Arsenic levels in wipe samples collected from play structures constructed with CCA-treated wood: Impact on exposure estimates

Lumber treated with chromated copper arsenate (CCA) has been used in residential outdoor wood structures and playgrounds. The U.S. EPA has conducted a probabilistic assessment of children's exposure to arsenic from CCA-treated structures using the Stochastic Human Exposure and Dose Simulation model for the wood preservative scenario (SHEDS-Wood). The EPA assessment relied on data from an experimental study using adult volunteers and designed to measure arsenic in maximum hand and wipe loadings. Analyses using arsenic handloading data from a study of children playing on CCA-treated play structures in Edmonton, Canada, indicate that the maximum handloading values significantly overestimate the exposure that occurs during actual play. The objective of our paper is to assess whether the dislodgeable arsenic residues from structures in the Edmonton study are comparable to those observed in other studies and whether they support the conclusion that the values derived by EPA using modeled maximum loading values overestimate hand exposures. We compared dislodgeable arsenic residue data from structures in the playgrounds in the Edmonton study to levels observed in studies used in EPA's assessment. Our analysis showed that the dislodgeable arsenic levels in the Edmonton playground structures are similar to those in the studies used by EPA. Hence, the exposure estimates derived using the handloading data from children playing on CCA-treated structures are more representative of children's actual exposures than the overestimates derived by EPA using modeled maximum values. Handloading data from children playing on CCA-treated structures should be used to reduce the uncertainty of modeled estimates derived using the SHEDS-Wood model.     

Diameter of Single-Walled Carbon Nanotubes (SWCNTs) as an Effective Factor in the Detection and Degradation of PCBs

Polychlorinated biphenyls (PCBs) are chlorinated organic compounds and well known carcinogenic and toxic pollutants. Currently, their detection and degradation to products with less risk are among environmental and health priorities. Passing 2,2′,4,4′,5,5′-Hexachlorobiphenyl (PCB-153) through the armchair single-walled carbon nanotubes (SWCNTs) (8, 8) and (10, 10) was investigated by Modified Neglect of Diatomic Overlap in the semi-empirical method. The analysis of results suggests that there are meaningful changes in the middle of the tubes. Based on the obtained evidence, the nanotubes have substantial potential to interact with the PCB-153 molecule effectively. The results show that the increased diameter in the armchair SWCNTs improves the detection and degradation potential of the tube to PCBs. According to the calculated thermodynamic parameters, the diameter of nano-structures is an effective factor in PCBs removal efficiency, as it could be helpful to make a more sensitive PCB nano-sensor.     

Assessing the impact of nanomaterials on anaerobic microbial communities

As the technological benefits of nanotechnology begin to rapidly move from laboratory to large-scale industrial application, release of nanomaterials to the environment is inevitable. Little is known about the fate and effects of nanomaterials in nature. Major environmental receptors of nanomaterials will be soil, sediment, and biosolids from wastewater treatment. Analysis of anaerobic microbial activity and communities provides needed information about the effects of nanoparticles in certain environments. In this study, biosolids from anaerobic wastewater treatment sludge were exposed to fullerene (C60) in order to model an environmentally relevant discharge scenario. Activity was assessed by monitoring production of CO2 and CH4. Changes in community structure were monitored by denaturing gradient gel electrophoresis (DGGE), using primer sets targeting the small subunit rRNA genes of Bacteria, Archaea, and Eukarya. Findings suggest that C60 fullerenes have no significant effect on the anaerobic community over an exposure period of a few months. This conclusion is based on the absence of toxicity indicated by no change in methanogenesis relative to untreated reference samples. DGGE results show no evidence of substantial community shifts due to treatment with C60, in any subset of the microbial community.     

The application of internet of things in healthcare: a systematic literature review and classification

Universal Access in the Information Society - The Internet of Things (IoT) is an ecosystem that integrates physical objects, software and hardware to interact with each other. Aging of population,...     

The rural–urban equity nexus of Metro Manila’s water system

ABSTRACT

This article examines equity concerns and inherent conflicts related to rural–urban water supply allocation and use, with focus on Metro Manila. Going beyond the much-discussed difficulty farmers experience from an allocation policy prioritizing urban water requirements, it shows that inequity in raw water allocation is linked to, and further exacerbated by, inequities in urban domestic water provision. Moreover, it highlights the need for broader equity reviews, using the concept of the rural–urban water equity nexus to draw attention to key equity considerations across space and scale that otherwise might remain invisible.     

Energy Efficiency Optimization for Wireless Body Area Networks Under 802.15.6 Standard

Wireless Personal Communications - With the attractive applications in e-Health, a booming interest is granted to wireless body area network (WBAN). Through WBAN, healthcare professionals can...     

Privacy‐preserving authentication scheme for on‐road on‐demand refilling of pseudonym in VANET

Privacy in Vehicular Ad Hoc Networks (VANET) is fundamental because the user's safety may be threatened by the identity and the real‐time spatiotemporal data exchanged on the network. This issue is commonly addressed by the use of certified temporal pseudonyms and their updating strategies to ensure the user's unlinkability and anonymity. IEEE 1609.2 Standard specified the process of certifying pseudonym along with certificates structure. However, the communication procedure between the certifying authority and the requesting vehicle was not defined. In this paper, a new privacy‐preserving solution for pseudonym on‐road on‐demand refilling is proposed where the vehicle anonymously authenticates itself to the regional authority subsidiary of the central trusted authority to request a new pseudonyms pool. The authentication method has two phases, the first one uses anonymous tickets, and the second one is a challenge‐based authentication. The anonymous tickets are certificates that do not include the identity of the user. Instead, it contains a reference number and the certifying authority signature. The challenge authentication is identity‐less to preserve the privacy, yet it is used to prevent the misuse of tickets and the impersonation of its owner. Our proposed scheme is analyzed by the use of Burrows, Abadi and Needham (BAN) logic to demonstrate its correctness. It is also specified and checked by using the Security Protocol ANimator (SPAN) and the Automated Validation of Internet Security Protocols and Applications (AVISPA) tools. The logical demonstration proved that this privacy‐preserving authentication is assured. The SPAN and AVISPA tools illustrated that it is resilient to security attacks.     

Fabrication of Millimeter‐Long Carbon Tubular Nanostructures Using the Self‐Rolling Process Inherent in Elastic Protein Layers

Millimeter‐long conducting fibers can be fabricated from carbon nanomaterials via a simple method involving the release of a prestrained protein layer. This study shows how a self‐rolling process initiated by polymerization of a micropatterned layer of fibronectin (FN) results in the production of carbon nanomaterial‐based microtubular fibers. The process begins with deposition of carbon nanotube (CNT) or graphene oxide (GO) particles on the FN layer. Before polymerization, particles are discrete and nonconducting, but after polymerization the carbon materials become entangled to form an interconnected conducting network clad by FN. Selective removal of FN using high‐temperature combustion yields freestanding CNT or reduced GO microtubular fibers. The properties of these fibers are characterized using atomic force microscopy and Raman spectroscopy. The data suggest that this method may provide a ready route to rapid design and fabrication of aligned biohybrid nanomaterials potentially useful for future electronic applications.