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841.
In this work, the synthesis, properties of a thermal/pH-sensitive core-shell copolymer latex were studied and its potential application as a targeting drug carrier was also investigated, where the crosslinked copolymer of N-isopropylacrylamide (NIPAAm) and chitosan was synthesized by soapless dispersion polymerization as the core, and the copolymer of methacrylic acid (MAA) and methyl methacrylate (MMA) was prepared as the shell. The weight ratio of chitosan/NIPAAm and the concentration of crosslinking agent in feed had been changed to investigate their effects on the particle size, reaction rate, zeta potential, surface functional groups, and specific surface area of latex particles. The swelling and thermo-sensitive behavior of the film made from these core-shell latexes were also studied under different pH values of buffer solution. The model drug (caffeine) could be loaded inside the copolymer particles and protected from releasing through the transport process effectively. And the thermo-responsive property of these copolymer particles significantly enhanced the protein conjugation that showed the potential of the latex being applied on the targeting drug carrier. 相似文献
842.
An EGF-pseudomonas exotoxin A recombinant protein with a deletion in toxin binding domain specifically kills EGF receptor bearing cells 总被引:2,自引:0,他引:2
Lee Chi-Hon; Lee E-Ching; Tsai Shih-Tzer; Kung Hsing-Jien; Liu Yin-Chang; Hwang Jaulang 《Protein engineering, design & selection : PEDS》1993,6(4):433-440
We constructed two chimeric toxins; one composed of epidermalgrowth factor (EGF) and pseudomonas exotoxin A (PE), designatedEGF-PE and the other composed of EGF and PE with a deletionof the Ia domain (cell-binding domain), designated EGF-PE (Ia).Both chimeric toxins reacted with anti-EGF and anti-PE antibodies.The cell-killing experiments showed that EGF-PE, but not EGF-PE(Ia),was cytotoxic to the murine fibroblast cell line NR6, whichcarried the PE receptor, but not the EGF receptor. However,after NR6 was transfected with DNA for the expression of humanEGF receptor, the transfected cell line, designated NRHER5,overexpressed human EGF receptors and became sensitive to EGF-PE(IA).The cytotoxicity of EGF-PE(Ia), but not EGF-PE, to NRHER5 canbe completely blocked by an excess amount of EGF. To completelyreverse the cytotoxicity of EGF-PE on NRHER5, both the EGF receptorpathway and the PE receptor pathway need to be blocked. Theseresults suggest that EGF-PE exhibits both EGF and PE bindingactivities, while EGF-PE(IA) possesses only EGF binding activity.Thus, EGF-PE(Ia) may be a better chimeric toxin than EGF-PEin terms of target specificity to EGF receptor bearing cells.We, therefore, examined the cytotoxicity of EGF-PE(Ia) to varioushuman cancer cell lines. We find that human cancer cells containingmore EGF receptors are more sensitive to EGF-PE(Ia). 相似文献
843.
Yang-Il Jung Byoung-Ki Lee Suk-Joong L. Kang 《Journal of the American Ceramic Society》2004,87(4):739-741
A structural transition of Ba6 Ti17 O40 /BaTiO3 interfaces from faceted to rough was induced by reducing oxygen partial pressure in the atmosphere. As the oxygen partial pressure decreased, the number densities of {111} twins and abnormal grain decreased. TEM observation showed that the twin formation was governed only by the faceting of the interface. Experimental evidence of {111} twin-assisted abnormal growth of faceted BaTiO3 grains was also obtained. 相似文献
844.
Seong Ik Yoo Tae Yeon Lee Jin‐San Yoon Ik‐Mo Lee Mal‐Nam Kim Han Sup Lee 《应用聚合物科学杂志》2002,83(4):767-776
The interfacial reaction of the polyethylene (PE)/starch blend system containing the reactive compatibilizer maleated polyethylene (m‐PE) was directly characterized by Fourier transform infrared (FTIR) spectroscopy. A significant amount of anhydride groups on m‐PE existed as hydrolyzed forms, resulting in a large amount of carboxyl groups. Using a vacuum‐heating‐cell designed in the laboratory, the carboxyl groups were successfully transformed into the dehydrolyzed state (i.e., anhydride group). This result enabled the direct spectroscopic observation of chemical reaction occurring at the interface. For the PE/starch blend system containing m‐PE, the chemical reaction at the interface was verified by the evolution of ester and carboxyl groups in the FTIR spectra. The effect of the reactive compatibilizer on the interfacial morphology was also examined by scanning electron micrography (SEM). Enhanced interfacial adhesion was clearly observed for the blend system containing reactive compatibilizer. Tensile strengths of blend systems containing m‐PE also increased noticeably compared with the corresponding system without compatibilizer. A similar observation was made for the breaking elongation data. © 2002 Wiley Periodicals, Inc. J Appl Polym Sci 83: 767–776, 2002 相似文献
845.
Yoshiyuki Sano Marcekazu Konda Chan Woo Lee Yoshiharu Kimura Takeo Saegusa 《大分子材料与工程》1997,251(1):181-191
A new technique for imparting antistatic properties to poly(ethylene terephthalate) (PET) fiber has been developed. In this technique, blend polyester fibers containing poly(ethylene terephthalate/5-sulfoisophthalate) (SIP-PET) were prepared by blend spinning and then treated with various cationic surfactants in the process of dyeing. The surfactants could effectively be immobilized on the fiber as the counter cations of the sulfonate groups of the 5-sulfoisophthalate (SIP) units and aid the release of static electrons formed in the fiber. Thus, the half-life time (t1/2) of leakage of static charge and the surface resistivity (Rs) of the blend PET fibers became much lower after treating. The best result was obtained with a methylated quaternary ammonium salt of a stearylamine-ethylene oxide (EO) adduct or hydrochloride of a laurylamine-EO adduct as the surfactant of which the number of EO units was around ten. Even after five washing cycles the t1/2 value of the fibers treated with these surfactants was kept lower than 30 s with the Rs value maintained in the order of 1013 Ω cm-2. Therefore, the present technique could be useful for practical production of polyester fibers with “semi-permanent” antistatic properties which can be recovered by re-treatment even if they were lost. 相似文献
846.
A thermally labile polymer, poly(propylene glycol), was modified to obtain PPG having an amino end group. PPG was incorporated into a partially aliphatic polyimide based on an alicyclic dianhydride, and this afforded triblock copolymers containing various amounts of PPG blocks. The thermal properties of the copolymers were investigated by thermogravimetric analysis and differential scanning calorimetry. The thermal decomposition of the PPG block in the copolymers was carried out at 240°C under various pressures to obtain porous polyimide films. The pores remained during the thermolysis under a reduced pressure of 710 mmHg, whereas they collapsed under (near) atmospheric pressure. The pore size increased as the amount of the PPG block in the copolymers increased. The dielectric constants of the porous polyimides varied from 2.60 to 2.42 with the original copolymer composition. © 2006 Wiley Periodicals, Inc. J Appl Polym Sci 101: 532–538, 2006 相似文献
847.
Jyh‐Ping Dong Jyh‐Gau Huang Fuh‐Huah Lee Jiunn‐Wei Roan Yan‐Jyi Huang 《应用聚合物科学杂志》2004,91(5):3388-3397
The effects of three series of self‐synthesized poly(methyl methacrylate) (PMMA)‐based low‐profile additives (LPAs), including PMMA, poly(methyl methacrylate‐co‐butyl acrylate), and poly(methyl methacrylate‐co‐butyl acrylate‐co‐maleic anhydride) with different chemical structures and MWs on the volume shrinkage characteristics and internal pigmentability for low‐shrink unsaturated polyester (UP) resins during curing were investigated by an integrated approach of static phase characteristics of the ternary styrene (ST)/UP/LPA system, reaction kinetics, cured‐sample morphology, microvoid formation, and property measurements. The relative volume fraction of microvoids generated during the cure was controlled by the stiffness of the UP resin used, the compatibility of the uncured ST/UP/LPA systems, and the glass‐transition temperature of the LPAs used. On the basis of the Takayanagi mechanical model, the LPA mechanism on volume shrinkage control, which accounted for phase separation and microvoid formation, and factors leading to both a good volume shrinkage control and acceptable internal pigmentability for the molded parts are discussed. © 2004 Wiley Periodicals, Inc. J Appl Polym Sci 91: 3388–3397, 2004 相似文献
848.
With the wide application of fiber-reinforced composite materials in aircraft, space structures and robot arms, the design and manufacture of composite joints have become a very important research area because they are often the weakest areas in composite structures.
In this paper, the stress and torque transmission capabilities of the adhesively-bonded tubular single lap joint and the double lap joint were experimentally tested. In order to compare the experimental results with the calculated results, the stress and torque transmission capabilities were analyzed by the 3-dimensional finite element method taking into consideration the nonlinear properties of the adhesive.
From the experiments it was found that the torque transmission capabilities of the adhesively-bonded double lap joint was 2.7 times as large as that of the single lap joint. Also, it was found that the fatigue limit of the double lap joint was 16 times as large as that of the single lap joint. 相似文献
In this paper, the stress and torque transmission capabilities of the adhesively-bonded tubular single lap joint and the double lap joint were experimentally tested. In order to compare the experimental results with the calculated results, the stress and torque transmission capabilities were analyzed by the 3-dimensional finite element method taking into consideration the nonlinear properties of the adhesive.
From the experiments it was found that the torque transmission capabilities of the adhesively-bonded double lap joint was 2.7 times as large as that of the single lap joint. Also, it was found that the fatigue limit of the double lap joint was 16 times as large as that of the single lap joint. 相似文献
849.
Organic-inorganic hybrid electrolytes based on poly(propylene glycol)-block-poly(ethylene glycol)-block-poly(propylene glycol) bis(2-aminopropyl ether) (D2000) complexed with LiClO4 via the co-condensation of an epoxy trialkoxysilane and tetraethoxysilane have been prepared and plasticized by a solution of ethylene carbonate (EC)/propylene carbonate (PC) mixture (1:1 by weight). The cross-linked hybrid network shows no solvent exudation and retains a large amount of plasticizer over 70 wt.% in stable state. The in situ built in silica network provides the hybrid electrolytes with good mechanical properties. The ionic conductivity of the dry hybrid electrolyte films was enhanced by two orders of magnitude via plasticization, reaching a maximum conductivity value of 4.0 × 10−3 S/cm at 30 °C. Variable temperature 7Li-{1H} magic angle spinning (MAS) NMR demonstrated that the Li+ cations can be complexed by the polymer network as well as by the plasticizing solvents, but not with the incorporated silica network. Furthermore, the 7Li chemical shift change indicated a progressive change in the lithium coordination from lithium-polymer to lithium-solvent with increasing temperatures. The role of the solvents and the mobility of the lithium ions were investigated by pulsed gradient spin echo (PGSE) NMR measurements to elucidate the behavior of the ionic conductivity. 相似文献
850.
Copoly(ehtylene terephthalate/imide)s (PETI) were prepared by melt polycodensation of bis(2-hydroxyethyl)terephthalate (BHET) and imide containing comonomer, 4,4′-bis[(4-carbo-2-hydroxyethoxy)phthalimido]diphenylmethane (BHEI) with Sb2O3 as catalyst at 280°C under vacuum (~ 1 mm Hg). The change of Tm with an increase of the BHEI repeat unit in the PETI copolymer was analyzed by the Flory equation. On isothermal crystallization, a longer induction time and a lower activation energy than for the PET homopolymer were observed with an increasing amount of BHEI repeat unit. The Avrami exponent, n, increased from 1.5 to 2.3 as the content of BHEI or crystallization temperature was increased. The Avrami rate constant K decreased with the increase of the BHEL unit. On nonisothermal crystallization, the Ozawa equation and Lawton plot were used to investigate the effect of BHEI units on the crystallization kinetics of PETI copolymers. From the change of the cooling crystallization function and the result of the Lawton plot, it was found that the BHEI unit effectively decreases the rate of crystallization. 相似文献