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41.
Partial acidulation of phosphate rock (PR) or compaction of PR with soluble P fertilizers can improve the usefulness of unreactive PR for use as P fertilizer. A greenhouse study was conducted to evaluate nonconventional phosphate fertilizers derived from a low reactive Sukulu Hills PR from Uganda. Raw PR (which contained 341.0 g kg–1 Fe2O3), beneficiated or concentrate PR, partially acidulated PR (PAPR) and PR compacted with triple superphosphate (TSP) were evaluated. Compacted materials had a P ratio of PR:TSP = 50:50. PAPR materials were made by 50% acidulation with H2SO4. TSP was used as a reference fertilizer. Fertilizers were applied to an acidic (pH = 5.4) Hiwassee loam (clayey, kaolinitic, thermic Rhodic Kanhapludults) at rates of 0, 50, 100, 200, 300 and 400 mg P kg–1 soil. Two successive corn (Zea mays L.) crops were grown for 6 weeks. Compacted concentrate PR + TSP and raw PR + TSP were 94.4 and 89.7% as effective as TSP, respectively, in increasing dry-matter yields for the first corn crop. PAPR from the concentrate was 54.8% as effective as TSP. Raw PR, concentrate PR and the PAPR from the raw PR were ineffective in increasing dry-matter yields. The same trends were obtained when P uptake was used to compare effectiveness. Ineffectiveness of the raw PR and its corresponding PAPR was attributed to a high Fe2O3 content in the raw PR. Bray I and Pi paper were found to be nearly equally suitable at estimating available P in the soils treated with responsive fertilizer materials. Mehlich 1 overestimated available P in soil treated with raw PR, concentrate PR or the PAPR from the raw PR. 相似文献
42.
Su‐Hsia Lin Hsiang‐Chien Kao Shih‐Hung Huang Ruey‐Shin Juang 《Journal of chemical technology and biotechnology (Oxford, Oxfordshire : 1986)》2002,77(2):168-174
The equilibrium and kinetics of solvent extraction of Cu2+ from aqueous solutions containing equimolar EDTA with Aliquat 336 in n‐decanol and kerosene at 298 K were investigated. The concentrations of Cu2+ (8–50 mol m?3), Cl? (5–60 mol m?3), and Aliquat 336 (20–100 mol m?3) were varied. A semi‐empirical model with three parameters was proposed to describe the equilibrium behavior, in which the non‐idealities in both aqueous and organic phases were considered. Over the ranges studied, the model agreed reasonably well with the experimental data (standard deviation, 15%). The forward and backward reaction rate constants were determined as (5.31 ± 0.16)×10?6 m9/4 mol?3/4 s?1 and (2.62 ± 0.09)×10?7 s?1, respectively, at 298 K. An interfacial reaction mechanism was proposed, which revealed that the reaction between the chelated anions and trimeric amine molecules at the interface was rate limiting. The derived rate laws were consistent with the experimental results. © 2002 Society of Chemical Industry 相似文献
43.
A new hybrid polymer electrolyte system based on chemical‐covalent polyether and siloxane phases is designed and prepared via the sol–gel approach and epoxide crosslinking. FT‐IR, 13C solid‐state NMR, and thermal analysis (differential scanning calorimetry (DSC) and TGA) are used to characterize the structure of these hybrids. These hybrid films are immersed into the liquid electrolyte (1M LiClO4/propylene carbonate) to form plasticized polymer electrolytes. The effects of hybrid composition, liquid electrolyte content, and temperature on the ionic conductivity of hybrid electrolytes are investigated and discussed. DSC traces demonstrate the presence of two second‐order transitions for all the samples and show a significant change in the thermal events with the amount of absorbed LiClO4/PC content. TGA results indicate these hybrid networks with excellent thermal stability. The EDS‐0.5 sample with a 75 wt % liquid electrolyte exhibits the ionic conductivity of 5.3 × 10?3 S cm?1 at 95°C and 1.4 × 10?3 S cm?1 at 15°C, in which the film shows homogenous and good mechanical strength as well as good chemical stability. In the plot of ionic conductivity and composition for these hybrids containing 45 wt % liquid electrolyte, the conductivity shows a maximum value corresponding to the sample with the weight ratio of GPTMS/PEGDE of 0.1. These obtained results are correlated and used to interpret the ion conduction behavior within the hybrid networks. © 2006 Wiley Periodicals, Inc. J Appl Polym Sci 100: 1000–1007, 2006 相似文献
44.
In this article, we proposed a rapid and continuous process for the production of nanoporous coatings for functional applications.
Experiments following two statistical designs were implemented to screen and investigate the spraying parameters’ effects
on coating crystallinity and porosity in order to gain a better understanding. The spraying standoff distance, solution flow
rate and power were identified as having significant effects on coating porosity and crystallinity. The result yielded a peculiar
microstructure comprised of interpenetrating pores and layered structures with embedded pores. A deposition mechanism was
postulated to explain this microstructure. Ethanol gas sensors that are constructed from the coatings had comparable sensitivities
to those reported in the literature for thick-film coatings and had a maximum sensitivity near 200 °C.
This article is an invited paper selected from presentations at the 2007 International Thermal Spray Conference and has been
expanded from the original presentation. It is simultaneously published in Global Coating Solutions, Proceedings of the 2007 International Thermal Spray Conference, Beijing, China, May 14-16, 2007, Basil R. Marple, Margaret M. Hyland, Yuk-Chiu Lau, Chang-Jiu Li, Rogerio S. Lima, and Ghislain
Montavon, Ed., ASM International, Materials Park, OH, 2007. 相似文献
45.
Myung-Sup Kim Noriaki Kamiyama Chih-Wei Yi Won-Kyu Hong Toshio Tonouchi Chien Chen Wang-Cheol Song 《Journal of Network and Systems Management》2016,24(3):754-763
This article presents a report on APNOMS2015, which was held August 19–21, 2015 in Busan, Korea. The theme of APNOMS2015 was “Managing a Very Connected World.” 相似文献
46.
47.
Broadcasting scheme with low client buffers and bandwidths for video-on-demand applications 总被引:1,自引:1,他引:0
Hsiang-Fu Yu Hung-Chang Yang Yao-Tien Wang Ping-Lin Fan Chu-Yi Chien 《Multimedia Tools and Applications》2009,42(3):295-316
Efficient data broadcasting is independent of request arrivals, and is thus highly promising when transmitting popular videos.
A conventionally adopted broadcasting method is periodic broadcasting, which divides a popular video into segments, which
are then simultaneously broadcast on different data channels. Once clients want to watch the video, they download the segments
from these channels. The skyscraper broadcasting (SkB) scheme supports clients with small bandwidths. An SkB client requires
only two-channel bandwidths to receive video segments. This work proposes a reverse SkB (RSkB) scheme, which extends SkB by
reducing buffering spaces. The RSkB is mathematically shown to achieve on-time video delivery and two-channel client bandwidths.
A formula for determining the maximum number of segments buffered by an RSkB client is presented. Finally, an analysis of
RSkB reveals that its client buffer requirements are usually 25–37% lower than SkB. Extensive simulations of RSkB further
demonstrate that RSkB yields lower client buffer demand than other proposed systems.
相似文献
Hsiang-Fu YuEmail: |
48.
A global sliding‐mode control (GSMC) scheme is proposed to provide a framework for ensuring the existence of a sliding mode throughout an entire response. Based on this framework, robust eigenvalue‐assignment GSMC (REA‐GSMC) is proposed to robustly assign closed‐loop eigenvalues that must be real. The eigenvalues being all real, however, leads to sluggish responses. According to most error criteria such as IAE, ISE, and ITAE, the optimum system should have complex eigenvalues. This paper proposes a GSMC scheme with generalized sliding dynamics, referred to as Generalized GSMC, in order to release the previous constraint on the REA‐GSMC. Thus, the Generalized GSMC can be designed to achieve a system that is both robust and optimum in the sense that it minimizes certain error performance indices in spite of the presence of system uncertainties. Experiments were conducted on a two‐link direct‐drive manipulator to demonstrate the effectiveness of the proposed scheme. Copyright © 2009 John Wiley and Sons Asia Pte Ltd and Chinese Automatic Control Society 相似文献
49.
Single phase (Sr1–x K2x
)Zr4(PO4)6, where x lies between 0.0 and 1.0, ceramic powder with a submicron scale particle size has been synthesized successfully at calcination temperatures as low as 650–750°C by a sol-gel technique. The formation of the powder strongly depends on calcination temperature, but is independent of solution pH in the studied range. Dilatometric measurement shows an ultra-low linear coefficient of thermal expansion of 0.1×10–6°C–1 when x=0.5 at temperature intervals of 25–1000°C. Thermal conductivity and flexural strength of the materials were determined at ambient temperature to be 1.0 Wm–1K–1 and as high as 280 MPa, respectively, indicating that this material can be an excellent candidate in many applications, especially those subjected directly to severe environments. 相似文献
50.
A scheme for distance and velocity signal detection is implemented. This technique is based on a laser diode with its frequency modulated by a triangular waveform and followed by time gating. 相似文献