Hydrolytic stability and protective properties of polyurethane oligomers based on polyester/ether/polyols

The present study deals with effect of the type and chemical character of incorporated polyester/polyether blocks on the hydrolytic stability of crosslinked polyurethane oligomers. Diffusion parameters of the investigated polyurethane oligomers, giving information concerning chemical changes taking place in neutral, basic and acidic aqueous environments, have also been determined.     

N.m.r. study of the ferroelectric phase transition in a 7030mol% copolymer of vinylidene fluoride (VF2) and trifluoroethylene (TrFE)

Nuclear magnetic resonance (n.m.r.) studies of ¹⁹F nuclei in a $\text{70}\text{30}\text{mol}\text{\%}$ random copolymer of vinylidene fluoride and trifluoroethylene were performed at 9.14 MHz and 20.0 MHz. The free induction decays (FIDs) were analysed in terms of two T₂ components attributed to the amorphous and crystalline portions of the polymer. The changes in crystallinity as well as the effects of the ferroelectric transition were observed during cycles of heating and cooling between 20°C and 140°C. The crystalline component of the FID lengthens by a factor of 2 at 100°C on heating and decreases by this factor at 60°C on cooling, thus exhibiting the thermal hysteresis of this ferroelectric transition. The spin-lattice relaxation was also investigated. From measurements at 9.14 MHz the observed longitudinal relaxation time T₁ appears to be dominated by the dynamics of the amorphous phase and exhibits no anomaly through the phase transition. However, from measurements at 20 MHz, well defined minima of T₁ were observed, which are associated with the ferroelectric transition (especially after repeated annealing of the samples). Results are discussed in terms of the crystalline phase structure, which appears dynamically disordered above the ferroelectric phase transition. An analogy is considered with the plastic phase transitions encountered in molecular crystals.     

Traffic officers'' attitudes toward blood alcohol law enforcement

Research findings in other countries suggest that drinking driving laws could be much better enforced even without resorting to special patrols or random checks. It has been reported that law enforcement officers apprehend or breath test only a small fraction of the potentially impaired drivers that they normally encounter on patrol. This survey of New Zealand traffic officers was designed to determine the extent to which this was the case here, and what were the major disincentives to breath testing. Traffic officer responses, obtained on an anonymous questionnaire, suggested that there were not so many missed opportunities as had been suggested by others, but that there was a great deal of variability in the number of drinking drivers detected by different officers. This was confirmed by the actual distribution of breath testing activity, which was markedly different in shape (positively skewed) compared to the distribution of traffic enforcement activities in general. Several clues from the disincentives cited on the questionaire suggested that there are major deterrents to a greater degree of alcohol enforcement activity on the part of most officers. These are discussed in terms of potential legislative changes, and in relation to the changes introduced in the 1978 Transport Act Amendment.     

Cyclic variations in the permeability of the cell wall of Saccharomyces cerevisiae.

To study cell-cycle-related variations in wall permeability of Saccharomyces cerevisiae, two approaches were used. First, an asynchronous culture was fractionated by centrifugal elutriation into subpopulations containing cells of increasing size. The subpopulations represented different stages of the cell cycle as judged by light microscopy. Cell wall porosity increased when these subpopulations became enriched with budded cells. Secondly, synchronous cultures were obtained by releasing MATa cells from alpha-factor induced G1-arrest. These cultures grew synchronously for at least two generations. The cell wall porosity increased sharply in these cultures, shortly before buds became visible and was maximal during the initial stages of bud growth. It decreased in cells which had completed nuclear migration and before abscission of the bud had occurred. The porosity reached its lowest value during abscission and in unbudded cells. We examined the incorporation of mannoproteins into the wall during the cell cycle. SDS-extractable mannoproteins were incorporated continuously. However, the incorporation of glucanase-extractable mannoproteins, which are known to affect cell wall porosity, showed cyclic oscillations and reached its maximum after nuclear migration. This coincided with a rapid decrease in cell wall porosity, indicating that glucanase-extractable mannoproteins might contribute to this decrease.     

Vinyl acetate monomer—a pilot plant study

The kinetics of the reaction of acetic acid and acetylene over zinc acetate-activated carbon catalyst was investigated over a wide range of process variables in a pilot reactor. Although various catalytic reaction mechanisms were postulated, the rate of reaction was most satisfactorily correlated by a mechanism of surface reaction between charged adsorbed acetic acid and acetylene, which assumes that the rate controlling step was the irreversible charged adsorption of acetylene and acetic acid.     

Consistent structure determination of a noisy measurement system model

This paper describes a fast and accurate method for defining the structure of a noisy measurement system model without a previous parameters evaluation. The procedure is based on the following steps: (i) choosing a stable system structure; (ii) determing the real model order; (iii) estimating the model parameters. In (i) a value of the model order greater than the supposed one is assumed; in (ii), in order to determine the real structure, samples of the input/output signals of the actual model and the over-parametrised one are used; in (iii), by means of unbiased identification techniques, the model parameters are evaluated. The proposed method can be used both in batch and real-time processing. Experimental results concerning a single input-single output linear process with different model order and noise statistical properties are given.     

Testing the Ortega hypothesis: Facts and artifacts

We examine the assumptions and data base used by researchers who have tested the Ortega hypothesis. We find that the assumptions are not supported by the data and that the data are faulty. We conclude that the results are artifactual. We recommend that any policy implemented on the basis of this research be suspended.