Monodisperse Hollow Supraparticles via Selective Oxidation

A novel and general strategy to fabricate monodisperse hollow supraparticles (SPs) via selective chemical oxidation is developed. Core‐shell SPs made of semiconductor nanocrystals (NCs) are first obtained by an in situ assembly method. Subsequently, the cores can be selectively removed by preferential oxidation with dilute H₂O₂, resulting in formation of monodisperse hollow SPs. The structural parameters of the products, such as size, shell thickness, and composition, are tailored easily. The hollow structures achieved from CdSe/CdS core‐shell SPs possess high fluorescence quantum yields and a large Stokes shift, the latter is remarkably different from that of conventional organic dyes and quantum dots. In addition to simple hollow structures, rattle‐type nanostructures composed of semiconductor SPs or noble metal‐semiconductor hybrids are also prepared, exemplifying the versatility of the proposed strategy.     

基于低压高精度运放的带隙基准电压源设计

基于传统带隙基准源的电路结构,采用电平移位的折叠共源共栅输入级和甲乙类互补推挽共源输出级改进了其运算放大器的性能,并结合一阶温度补偿、电流负反馈技术设计了一款低温度系数、高电源电压抑制比(PSRR)的低压基准电压源。利用华润上华公司的CSMC 0.35μm标准CMOS工艺对电路进行了Hspice仿真,该带隙基准源电路的电源工作范围为1.5～2.3 V,输出基准电压为(600±0.2)mV;工作温度为10～130℃,输出电压仅变化8μV,温度系数为1.86×10-6/℃,低频时PSRR为-72 dB。实际流片进行测试,结果表明达到了预期结果。     

Photo‐Induced Charge‐Variable Conjugated Polyelectrolyte Brushes Encapsulating Upconversion Nanoparticles for Promoted siRNA Release and Collaborative Photodynamic Therapy under NIR Light Irradiation

Combination of photodynamic therapy (PDT) with small interfering RNA (siRNA) therapy has become a major strategy in cancer treatment for enhancing anticancer efficacy. However, developing nanoplatform that can promote siRNA release and collaborate with efficient PDT under NIR light irradiation is still a big challenge. Photo‐induced charge‐variable conjugated polyelectrolyte brushes encapsulating upconversion nanoparticles (UCNP@CCPEB) as an efficient nanoplatform are reported. Cationic conjugated polyelectrolyte brush (CCPEB) is synthesized through quaternary ammoniation of N‐functionalized polyfluorene brush by photodegradable 2‐nitrobenzyl‐2‐bromoacetate. CCPEB with abundant positive charges and intrinsic photosensitizer (PS) performance is good for integrating siRNA carrier and PS into one molecule. The obtained CCPEB next encapsulates upconversion nanoparticle for realizing its NIR light excitation. Agarose gel electrophoresis experiments show that UCNP@CCPEB present good stability and excellent siRNA‐loading capacity (1 mol UCNP@CCPEB to at least 32.5 mol siRNA). Under 980 nm light irradiation, UCNP@CCPEB exhibit efficient single oxygen production for PDT. Concurrently, the photoresponsive cationic side‐chain of CCPEB turns into zwitterionic chain and thus accelerates its siRNA release to 80%. In vitro and in vivo experiments show that the successful A549 tumor suppression is achieved by UCNP@CCPEB/siPlk1 complex under 980 irradiation. It is envisioned that UCNP@CCPEB can serve as an efficient platform for combining various phototherapies together.     

Multifunctional Electrode Design Consisting of 3D Porous Separator Modulated with Patterned Anode for High‐Performance Dual‐Ion Batteries

Searching for low‐cost and high‐capacity electrode materials such as metal anodes is of important significance for the development of new generation rechargeable batteries. However, metal anodes always suffer from severe volume expansion/contraction during a repeated electrochemical alloying/dealloying process. In this study, a novel concept about modifying metal‐anodes‐based battery construction with a multifunctional electrode (ME) design is provided. The ME consists of a 3D porous separator that is modulated with a patterned aluminum anode, which simultaneously works as a current collector, anode material, and separator in a dual‐ion battery (DIB). The 3D porous separator not only enables the ME to possess significantly improved electrolyte uptake and retention capabilities, but also acts as a protecting layer to restrict the surface pulverization of the Al anode. The ME‐DIB displays remarkably enhanced cell performances, including excellent cycling stability with 92.4% capacity retention after 1000 cycles at a current density of 2 C, and superior rate performance with 80.7% capacity retention at 10 C.     

Generation of four-photon GHZ states based on interaction between a four-level atom and two bimodal cavities

A simple scheme is presented for generating four-photon Greenberger-Horne-Zeilinger (GHZ) states with interaction between a four-level atom and two bimodal cavities. In the proposed protocol, the quantum information is encoded on Fock states of the cavity fields. The detection of the atom can collapse the cavity to the desired state. The experimental feasibility of our proposal is also discussed.     

采用混合晶向实现PMOSFET迁移率提升了150%

本文提出了一种基于混合晶向硅材料的高性能PMOSFET 器件。采用硅玻键合、化学机械抛光、硅刻蚀和非选择性外延等方法,成功制作了集成有（100）和（110）晶向的混合晶向硅片。基于这种混合晶向材料,成功研制了沟道宽长比为50：8 的PMOSFET器件,器件测试结果表明：制作在（110）晶向上的PMOSFET 器件在低场条件下,电流驱动能力提高了50.7%,最大迁移率增加了150%,是当前见于报道的PMOSFET迁移率提升指标较高的一颗器件。     

城域网的业务需求及其与MSTP网络互联互通场景分析

随着数据业务的发展,分组城域网建设已成为各大网络运营商所关注的重点,文章从业务承载角度出发,在分析未来各种新兴业务传输承载需求的基础上,重点讨论了分组城域网与现有MSTP网络互联互通的组网策略。     

基于SiGe虚拟衬底的低场迁移率提升140%的应变Si沟道NMOS器件 Cui Wei(崔伟)1,2,Tang Zhaohuan(唐昭焕)2, Tan Kaizhou(谭开洲)2, Zhang Jing(张静)2,

本文研究了一种应变SiGe沟道的NMOS器件,通过调整硅帽层、SiGe缓冲层,沟道掺杂和Ge组分变化,并采用变能量硼注入形成P阱的方式,成功完成了应变NMOS器件的制作。测试结果表明应变的NMOS器件在低场(Vgs=3.5V, Vds=0.5V)条件下,迁移率极值提升了140%,而PMOS器件性能保持不变。文中对硅基应变增强机理进行了分析。并利用此NMOS器件研制了一款CMOS倒向器,倒向器特性良好, 没有漏电,高低电平转换正常。     

瑞利测风激光雷达接收机校准

介绍了直接探测瑞利测风激光雷达工作及风速反演的原理,说明了激光雷达接收机的内部结构及工作情况。为修正雷达接收机中分光片分束比、单光子计数器探测率等参数与设计值的偏差所导致的风速测量误差,提出了随光强变化比较两信号通道的计数值的接收机校准方案。实验测得了校准系数随信号通道信号强度的变化关系。在弱光下该系统两信号通道性能差异小于25%。在当前系统的标准具透过率条件和对称的风场扫描合成方式下,接收机校准只对系统透过率曲线和径向风速的测量有较大影响,对合成风场没有影响。