全文获取类型
收费全文 | 707篇 |
免费 | 26篇 |
国内免费 | 2篇 |
专业分类
电工技术 | 5篇 |
综合类 | 1篇 |
化学工业 | 176篇 |
金属工艺 | 23篇 |
机械仪表 | 18篇 |
建筑科学 | 24篇 |
能源动力 | 50篇 |
轻工业 | 57篇 |
水利工程 | 12篇 |
石油天然气 | 7篇 |
无线电 | 83篇 |
一般工业技术 | 158篇 |
冶金工业 | 62篇 |
原子能技术 | 12篇 |
自动化技术 | 47篇 |
出版年
2024年 | 6篇 |
2023年 | 11篇 |
2022年 | 20篇 |
2021年 | 26篇 |
2020年 | 25篇 |
2019年 | 12篇 |
2018年 | 26篇 |
2017年 | 19篇 |
2016年 | 33篇 |
2015年 | 20篇 |
2014年 | 30篇 |
2013年 | 41篇 |
2012年 | 46篇 |
2011年 | 50篇 |
2010年 | 41篇 |
2009年 | 23篇 |
2008年 | 40篇 |
2007年 | 31篇 |
2006年 | 23篇 |
2005年 | 11篇 |
2004年 | 14篇 |
2003年 | 13篇 |
2002年 | 14篇 |
2001年 | 13篇 |
2000年 | 9篇 |
1999年 | 7篇 |
1998年 | 15篇 |
1997年 | 7篇 |
1996年 | 16篇 |
1995年 | 9篇 |
1994年 | 5篇 |
1993年 | 10篇 |
1992年 | 6篇 |
1991年 | 7篇 |
1989年 | 7篇 |
1988年 | 5篇 |
1987年 | 3篇 |
1986年 | 4篇 |
1985年 | 4篇 |
1984年 | 5篇 |
1983年 | 6篇 |
1982年 | 5篇 |
1981年 | 2篇 |
1978年 | 3篇 |
1977年 | 1篇 |
1976年 | 4篇 |
1975年 | 2篇 |
1972年 | 1篇 |
1966年 | 1篇 |
1965年 | 1篇 |
排序方式: 共有735条查询结果,搜索用时 15 毫秒
31.
Differential scanning calorimetric studies on structured lipids from coconut oil triglycerides containing stearic acid 总被引:1,自引:0,他引:1
Reena Rao Kadimi Udaya Sankar Kari Sambaiah B. R. Lokesh 《European Food Research and Technology》2001,212(3):334-343
Triglycerides from coconut oil contain high levels of lauric acid. They were replaced by incremental amounts of stearic acid by interesterification reactions catalyzed by immobilized lipase (IM 60 from Rhizomucor miehei). The reactions were carried out in organic solvents such as hexane. Maximum incorporation of stearic acid was observed by 4 h at 37vv°C or by 2 h at 60vv°C when triglycerides to fatty acid (stearic acid) ratio was maintained at 1v:Ң. The stearic acid level in coconut oil triglycerides was increased from an initial value of 2% to 60% under these conditions. The stearic acid replaced lauric, myristic, and palmitic acids in unmodified triglycerides. A major portion of stearic acid incorporated was found in positions 1 and 3 of triglycerides. Differential scanning calorimetry indicated that stearic acid enrichment increased the solid fat content and also the higher melting polymorphs in modified lipids. The studies also indicated that low melting polymorphic forms of coconut oil triglycerides are converted to higher melting forms by stearic acid enrichment. The modified lipids thus obtained can find use in various food applications. 相似文献
32.
The efficacy of individual ω-t-3 polyunsaturated fatty acids (PUFA) in altering eicosanoid synthesis in peritoneal macrophages
was studied by feeding mice for 10 days a diet containing 2 wt% fat, which included 0.5 wt% ethyl esters of eicosapentaenoic
acid (EPA), docosahexaenoic acid (DHA) or linolenic acid (LNA). Upon stimulation with calcium ionophore A23187, macrophages
from these animals produced significantly lower amounts of leukotriene C4, leukotriene B4 and 12-hydroxyeicosatetraenoic acid, prostaglandin E2 and 6-keto prostaglandin F1α compared with those obtained from animals on the diets containing olive oil or safflower oil. The decrease in leukotriene
synthesis was similar in the animals fed DHA, EPA or LNA diets. This depression of eicosanoids by DHA and EPA was associated
with decreased levels of arachidonic acid (AA); however, LA that altered eicosanoids did not have the same effect on AA levels. 相似文献
33.
Electrochemical oxidation of Inosine has been studied in the phosphate buffers of pH range 3.3-10.9 at pyrolytic graphite electrode. In the entire pH range a single well-defined oxidation peak (Ia) was observed, when the sweep was initiated in the positive direction. In the reverse sweep no cathodic peak was obtained. The peak potential of the oxidation peak was dependent on pH and shifted to less positive potential with increase in pH. The kinetics of the UV absorbing intermediate was followed spectrophotometrically and the decay occurred in a pseudo first order reaction having k values in the range 0.50-0.92 × 10−3 s−1 in the entire pH range studied. The value of n was found to be 2.95 ± 0.3. The products of oxidation were silylated and characterized by using GC-Mass. Two tetramers having CC, CN, NN, CON and COOC linkages were identified. A plausible mechanism for the electrooxidation of Inosine has been suggested. 相似文献
34.
Sathi Rajachandran Nair Ram Dayal Purohit Avesh Kumar Tyagi Pankaj Kumar Sinha Beant Prakash Sharma 《Journal of the American Ceramic Society》2008,91(1):88-91
Ultrafine La(Ca)CrO3 (LCC) powder was prepared through the glycine–nitrate gel combustion process. It was shown for the first time that the use of relatively inexpensive CrO3 as a starting material for chromium has potential for the bulk preparation of sinter-active LCC powder. As-prepared powder, when calcined at 700°C, resulted in LCC along with a small amount of CaCrO4 . The calcined powder was found to be composed of soft agglomerates with a particle size of ≈70–290 nm. The cold pressing and sintering of the calcined powder at 1200°C resulted in the mono-phasic La0.7 Ca0.3 CrO3 with density ≈98% of its theoretical value. This is the lowest sintering temperature ever reported for La0.7 Ca0.3 CrO3 . The conductivity of the sintered La0.7 Ca0.3 CrO3 at 1000°C was found to be ≈57 S/cm in air. The sintering and electrical behavior achieved for La0.7 Ca0.3 CrO3 may find application as an interconnect material for high-temperature solid oxide fuel cells if problems with chemical expansion and poor conductivity in fuel can be overcome. 相似文献
35.
36.
37.
Nowadays, energy is key consideration in discussions of sustainable development. So, sustainable development requires a sustainable supply of clean and affordable renewable energy sources that do not cause negative societal impacts. Energy sources such as solar radiation, the winds, waves and tides are generally considered renewable and, therefore, sustainable over the relatively long term. Wastes and biomass fuels are usually viewed as sustainable energy sources. Wastes are convertible to useful energy forms like hydrogen (biohydrogen), biogas, bioalcohol, etc., through waste-to-energy technologies.In this article, possible future energy utilization patterns and related environmental impacts, potential solutions to current environmental problems and renewable energy technologies and their relation to sustainable development are discussed with great emphasis on waste-to-energy routes (WTERs). 相似文献
38.
Gayatri Chauhan Ritu Srivastava Priyanka Tyagi Amit Kumar P.C. Srivastava M.N. Kamalasanan 《Synthetic Metals》2010,160(13-14):1422-1426
The frequency dependent ac conduction mechanism in 4,4′,4″-tris(N-3-methylphenyl-N-phenylamine)triphenylamine (m-MTDATA) has been studied as a function of applied bias and temperature. The Cole–Cole plot shows a slightly depressed semicircle indicating Debye type relaxation. This result has been explained by an equivalent circuit of the device designed as a two parallel resistor and capacitance network in series with contact resistance. The ac conduction studies under dc bias for hole only devices shows an increase in device conductivity with the increase in bias. The variation of bulk resistance with applied bias indicates Space Charge Limited Conduction (SCLC) mechanism for hole conduction. The hole mobility of the material has also been evaluated from SCLC as 8.859 × 10?6 cm2/V s. The temperature dependent impedance studies show two activation energies indicating two different phase of the material with a phase transition at 235 K. 相似文献
39.
Shekhar Tyagi V. G. Sathe Gaurav Sharma Velaga Srihari Himanshu Kumar Poswal 《Journal of Materials Science》2018,53(10):7224-7232
In the earlier pressure-dependent Raman spectroscopic studies, it has been reported that BaTiO3 undergoes a tetragonal to cubic phase transition above ~ 2 GPa, whereas pressure-dependent X-ray absorption, X-ray diffuse scattering studies and pair distribution function studies have reported the presence of a low-symmetry rhombohedral phase above ~ 2.3 GPa. In this report, we present our pressure-dependent Raman spectroscopic studies on polycrystalline BaTiO3 which shows that it first undergoes a transition from tetragonal to orthorhombic/rhombohedral phase above ~ 2.6 GPa and then finally goes to the cubic phase above 8.4 GPa. Pressure-dependent synchrotron X-ray diffraction (SXRD) studies have also been carried out that provided rate of change of volume as a function of pressure resulting in bulk modulus of 215 ± 9 GPa. 相似文献
40.
Geometric optimization of trapezoidal thermoelectric heat pump considering contact resistances through genetic algorithm 下载免费PDF全文
An alternate option for improving the performance of the thermoelectric heat pump (TEHP) is the variation in thermoelectric leg configuration. In this paper, the thermodynamic model based on first and second law of thermodynamics for an exoreversible TEHP including influence of Thomson effect as well as leg geometry on the coefficient of performance and heating load of the device has been developed and optimized. Modified expressions have been derived analytically for dimensionless heating load, irreversibilities, figure of merit, energy, and exergy efficiency. The effects of operating and geometry parameters such as shape parameter (Ac/Ah), temperature ratio (Tc/Th), Thomson effect, thermal and electrical contact resistances on the coefficient of performance, and heating load of the TEHP have been analysed. The results indicate that the Thomson effect has adverse effect on heating load of the system. The optimal parameters obtained through GA optimization process have been compared with the optimal parameters obtained through analytical method which proved the validity of GA optimization method for optimization of TEHP. After the testing, the GA optimization has been performed to determine the optimum parameters corresponding to maximum energy efficiency and maximum heating load. It was found that the GA population converges quickly after 20 runs only which proved the GA as time and cost‐effective optimization tool. This study will be useful for designing of practical TEHP systems of different leg geometries. 相似文献