Using silica nanoparticles as curing reagents for epoxy resins to form epoxy–silica nanocomposites

Nanoscale colloidal silica showed high reactivity toward curing epoxy resins to form epoxy–silica nanocomposites under mild conditions. Adding a certain amount (5000 ppm) of magnesium chloride lowered the activation energy of the reaction from 71 to 46 kJ/mol. Less and more magnesium chloride both exhibited counter action on lowering the activation energy of the curing reaction. Tin chloride dihydrate and zinc acetylacetonate hydrate were also added into the curing compositions, however, showing no significant effect on promoting the curing reaction. Through this curing reaction, epoxy–silica nanocomposites containing high silica contents up to 70 wt % were obtained. Therefore, this reaction provided a novel and convenient route in preparation of epoxy–silica nanocomposites. © 2005 Wiley Periodicals, Inc. J Appl Polym Sci 95: 1237–1245, 2005     

甲缩醛空气氧化制甲醛催化剂的研制和工艺条件探讨

考察了铁钼催化剂对甲缩醛空气氧化制甲醛的催化性能。制备了多种不同钼铁比和第三、第四组分的催化剂,进行了活性评价和筛选,探讨了适宜的工艺条件范围。对于所选定的催化剂(钼铁比为1.82～1.88;铬铁比为0.1～0.38)在适宜的工艺条件(甲缩醛进料浓度4.5～5.5％;甲缩醛和氧气进料比1:2.0±0.2;空速12000～22000h~(-1);热点温度370～390℃)下,甲醛收率可达85％左右。     

Analysis and design of secure cyber-physical systems

Cyber-physical systems （CPSs） are new emerging systems that seamlessly integrate physical systems, communication systems and computation systems. Their wide use has been witnessed in the past decades in many crossdiscipline fields such as smart energy systems, industrial process control, aerospace and automobile engineering, health-care and assisted living, to just name a few. For many of these systems, secure operations are of key con- cerns. In particular, for some safety-critical applications, security is of paramount importance. Diverse motivations and strong incentives exist everywhere and at any time for launching malicious attacks on the CPSs, for example, economic reasons （e.g., by reducing or even not paying electricity charge） and terrorism the purpose of which is apparent.     

Impact of H+ ion irradiation on Matrimid®. I. Evolution in chemical structure

Ion beam irradiation can be used to modify the structure and gas transport properties of glassy polymers. This is the first of two studies that focus on the impact of H⁺ ion irradiation on the structure and permeation properties of the polyimide Matrimid®. Specifically, the evolution in chemical structure after H⁺ irradiation over a range of fluences was analyzed using FTIR spectroscopy and dissolution studies. Although H⁺ ion irradiation at very low ion fluences induced little modification in the chemical structure, irradiation at relatively high ion fluences resulted in crosslinking of the irradiated films. The branched structure of the aliphatic methyl (CH₃) was the most sensitive to the H⁺ ion irradiation. The para‐disubstituted aromatic ring showed the strongest resistance toward ion irradiation and required fairly high doses to induce degradation. Two potential crosslinking mechanisms related to the degradation of the aliphatic methyl and the benzophenone carbonyl were presented. © 2003 Wiley Periodicals, Inc. J Appl Polym Sci 90: 2010–2019, 2003     

沥青表面形貌的表征与测试及其对与集料接触特性的影响

采用原子力显微镜对SK90#基质沥青和SBSⅠ-C改性沥青的表面形貌进行了测试,获得了两种沥青的表面形貌参数,并基于此对沥青的表面形貌特性进行了分析;基于沥青表面的高度概率密度曲线和承载面曲线,从界面实际接触面积的角度分析了沥青表面特性对与集料接触特性的影响.结果表明,SBSⅠ-C改性沥青的表面起伏情况高于SK90#基质沥青,具有更大的表面粗糙度.具有更大Ssk(歪斜度)的沥青更有利于形成更好的黏附强度,但也更容易发生磨损而使黏附性能快速降低.沥青与集料间的接触性能受其实际接触面积的影响,SBSⅠ-C改性沥青具有与集料更大的实际接触面积,从而形成更大的摩擦力而具有更优良的黏附性能.     

抗咽喉炎常见菌IgY抗体的制备及其特性的研究

目的制备抗β-溶血性链球菌、G簇溶血性链球菌、金黄色葡萄球菌3种咽喉炎常见菌IgY抗体,并分析其特性。方法采用超声波破碎法将3种咽喉菌制备成可溶性抗原液,免疫产蛋母鸡,从鸡蛋黄中提取IgY抗体,应用免疫电泳、ELISA、SDS-PAGE检测抗3种咽喉菌IgY抗体的特性及热稳定性。结果抗原免疫母鸡10d后,鸡蛋黄中即有抗3种咽喉菌的IgY抗体产生,60d时抗体滴度高达1∶102400,IgY抗体滴度在室温可保持5~6个月不变。结论制备的抗3种咽喉菌IgY抗体滴度高,特异性强,稳定性好。     

Morphology and characterization of conductive films based on polyaniline‐coated polystyrene latexes

The polyaniline (PANI)‐coated polystyrene (PS) latexes were synthesized, and the electrically conductive films were prepared thereafter. The weight ratio of PANI was 5%. Thermal analysis of the latices was performed using DSC and TGA. In this study, the electrically conductive films were prepared above the PS glass transition temperature (T_g). During the film formation, the effects of the annealing temperature and atmosphere (air or N₂) on the film resistance were investigated. In addition, the film morphology was observed utilizing scanning electron microscopy. The film resistance decreased in the initial heating stage due to the increasing temperature and the compaction of film. Then the film resistance increased with further annealing due to the aging of PANI. Typically, the film resistance was about 6000 Ω/sq, and the conductivity was 0.3 S/cm. © 2006 Wiley Periodicals, Inc. J Appl Polym Sci 102: 5406–5413, 2006     

基于共享存储的Web服务交互模型的研究

结合异步通信与持久性信息共享的思想,将共享存储引入到Web服务设计中,为Web服务的提供一种持久的、全局可访问的异步交互活动模式.分析结果表明,本文模型向Web服务提供了一种符合REST风格的异步交互活动模式.     

微博观点句识别的话题影响研究

为了从海量的网络信息中迅速准确地获取评价信息,观点句识别已经成了自然语言处理的一个研究热点。现在观点句识别系统大都是基于机器学习的方法,一般使用机器学习的方法来进行分类会受到领域差异性影响。针对这个问题,该文对微博观点句识别系统是否会受到微博话题影响做了经验性研究,同时为了弥补训练数据的不足,该文通过规则方法自动标注网络数据进行了训练集的扩充。实验结果表明,微博话题间存在差异,进行分话题模型训练可以提升微博观点句识别系统的性能。     

Accommodation and convergence in integral imaging 3D display

In this paper, we analyze the visual fatigue of integral imaging three‐dimensional (3D) display by studying the accommodation and convergence when viewing the integral imaging 3D images. The theoretical analyses show that there is no inconsistency between the accommodation and convergence distances, which means that the integral imaging 3D display has no visual fatigue. Experiments are implemented, and the results finally demonstrate the rationality of the theoretical analyses. These analyses can be quite beneficial for researchers to better understand the performances and promote the practical applications of the integral imaging 3D display.