金共晶硅相细化、球化和分布的影响.测量了硅颗粒的长径和短径,计算了颗粒的直径和长短径比值等参数,分析了上述参数随固溶时间的变化及其概率密度分布.实验结果表明:由该电解合金制备的A356合金经2～4 h的固溶处理,共晶硅就可得到较好的细化和球化效果,具有较高的分布集中度;A356合金的固溶处理时间可有效缩短.     

消失模铸造充型过程的模拟方法

通过分析消失模铸造充型过程的特点，提出了一种消失模铸造充型过程的计算模型，并用人工神经网络算法计算了充型过程中不同时刻液态金属-模样界面的位置．模拟计算结果与实际测试结果无论在充型形态还是充型时间上都符合得较好．