Miniature erbium:ytterbium fiber Fabry-Perot multiwavelength lasers

We demonstrate stable simultaneous lasing of up to 29 wavelengths in miniature 1- and 2-mm-long Er³⁺:Yb³⁺ fiber Fabry-Perot lasers. The wavelengths are separated by 0.8 (100 GHz) and 0.4 nm (50 GHz), respectively, corresponding to the free spectral range of the laser cavity. The number of lasing wavelengths and the power stability of the individual modes are greatly enhanced by cooling the laser in liquid nitrogen (77 K). The polarization modes and linewidth of each wavelength are measured with high resolution by heterodyning with a local oscillator. The homogeneous linewidth of the Er³⁺:Yb ³⁺ fiber at 77 K is determined to be ~0.5 nm, from spectral-hole-burning measurements, which accounts for the generation of a stable multiwavelength lasing comb with wavelength separations of 0.4 nm     

Experimental Study of Seismic Behaviors of As-Built and Carbon Fiber Reinforced Plastics Repaired Reinforced Concrete Bridge Columns

In order to reliably obtain seismic responses of as-built and repaired reinforced concrete bridge columns under near-fault ground motions, pseudodynamic testing of two bridge columns with a reduced scale of 2/5 was performed. Pseudodynamic test results reveal that a ductile member may have no chance to entirely develop its ductile behavior to dissipate seismic energy, because it may suddenly be destroyed by a significant pulse-like wave. The seismic performance of the two damaged bridge columns can be recovered after repair with carbon fiber reinforced plastics composite sheets. It is also experimentally confirmed that the flexural failure moment obtained from the pseudodynamic test is in good agreement with the plastic moment predicted by the ACI 318 code. As pseudodynamic test results are believed to be more accurate than numerical solutions, they can be considered as reference solutions in developing a finite-element model. An identical specimen was tested under cyclic loading to estimate basic properties of these columns, such as shear strength, flexural strength, and ductility, so that the seismic responses obtained from pseudodynamic tests can be thoroughly discussed. Furthermore, its hysteretic response may also be used to match a mathematical model to simulate the very complicated load-displacement relation for analysis.     

A Six-sigma approach for benchmarking of RP&M processes

This paper presents a methodology of using six-sigma quality tools for benchmarking of rapid prototyping & manufacturing (RP&M) processes. It involves the fabrication of a geometric benchmark part and a methodology to control and identify the best performance of the process to reduce the variablity in the fabricated parts. The approach is demonstrated with a case study based on the direct laser sintering (DLS) process for prototyping using plastic powder. In the case study an identified set of six-sigma/ statistical process control tools is employed to determine and best tune factors affecting the desired outcomes of the built parts.     

Computational models of germanium point contact detectors

In the crystal bulk of group IV covalent semiconductors such as germanium (Ge), simple analytic models for the valence band structure can provide fast, accurate computations of hole mobility for moderate energy ranges up to a few eV. On the surfaces of these materials, such as on Ge-vacuum or Ge-GeO₂ interfaces, the transport rates differ significantly from the bulk. This can be problematic for both point contact and segmented Ge gamma ray detectors, that require accurate carrier drift rates for computing signal basis sets, which themselves are necessary for the precise determination of gamma-ray induced compton scattering events. While several techniques exist for computing surface hole mobilities, more often than not, these methods are complex to implement, require significant computational resources, and lack the simplicity of bulk models for interpreting results. This paper presents a new technique for computing Ge surface hole mobility that can give a first estimate for the surface transport rates after tuning a physically based computational parameter. This model is used in conjunction with particle-in-cell (PIC) simulations for modeling hole-dynamics inside a Ge p-type point contact detector. The results of our calculations agree with experimental data gathered from Ge p-type point contact detectors at Oak Ridge National Laboratory.     

Association of size‐fractionated indoor particulate matter and black carbon with heart rate variability in healthy elderly women in Beijing

Associations between size‐fractionated indoor particulate matter (PM) and black carbon (BC) and heart rate variability (HRV) and heart rate (HR) in elderly women remain unclear. Twenty‐nine healthy elderly women were measured for 24‐hour HRV/HR indices. Real‐time size‐fractionated indoor PM and BC were monitored on the same day and on the preceding day. Mixed‐effects models were applied to investigate the associations between pollutants and HRV/HR indices. Increases in size‐fractionated indoor PM were significantly associated with declines in power in the high‐frequency band (HF), power in the low‐frequency band (LF), and standard deviation of all NN intervals (SDNN). The largest decline in HF was 19% at 5‐minute moving average for an interquartile range (IQR) increase (24 μg/m³) in PM_0.5. The results showed that smaller particles could lead to greater reductions in HRV indices. The reported associations were modified by body mass index (BMI): Declines in HF at 5‐minute average for an IQR increase in PM_0.5 were 34.5% and 1.0% for overweight (BMI ≥25 kg/m²) and normal‐weight (BMI <25 kg/m²) participants, respectively. Moreover, negative associations between BC and HRV indices were found to be significant in overweight participants. Increases in size‐fractionated indoor PM and BC were associated with compromised cardiac autonomic function in healthy elderly women, especially overweight ones.     

Cu-assisted induced atomic-level bivalent Fe confined on N-doped carbon concave dodecahedrons for acid oxygen reduction electrocatalysis

Atomically dispersed transition metals anchored on N-doped carbon have been successfully developed as promising electrocatalysts for acidic oxygen reduction reaction (ORR). Nonetheless, how to introduce and construct single-atomic active sites is still a big challenge. Herein, a novel concave dodecahedron catalyst of N-doped carbon (FeCuNC) with well confined atomically dispersed bivalent Fe sites was facilely developed via a Cu-assisted induced strategy. The obtained catalyst delivered outstanding ORR performance in 0.5 M H₂SO₄ media with a half-wave potential (E_1/2) of 0.82 V (vs reversible hydrogen electrode, RHE), stemming from the highly active bivalent Fe-N_x sites with sufficient exposure and accessibility guaranteed by the high specific surface area and curved surface. This work provides a simple but efficient metal-assisted induced strategy to tune the configurations of atomically dispersed active sites as well as microscopy structures of carbon matrix to develop promising PGM-free catalysts for proton exchange membrane fuel cell (PEMFC) applications.     

Analytical Landau-type model of polarization switching in ferroelectrics

The polarization switching properties of ferroelectric materials have been extensively studied, both experimentally and theoretically owing to their wide applications in industry and hence generating a need to gain a deeper understanding of factors affecting their switching behaviour. In this paper, an analytical Landau theory incorporating the Landau–Khalatnikov equation has been developed to describe the switching properties of second order ferroelectrics. Analytical expressions derived from exact results of Landau theory are used in modelling work carried out in this study for comparison with trends predicted by empirical laws used to describe polarization switching behaviour at high electric fields. As such this work has established the theoretical basis for empirical laws of polarization switching and developed simple numerical tools which can be quickly used to model trends in polarization switching behaviour of ferroelectrics.     

Influence of nitrogen doping on carbon nanotubes towards the structure,composition and oxygen reduction reaction

Nitrogen-doped carbon nanotubes (NCNTs) as noble-metal free catalysts were synthesised via chemical vapour deposition using iron (II) phthalocyanine as a metal catalyst for growth of the nanotubes. The synthesis process was performed in one step in a tube furnace using different chemical precursors (aniline, diethylamine and ethylenediamine) as nitrogen sources. The NCNT samples were physically characterised using scanning electron microscopy, transmission electronic microscopy and X-ray photoelectron spectroscopy. Cyclic voltammetry measurements were conducted to investigate the oxygen reduction reaction (ORR), and they showed that the electrocatalytic activities depend on the structural and morphological changes in the NCNTs. The results showed that NCNTs synthesised from ethylenediamine precursors exhibit an ORR scheme proceed via indirect four electron transfer process in acidic media, which implies that these NCNTs are a candidate for serving as the cathodic catalyst in PEMFCs. The highly active NCNTs possess unique characteristics, including a high concentration of surface defects with high pyridinic-N and pyridinic-N-oxides configurations that serve as active sites for ORR activity in acidic media.     

Computer simulation of viscoelastic flow at the entry region

Non-Newtonian flow has a nonlinear constitutive relationship with an advective nature. It was found that in highly advective (convective) problems, the Galerkin formulation “under-diffused,” resulting in divergence at low elastic numbers. The use of the Streamline-Upwinding (SU) method improved the solution, especially when used with the Phan-Thien-Tanner (PTT) model. At the boundary discontinuity, however, the stress gradient did not necessarily flow along the streamline direction, and oscillations still remained at the corner. The Discontinuity-Capturing (DC) method resolved this problem by applying control in the direction of the stress gradient rather than the stream line direction, and a smoother solution at the corner region was achieved.     

Effect of constitutive models on the numerical simulation of viscoelastic flow at an entry region

The poor solutions of numerical simulations at a contraction has often been attributed to the numerical scheme used. However, the solution of a numerical simulation is also highly dependent on the constitutive equation. A study of various constitutive equations on the simulation of the 4:1 contraction flow is made in this paper, and their effects on the results analyzed. The constitutive models considered include the Upper Convected Maxwell model, the Oldroyd-B model, the White-Metzner model, the Phan-Thien-Tanner model and the Giesekus-Leonov model. It was found that although the Phan-Thien-Tanner model gave the best results, the solution at higher shear rates were still not satisfactory.