Organic Materials and Thin‐Film Structures for Cross‐Point Memory Cells Based on Trapping in Metallic Nanoparticles

Non‐volatile solid‐state memory cells based on composites of metal nanoparticles and polymers are embedded in organic semiconducting host materials. This paper presents data from a wide range of materials and device structures and shows that the switching phenomenon is commonly observed.     

CdTe/CdS thin film solar cells grown in substrate configuration

The ability to grow efficient CdTe/CdS solar cells in substrate configuration would not only allow for the use of non‐transparent and flexible substrates but also enable a better control of junction formation. Yet, the problems of barrier formation at the back contact as well as the formation of a p–n junction with reduced recombination losses have to be solved. In this work, CdTe/CdS solar cells in substrate configuration were developed, and the results on different combinations of back contact materials are presented. The Cu content in the electrical back contact was found to be a crucial parameter for the optimal CdCl₂‐treatment procedure. For Cu‐free cells, two activation treatments were applied, whereas Cu‐containing cells were only treated once after the CdTe deposition. A recrystallization behavior of the CdTe layer upon its activation similar to superstrate configuration was found; however, no CdTe–CdS intermixing could be observed when the layers were treated consecutively. Remarkably high V_OC and fill factor of 768 mV and 68.6%, respectively, were achieved using a combination of MoO₃, Te, and Cu as back contact buffer layer resulting in 11.3% conversion efficiency. With a Cu‐free MoO₃/Te buffer material, a V_OC of 733 mV, a fill factor of 62.3%, and an efficiency of 10.0% were obtained. Copyright © 2012 John Wiley & Sons, Ltd.     

Osteoconductive Performance of Carbon Nanotube Scaffolds Homogeneously Mineralized by Flow‐Through Electrodeposition

The treatment of bone lesions, including fractures, tumor resection and osteoporosis, is a common clinical practice where bone healing and repair are pursued. It is widely accepted that calcium phosphate‐based materials improve integration of biomaterials with surrounding bone tissue and further serve as a template for proper function of bone‐forming cells. Within this context, mineralization on preformed substrates appears as an interesting and successful alternative for mineral surface functionalization. However, mineralization of “true” 3D scaffolds –in which the magnitude of the third dimension is within the same scale as the other two– is by no means a trivial issue because of the difficulty to obtain a homogeneous mineral layer deposited on the entire internal surface of the scaffold. Herein, a “flow‐through” electrodeposition process is applied for mineralization of 3D scaffolds composed of multiwall carbon nanotubes and chitosan. It is demonstrated that, irrespective of the experimental conditions used for electrodeposition (e.g., time, temperature and voltages), the continuous feed of salts provided by the use of a flow‐through configuration is the main issue if one desires to coat the entire internal structure of 3D scaffolds with a homogeneous mineral layer. Finally, mineralized scaffolds not only showed a remarkable biocompatibility when tested with human osteoblast cells, but also enhanced osteoblast terminal differentiation (as early as 7 days in calcifying media).     

Network and single user performance evaluation of a mobile data system over flat fading transmission channels

In this paper the contrasting effects of transmission impairments and capture on both the network and single user performance of a slotted Aloha system are investigated in a mobile radio environment, accounting for frequency non-selective random propagation phenomena, and employing the packet error probability in order to define packet losses and capture. With this study we demonstrate that it is possible to generalize in a real propagation context a method previously proposed in literature for evaluating the network behavior in terms of steady-state throughput, backlog and stability in conventional transmission conditions, i.e., when all the transmission channels were error-free and the collisions caused the loss of all the packets involved. Moreover, we indicate under which specific constraints on the terminal mobility we can apply this method to analytically predict the single user performance, which we show being an important design parameter. Through the numerical results reported we quantitatively point out that in the absence of coding capture increases system stability and moderately improves the overall system throughput and backlog. We also outline the trade-off between an increased capture gain obtained by means of coding and the corresponding system cost in terms of complexity and bandwidth occupancy. Furthermore, we demonstrate the unfairness which affects the single user performance and the consequent need for countermeasures in order not to discriminate among users differently located within the network; yet, this last solution is detrimental as regards the positive capture effects.This work was supported by M.U.R.S.T. and C.N.R. (Italy).     

A SAED and HREM study of structural defects in brownmillerite,LaBa(x)Sr(1-x)CuGaOy related oxides

The synthesis and microstructural characterization, by means of selected area electron diffraction (SAED) and high resolution electron microscopy (HREM), of the solid solution LaBa(x)Sr(1-x)CuGaO5 (0.1 < or = 5 x < or = 0.9) is reported. Although an average brownmillerite Ima2 structure is proposed for the whole compositional range, SAED and HREM clearly show that structural defects appear as barium content increases.     

Design of Engineered Elastomeric Substrate for Stretchable Active Devices and Sensors

In the field of flexible electronics, emerging applications require biocompatible and unobtrusive devices, which can withstand different modes of mechanical deformation and achieve low complexity in the fabrication process. Here, the fabrication of a mesa‐shaped elastomeric substrate, supporting thin‐film transistors (TFTs) and logic circuits (inverters), is reported. High‐relief structures are designed to minimize the strain experienced by the electronics, which are fabricated directly on the pillars' surface. In this design configuration, devices based on amorphous indium‐gallium‐zinc‐oxide can withstand different modes of deformation. Bending, stretching, and twisting experiments up to 6 mm radius, 20% uniaxial strain, and 180° global twisting, respectively, are performed to show stable electrical performance of the TFTs. Similarly, a fully integrated digital inverter is tested while stretched up to 20% elongation. As a proof of the versatility of mesa‐shaped geometry, a biocompatible and stretchable sensor for temperature mapping is also realized. Using pectin, which is a temperature‐sensitive material present in plant cells, the response of the sensor shows current modulation from 13 to 28 °C and functionality up to 15% strain. These results demonstrate the performance of highly flexible electronics for a broad variety of applications, including smart skin and health monitoring.     

Contact effects in organic thin-film transistor sensors

Contact effects in organic thin-film transistors (OTFTs) sensors are here investigated specifically respect to the gate field-induced sensitivity enhancement of more than three orders of magnitude seen in a DHα6T OTFT sensor exposed to 1-butanol vapors. This study shows that such a sensitivity enhancement effect is largely ascribable to changes occurring to the transistor channel resistance. Effects, such as the changes in contact resistance, are seen to influence the low gate voltage regime where the sensitivity is much lower.     

An adaptive hybrid MOOC model: Disrupting the MOOC concept in higher education

In the 18th century, the educational model underwent a disruptive change driven by the transition from an agricultural to an industrial society. In the 21st century, the change from the industrial society to a knowledge society has been consolidated, but it has not involved a disruption in the learning context. Some elements, many based on technologies, can be considered disruptive, but they have not had sufficient effect to produce a change in the model that has predominated for 300 years. In 2008, teachers began to offer training outside the walls of the university, with a totally disruptive and chaotic model compared to the traditional one; this was supported by open, informal, cooperative, connectivist, autonomous and self-guided training. Massive open online courses (MOOCs) began with cMOOCs, and most universities join the initiative, but they abandoned this disruption, ultimately offering the same courses they always had with free access for anyone, resulting in the second generation of MOOCs (xMOOCs). These MOOCs responded to a new social demand, but their characteristics and context make a formative disruption – which has not yet emerged – necessary. This paper analyses the elements of the two generations of MOOCs in order to propose a new model that does not require sophisticated technological solutions and recovers the initial disruptive sense of MOOCs, so called ahMOOC. It also presents a case study that integrates the social advantages of cMOOCs, the organisational benefits of xMOOCs and the personalisation of the learning, which is essential due to the heterogeneity of the participants. The results and the participant viewpoints emerging from the case study confirm the feasibility of the model, the improvement of the results of current MOOCs and the need – demanded by the participants – to consider diversity, all of which should be accomplished in a disruptive way.     

Changes in the volatile composition of red wines during aging in oak barrels due to microoxygenation treatment applied before malolactic fermentation

Microoxygenation is a wine-making technique consisting in the addition of small and controlled amounts of oxygen. This study has examined the effect of this technique on the volatile composition of two red single variety wines during two successive vintages. The microoxygenation treatment was applied at the end of alcoholic fermentation and before beginning malolactic fermentation. Once the microoxygenation treatment had finished, wines were aged in new American oak barrels for 12 months. The results obtained showed that the microoxygenation treatment did not cause significant changes in the varietal and fermentation volatile compounds, however microoxygenation slowed down the extraction of some of the volatile compounds extracted from wood. A varietal and vintage effect was also observed for some of the compounds studied.