乙烯基三甲基硅烷等离子体聚合反应历程

应用色谱—质谱(GC-MS)及裂解色谱-质谱(PGC-MS)测定了乙烯基三甲基硅烷等离子体聚合反应中的气体冷凝物及聚合物,研究推导了等离子体聚合反应历程。单体在气相中被电子撞击,然后扩散到基底,在基底发生链增长和链终止反应。     

Use of Explosives on The Moon

The utilization of explosives for excavation on the lunar surface is under serious consideration as a part of the design for construction of temporary and permanent bases. An excavation research program has shown that small‐scale explosives blasting in a lunar‐soil simulant will greatly reduce the digging forces required for scoop and dragline excavators. Some crater‐blasting parameters were determined for the lunar soil simulant at one Earth gravity and at 10 Earth gravities using a centrifuge. The size of the craters produced at 10 Earth gs matched those formed at one earth g by scaling according to the weight of the explosive. These data can be applied to explosive‐excavation problems such as habitat construction, burial of nuclear power sources, and the rapid construction of shelters remote from the main base to shield against solar‐flare activity.     

Matrix morphology and fibre pull-out strength of T700/PPS and T700/PET thermoplastic composites

The main objective of this fundamental study was to investigate effects of processing conditions and resulting matrix morphology on interfacial bond strength of fibre reinforced thermoplastic composites. Using a hot stage microscope, single fibre pull-out samples were produced with T700S high strength carbon fibre and two semicrystalline thermoplastic matrices, polyphenylene sulphide (PPS) and polyethylene terephthalate (PET), respectively. Processing temperatures and cooling histories were the major variables in sample preparation. The T700S fibre had no clear effect on the surrounding PPS and PET matrix morphology, as long as direct cooling at constant rates was selected. A transcrystalline phase around the fibres could be induced in the T700S/PPS system, if isothermal crystallization was carried out at 227°C. Fibre pull-out tests were conducted at room temperature and two basic failure paths were observed, i.e. debonding at the fibre-matrix interface and cohesive failure of the matrix close to the fibre surface. The results indicate that slow cooling rate and a resulting coarse spherulitic morphology around the fibres correlate with high interfacial shear strength. In fact somewhat higher strength values were obtained for samples with transcrystalline layers around the fibres.     

Laboratory aid and ultrasonography in the diagnosis of appendicitis in children

The purpose of this study was to evaluate the relationship between the number of yolk sacs and amnionicity in monochorionic twin pregnancies scanned early in the first trimester. We retrospectively reviewed images of all monochorionic twins scanned between 6 and 9.5 weeks' gestation and with pathologic or sonographic confirmation of chorionicity-amnionicity. Each film was reviewed for the number of yolk sacs present, as well as for the gestational age at which the amniotic membrane was first visualized. Twenty monochorionic-diamniotic pregnancies and two monochorionic-monoamniotic pregnancies met the criteria for inclusion in the study. In diamniotic pregnancies scanned at less than 8 weeks' gestation, only the yolk sacs were identified; none of the dividing amniotic membranes were detected. Two yolk sacs were identified in all but one case. In this case, although one yolk sac was seen at 6 weeks, follow-up scanning at 8 weeks revealed two yolk sacs. In each of the monochorionic-monoamniotic twin pregnancies, one yolk sac was seen at 9 weeks and a single amnion encircled both embryos. We conclude that the sonographic identification of two yolk scas in monochorionic twins enables us to make the diagnosis of diamniotic twins early in the first trimester, before the amniotic membrane can be imaged. The presence of one yolk sac should prompt a follow-up ultrasonogram to assign amnionicity definitively.     

Economics of liquid hydrogen from water electrolysis

Using the data from vendors and open literature, we have constructed a preliminary cost model to predict the cost of liquid hydrogen (LH₂) from water electrolysis. The model has been applied to two LH₂ plants. Both have a production rate of 10 886 kg day⁻¹. The first plant (Plant 1) consists of a tank-type electrolyzer and a liquefier and runs all day at the base-load (or equivalent base-load) power rate. The second (Plant 2) consists of a tank-type electrolyzer, a liquefier, a compressor, and storage vessels. The electrolyzer and the compressor shall run only during the off-peak hours at the off-peak power rate. However, the liquefier shall run all day at the base-load (or equivalent base-load) power rate. The costs of LH₂ from both plants are presented. Unless the base-load power rate is high and the off-peak power rate is substantially low, Plant 1 appears to be economically more feasible than Plant 2.     

Cloud analysis by modeling the integration of heterogeneous satellite data and imaging

This paper presents a computer-aided cloud-analysis approach by effectively modeling the integration of heterogeneous satellite-observed data and remote sensing images. First, automatic cloud detection and tracking methods are proposed to identify the georeferenced cloud objects in satellite remote sensing images. Then, a data integration modeling mechanism is designed to collect meaningful properties of those detected clouds by integrating the heterogeneous satellite-observed data and imaging into a unified cloud database. Finally, based on the integrated global data schema, a two-phase data mining method employing the decision tree algorithm is implemented to analyze and forecast the meteorological activities of all the cloud objects. Experimental results have shown that the proposed data integration model can effectively extract and synthesize all the useful information from heterogeneous data sources to generate a unified view of knowledge, on the basis of which the evolvement trends of clouds can be analyzed properly.     

An empirical formula for the prediction of rain attenuation infrequency range 0.6 - 100 GHz

An empirical formula for calculating the extinction cross section (ECS) by raindrops over a broad frequency range is first derived based on extensive calculations made on a widely varying in mean radius of modified Pruppacher and Pitter (MPP) raindrop models ranging from 0.25 to 3.5 mm. The expansion coefficients in the empirical formula are determined by least-squares curve fitting of numerical data obtained by the volume integral equation formulation (VIEF). The formula satisfies the frequency and raindrop size dependence. Numerical results obtained from the empirical formula for calculating the ECS are generally in good agreement with those calculated by the VIEF for raindrops with mean radius varying from 0.25 to 3.5 mm in the frequency range from 0.6 to 100 GHz. The average error in the ECS is less than 10%. The formula thus provides a simple and inexpensive method for calculating the ECS of raindrops, which otherwise requires complicated and expensive methods of calculation. By implementing this empirical formula of ECS into the rain attenuation equation, a new numerically empirical formula for calculating the specific rain attenuation is also proposed. The validity of the empirical formula for calculating the specific rain attenuation is also checked by comparing the obtained results of specific rain attenuation with those obtained from Li et al.'s (1995) solution, Yeo et al.'s (1993) measurement, and Olsen et al.'s (1978) power-law equation