Some applications of ultraviolet spectrophotometry in drying oil research

Conclusions An alkaline-solution technique has been developed permitting the study of the drying and aging process of an oil film using the ultraviolet spectrophotometer. This technique has been found to be a valuable tool for investigating some of the chemical changes which occur as a vegetable oil film dries and ages. The drying or autoxidation of an oil film has been shown to proceed along the general lines of a three-stage reaction with the short initial stage being characterized by an accumulation of conjugated diene and triene structures which reaches a maximum at the time the film has set up or becomes continuous. The second or curing stage was characterized by a slow decrease in the measurable conjugated diene and triene structures. The third or deterioration stage was not investigated; however, this method should be readily adaptable to studies involving film breakdown as represented by phenomena such as after-yellowing since the development of absorption peaks characteristic of linolenic ketones, for example, would permit an early prediction of yellowing long before the concentration of the chromophore groups became great enough for visual observation. During the initial stage of drying there was also evidence for an increase in the alpha-keto structures capable of enolizing in alkali to give absorption maxima characteristic of triene and tetraene conjugated systems. These enolizable structures also decreased in amount during the film curing period and are not characterizable on the basis of observed absorption maxima and published information. The method of obtaining a spectral solution of a dry, infusible oil film through the medium of alcoholic KOH was applied to investigations on the relationship existing between the light absorption of the film solution and the durability or weather resistance of the straight oil film. The results obtained verified the principle previously reported that the quantity of light absorbed by an oil film in the region of 320–400 mμ was indicative of the durability of the film upon exposure to accelerated weathering conditions.     

Application of the line-width method to the spectrochemical analysis of oils,fats, and related substances

Summary The application of the line-width method to the spectrochemical analysis of oils and fats in conjunction with the use of an improved ashing technique has been shown to permit the quantitative determination of copper, iron, manganese, nickel, and tin in quantities as low as 1 part in 10 million. The procedure has been critically examined by precision tests on commercial and experimental samples, by accuracy tests on synthetic samples, and by recovery tests. Results of actual analysis of 30 vegetable oils and fats indicate the use of the procedure as a research tool. The procedure may be used for the trace element analysis of organic material low in ash content. One of the laboratories of the Bureau of Agricultural and Industrial Chemistry, Agricultural Research Administration, U. S. Department of Agriculture.     

The hydrolysis of soap solutions. IV. The composition of acid potassium laurates and acid sodium oleates as determined by conductivity measurements

The effect of excess lauric and oleic acids on the conductivity and on the pH of 0.2–0.02N potassium laurate and 0.1–0.01N sodium oleate systems was observed. The decrease in the specific conductivity corresponded with the formation of the acid soaps, 2KL·HL, KL·HL, 2NaOl·HOl, NaOl·HOl, and the mixed soaps 2KL·HOl and 2NaOl·HL. The mixed soaps resemble the oleates in appearance. All of these systems, even with 100 or 150 moles per cent excess acid, were slightly alkaline.     

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