Prevention of steel corrosion in concrete exposed to seawater with submerged sacrificial anodes

This paper presents the results of a study of the effectiveness of submerged sacrificial anodes in preventing the onset of pitting corrosion in the emerged part of marine piles. Experimental tests were carried out on reinforced concrete columns with steel embedded both in chloride free concrete and chloride contaminated concrete in order to compare the effects of sacrificial anodes on passive steel and on corroding steel. Results have shown, at least under the present testing conditions, that sacrificial anodes may be more effective in preventing corrosion initiation (i.e. in providing cathodic prevention) than in controlling ongoing pitting corrosion (i.e. in guaranteeing cathodic protection). Monitoring criteria for this type of prevention are also discussed.     

Neutronic characterization of the MEGAPIE target

The MEGAPIE project aimed to design, build and operate a liquid metal spallation neutron target of about 1 MW beam power in the SINQ facility at the Paul Scherrer Institut (Villigen, Switzerland). This project is an important step in the roadmap towards the demonstration of the accelerator driven system (ADS) concept and high power liquid metal targets in general. Following the design phase, an experimental program was defined to provide a complete characterization of the facility by performing a “mapping” of the neutron flux at different points, from the center of the target to the beam lines. The neutronic performance of the target was studied using different experimental techniques with the goals of validating the Monte Carlo codes used in the design of the target; additionally, the performance was compared with the solid lead targets used before and after the MEGAPIE experiment.     

Distribution of POPs,pesticides and antibiotic residues in organic honeys from different production areas

Demand for honey is increasing, especially if it is organic and if its nutritional properties are linked to untreated environments in order to guarantee quality for health. Sources of contamination of honey can be divided into environmental and apicultural. Therefore, the distribution of persistent organic pollutants, pesticides and antibiotic residues from geographical areas with different contamination sources (high anthropic impact, intensive farming, husbandry and low anthropic impact) was investigated in order to confirm the potential transfer of xenobiotics into the supply chain and to give beekeepers tools for the selection of areas dedicated to organic production. The presence of polychlorinated biphenyls, polybrominated diphenyl ether and polycyclic aromatic hydrocarbons was confirmed, not only in proximity to highly urbanised centres, where the concentrations were higher, but in all environment contexts, confirming their ubiquity. No antibiotics or neonicotinoids were detected in 95 organic honeys, demonstrating the absence of apicultural treatments and consequently the good quality of honey of different areas. These results are important due to the undefined regulatory European situation on honey antibiotic limits.     

Systematic Review on Tumor Microenvironment in Glial Neoplasm: From Understanding Pathogenesis to Future Therapeutic Perspectives

Despite the multidisciplinary management in the treatment of glioblastomas, the average survival of GBM patients is still 15 months. In recent years, molecular biomarkers have gained more and more importance both in the diagnosis and therapy of glial tumors. At the same time, it has become clear that non neoplastic cells, which constitute about 30% of glioma mass, dramatically influence tumor growth, spread, and recurrence. This is the main reason why, in recent years, scientific research has been focused on understanding the function and the composition of tumor microenvironment and its role in gliomagenesis and recurrence. The aim of this review is to summarize the most recent discovery about resident microglia, tumor-associated macrophages, lymphocytes, and the role of extracellular vesicles and their bijective interaction with glioma cells. Moreover, we reported the most recent updates about new therapeutic strategies targeting immune system receptors and soluble factors. Understanding how glioma cells interact with non-neoplastic cells in tumor microenvironment is an essential step to comprehend mechanisms at the base of disease progression and to find new therapeutic strategies for GBM patients. However, no significant results have yet been obtained in studies targeting single molecules/pathways; considering the complex microenvironment, it is likely that only by using multiple therapeutic agents acting on multiple molecular targets can significant results be achieved.     

Gate‐Controlled Energy Barrier at a Graphene/Molecular Semiconductor Junction

The formation of an energy‐barrier at a metal/molecular semiconductor junction is a universal phenomenon which limits the performance of many molecular semiconductor‐based electronic devices, from field‐effect transistors to light‐emitting diodes. In general, a specific metal/molecular semiconductor combination of materials leads to a fixed energy‐barrier. However, in this work, a graphene/C₆₀ vertical field‐effect transistor is presented in which control of the interfacial energy‐barrier is demonstrated, such that the junction switches from a highly rectifying diode at negative gate voltages to a highly conductive nonrectifying behavior at positive gate voltages and at room temperature. From the experimental data, an energy‐barrier modulation of up to 660 meV, a transconductance of up to five orders of magnitude, and a gate‐modulated photocurrent are extracted. The ability to tune the graphene/molecular semiconductor energy‐barrier provides a promising route toward novel, high performance molecular devices.     

The genesis and the hydrogeological features of the Turin Po Plain fontanili,typical lowland springs in Northern Italy

The fontanili are typical lowland springs that occur in Northern Italy along the transition zone from high to low plain (the “fontanili line”), due to changes in both the slope surface and the sediment grain size. These resurgences of phreatic water were investigated in the western sector of the Po Plain in the Turin Province. Although the available bibliographic data through 2005 reveal the occurrence of 111 fontanili in the study area, only 51 preserved fontanili have been identified in field surveys. The main morphological and geological features of these resurgences were recorded and entered into a database. In addition, the small-scale hydrogeologic framework of these fontanili was clarified by means of lithostratigraphic cross-sections. Taking into account the drastic decrease in the number of these particular springs, ten fontanili were selected for detailed investigation based on their state of preservation and accessibility. A geological map of each emergence was constructed to explain its origin. The main hydrochemical and physical variables and parameters were measured every month for a period of one year. Only three sources provided water throughout the entire year, and their flow rates reached 60–80 l/S during the summer due to recharge from irrigation channels. All other fontanili remained dry during different periods of the year. The hydrochemical data revealed a Ca–Mg bicarbonate composition. The electrical conductivity increased from the north (100–300 μS/cm) to the south (300–600 μS/cm), and nitrate concentrations were below the limits imposed by Italian law (50 mg/l). This study should be considered as the basis of a proposal to the local government for the protection of a subset of these springs as sites of special geological interest (geo-sites).     

H2S removal from biogas for fuelling MCFCs: New adsorbing materials

Cu and Zn modified 13X zeolites prepared by ion exchange or impregnation and activated carbons (ACs) treated with KOH, NaOH or Na₂CO₃ solutions were studied as H₂S sorbents for biogas purification for fuelling molten carbonate fuel cells. H₂S sorption was studied in a new experimental set-up equipped with a high sensitivity potentiometric system for the analysis of H₂S. Breakthrough curves were obtained at 40 °C with a fixed bed of 20 mg of the samples under a stream (6 L h⁻¹) of 8 ppm H₂S/He mixture. The adsorption properties of 13X zeolite improved with addition of Cu or Zn:Cu exchanged zeolite showed the best performances with a breakthrough time of 580 min at 0.5 ppm H₂S, that is 12 times longer than the parent zeolite. In general, unmodified and modified ACs were more effective H₂S sorbents than zeolites. Treating ACs with NaOH, KOH, or Na₂CO₃ solutions improved the H₂S adsorption properties: AC treated with Na₂CO₃ was the most effective sorbent, showing a breakthrough time of 1222 min at 0.5 ppm, that is twice the time of the parent AC.     

Modeling sleep mode gains in energy-aware networks

Nowadays two main approaches are being pursued to reduce energy consumption of networks: the use of sleep modes in which devices enter a low-power state during inactivity periods, and the adoption of energy proportional mechanisms where the device architecture is designed to make energy consumption proportional to the actual load. Common to all the proposals is the evaluation of energy saving performance by means of simulation or experimental evidence, which typically consider a limited set of benchmarking scenarios.     

Flexible joints control: A minimum-time feed-forward technique

The paper proposes a linear programming approach to the feed-forward minimum-time control of flexible joints. Taking into account both input and output constraints, the optimal bang–bang control is computed by discretizing a continuous-time joint model and by solving a sequence of linear programming feasibility problems. The resulting joint motion is a smooth rest-to-rest motion without oscillations. Theoretical analysis is presented and proof of convergence is given. Experimental results illustrate the proposed open-loop technique. Comparisons are made with inversion-based techniques.     

Performance and robustness of block constraint preconditioners in finite element coupled consolidation problems

Block constraint preconditioners are a most recent development for the iterative solution to large‐scale, often ill‐conditioned, coupled consolidation problems. A major limitation to their practical use, however, is the somewhat difficult selection of a number of user‐defined parameters (at least 4) in a more or less optimal way. The present paper investigates the robustness of three variants of the block constraint preconditioning in relation to the above parameters. A theoretical analysis of the eigenspectrum of the preconditioned matrix provides relatively simple bounds of the eigenvalues as a function of these parameters. A number of test problems used to validate the theoretical results show that both the mixed constraint preconditioner (MCP) combined with the symmetric quasi‐minimal residual (SQMR) solver and the MCP triangular variant (T‐MCP) combined with the bi‐conjugate gradient stabilized (Bi‐CGSTAB) are efficient and robust tools for the solution to difficult Finite Element‐discretized coupled consolidation problems. Moreover, the practical selection of the user‐defined parameters is relatively easy as a stable behavior is observed for a wide range of fill‐in degree values. The theoretical bounds on the eigenspectrum of the preconditioned matrix may help to suggest the most appropriate parameter combination. Copyright © 2009 John Wiley & Sons, Ltd.