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11.
Marta Fernndez-García Pedro Francisco Caamero Jos Luis de la Fuente 《Reactive and Functional Polymers》2008,68(9):1384-1391
Epoxy-functional spontaneous gradient copolymers of glycidyl methacrylate (G) and n-butyl acrylate (B) were synthesized via atom transfer radical polymerization (ATRP). The copolymerization reactions were carried out in toluene solution at 70 °C, using methyl 2-bromopropionate (MBrP) as initiator and copper chloride with N,N,N′,N′′,N′′-pentamethyldiethylenetriamine (PMDETA) as the catalyst system. The kinetic behaviour of the statistical copolymerizations was studied in a wide composition interval with molar fractions of G ranging from 0.10 to 0.75. The synthesized copolymers were characterized by size exclusion chromatography (SEC) and nuclear magnetic resonance (NMR) spectroscopy. 1H NMR was employed to determine the copolymer composition, demonstrating the gradient character of the copolymers along the main chain in the whole monomer conversion interval. Apart from this, the sequence distribution and stereoregularity were analyzed. These microstructural experimental data agreed well with those calculated from Mayo-Lewis terminal model (MLTM) and a Bernoullian statistic with an isotacticity parameter of σG = 0.28 and a coisotacticity parameter of σ = 0.30. 相似文献
12.
13.
Performance of Storage Tanks in Oil Facilities Damaged by Hurricanes Katrina and Rita 总被引:1,自引:0,他引:1
Luis A. Godoy 《Canadian Metallurgical Quarterly》2007,21(6):441-449
14.
Beatriz O. Hincapie Luis J. Garces Sinue Gomez Ruma Ghosh Steven L. Suib 《Catalysis Today》2005,110(3-4):323
Copper containing faujasite has been successfully prepared for the first time using a direct synthesis method. Faujasite type zeolite can be prepared in the presence of copper species by tuning the synthesis conditions. Ammonium hydroxide was used to form a copper complex that was later mixed with the reacting gel. Sodium is required to obtain copper faujasite. The complete elimination of sodium ions from the starting gel produces amorphous material. Crystallization took place at 358 K for 11 days. Crystallization temperature of 373 K produces ANA type zeolite as an impurity. Increasing by two times the amount of copper complex added to the reacting gel increases the crystallization time of Cu-FAU from 11 to 20 days (the crystallization rate decreases). The copper containing faujasite obtained was characterized by XRD, FESEM, EDX, EPR, FT-IR, TPR, and BET. According to the XRD pattern only FAU type zeolite was obtained. According to TPR experiments, the reduction temperature for Cu2+ ions present in Cu-FAU prepared by direct synthesis was 70 K more than for Cu-FAU prepared by ion-exchange. This difference can be due to the different location of the copper ions in the supercages or in the sodalite cages of the faujasite. 相似文献
15.
Steady-state and three-dimensional simulations were carried out to study the influences of geometrical parameters on the performance of PEMFC under different hydrating conditions. Flow fields, species transport, transport of water in polymer membrane and movement of liquid water in cathode and anode porous layers were determined, in order to accomplish a complete estimation of ohmic and concentration losses of PEMFC power. The geometrical parameters were thickness of the polymer membrane, cathode catalyst layer as well as gas channel to rib width ratio. Every simulation was made under different relative humidities of inlet flows (50 and 100%) for every change of characteristic length. Results show that the influence of the geometrical parameters on ohmic and concentration losses is of considerable importance. The performance of PEMFC is seriously affected under dehydrating conditions. However, such performance may be considerably improved by using suitable geometrical parameters. Cathode and anode liquid saturation may not only affect the transport of species, but also the polymer electrolyte water content. These results show the importance of simultaneously calculating both the water absorption and desorption through the polymer electrolyte and the liquid saturation in the cathode and anode porous mediums to obtain an actual view of ohmic and concentration losses of the PEMFC performance. 相似文献
16.
An evaluation of the Spanish CSIC performance in Biotechnology, as compared with those of the French CNRS and the Italian
CNR, has been carried out to determine the balance between the generation of scientific knowledge and the transfer of technology.
This study shows a high scientific productivity mostly in journals with moderate impact factor, a low generation of patents
and an insufficient transfer of knowledge to the Spanish companies. Other indicators confirm the existence of competitive
human resources in biotechnological research producing scientific knowledge of interest for the development of patents and
that cooperates successfully at European level. 相似文献
17.
For a model class of repellers of non-conformal expanding maps, we obtain sharp lower bounds for the dimension spectra of the Birkhoff averages of a Hölder continuous function. As in the well-studied case of conformal dynamics, the bounds are also expressed here in terms of the thermodynamic formalism. 相似文献
18.
In this work, we present a novel process to produce plasticized PVC articles. Plasticized PVC dispersion resin (dry blend) was extruded and poured into a hot mold. The mold was transferred to a rotomolding machine, where the final geometry was obtained. Formulations using commercial PVC suspension resin and three different types of plasticizers were prepared under different processing conditions. The physical appearance of the articles and the tensile properties of the materials were evaluated. 相似文献
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20.
Large diameter slender cylindrical shells used as buoyancy chambers and support legs for compliant marine structures experience a variety of impact loadings which could induce significant levels of dynamic response. By examining the response of a typical range of cylindrical shell geometries to a simulation of the impact loading typical of wave slamming, the paper examines the likely levels and practical significance of the transient dynamic response. It shows that the levels of dynamic response are sufficiently severe to have important implications for the triggering of buckling and fatigue collapse characteristics. It is suggested that this phenomenon requires additional more-detailed consideration, including the provision of reliable predictions of transient slam pressure distributions and the levels and forms of hydrodynamic damping, as well as the effects of more practical shell and stiffening geometries, and ambient stress levels. 相似文献