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101.
Thermal,mechanical, and corrosion resistance properties of vinyl ester/clay nanocomposites for the matrix of carbon fiber‐reinforced composites exposed to electron beam
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Seyed Mohammad Razavi Negar Dehghanpour Seyed Javad Ahmadi Mahdi Rajabi Hamaneh 《应用聚合物科学杂志》2015,132(33)
Vinyl ester/clay nanocomposites with 1, 3, and 5% nanoclay contents were prepared. X‐ray diffractography patterns and Scanning Electron micrographs showed that nanocomposites with the exfoliated structure were formed. Thermogravimetric analysis, water absorption test, and Tafel polarization method, respectively, revealed the improvements in thermal resistance, water barrier properties, and corrosion resistance properties of the samples with an increase in the amount of the incorporated nanoclay. Tensile tests showed that nanoclay also enhanced the mechanical properties of the polymer, so that the tensile strength of the samples with 5% nanoclay was more than 3 times higher than tensile strength of pure vinyl ester samples. Overall, the best properties were observed for the samples containing 5% nanoclay. Pure vinyl ester and nanocomposite with 5% nanoclay content were exposed to the electron beam radiation and their mechanical properties improved up to 500 kGy irradiation dose. Finally, pure vinyl ester and vinyl ester/nanoclay (5%) matrixes were reinforced with carbon fiber and the effect of electron beam irradiation on their mechanical properties was examined. The tensile strength and the modulus of the samples initially increased after exposure to the radiation doses up to 500 kGy and then a decrease was observed as the irradiation dose rose to 1000 kGy. Moreover, nanoclay moderated the effect of the irradiation. © 2015 Wiley Periodicals, Inc. J. Appl. Polym. Sci. 2015 , 132, 42393. 相似文献
102.
Thermal,mechanical, and barrier properties of polyethylene/surlyn/organoclay nanocomposites blown films prepared by different mixing methods
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Homayoon Hosseinkhanli Jamal Aalaie Mahdi Abdollahi Talat Khalkhali Mehrdad Shojaei 《乙烯基与添加剂工艺杂志》2015,21(1):60-69
(Low‐density polyethylene) (LDPE)/clay nanocomposites were prepared by melt blending in a twin‐screw extruder by using different mixing methods. Zinc‐neutralized carboxylate ionomer was used as a compatibilizer. Blown films of the nanocomposites were then prepared. The effect of mixing method on the clay dispersion and properties of the nanocomposites was evaluated by wide‐angle X‐ray diffraction analysis, mechanical properties, thermal properties, and barrier properties. The structure and properties of nanocomposites containing different amounts of nanoclay prepared by selected mixing techniques were also investigated. It was found that melt compounding of Surlyn/clay masterbatch with pure LDPE and Surlyn (two‐step‐a method) results in better dispersion and intercalation of the nanofillers than melt mixing of LDPE/Surlyn/clay masterbatch with pure LDPE and surlyn (two‐step‐b method) and direct mixing of LDPE with clay. The films containing ionomer have good barrier properties. A wide‐angle X‐ray diffraction pattern indicates that intercalation of polymer chains into the clay galleries decreases by increasing the clay content. Barrier properties and tensile modulus of the films were improved by increasing the clay content. In addition, tensile strength increased in the machine direction, but it decreased in the transverse direction by increasing the clay content. DSC results showed that increasing the clay content does not show significant change in the melting and crystallization temperatures. The results of thermogravimetric analysis showed that the thermal stability of the nanocomposites decreased by increasing the clay content more than 1 wt%. J. VINYL ADDIT. TECHNOL., 21:60–69, 2015. © 2014 Society of Plastics Engineers 相似文献
103.
Microencapsulation is a rapidly expanding technology which is a unique way to package materials in the form of micro- and nano-particles, and has been well developed and accepted within the pharmaceutical, chemical, food and many other industries. Spray drying is the most commonly used encapsulation technique for food products. A successful spray drying encapsulation relies on achieving high retention of the core materials especially volatiles and minimum amounts of the surface oil on the powder particles for both volatiles and non-volatiles during the process and storage. The properties of wall and core materials and the prepared emulsion along with the drying process conditions will influence the efficiency and retention of core compounds. This review highlights the new developments in spray drying microencapsulation of food oils and flavours with an emphasis on the encapsulation efficiency during the process and different factors which can affect the efficiency of spray drying encapsulation. 相似文献
104.
Mahsa S. Asgari Manouchehr Nikazar Payam Molla-abbasi Mohammad Mahdi Hasani-Sadrabadi 《International Journal of Hydrogen Energy》2013
Here we show preparation and characterization of a new type of composite membrane based on Nafion®/histidine modified carbon nanotube by imidazole groups (Im-CNT), for direct methanol fuel cell (DMFC) applications. Due to the presence of this imidazole-based amino acid on the surface of CNT, new electrostatic interactions can be formed in the interface of Nafion® and Im-CNT. Physical characteristics of these nanocomposite membranes are investigated by water uptake, methanol permeability, ion exchange capacity, proton conductivity, as well as fuel cell performance results. 相似文献
105.
Ali IZADI GHAHFEROKHI Masoud KASIRI-ASGARANI Kamran AMINI Mahdi RAFIEI Reza EBRAHIMI-KAHRIZSANGI 《中国有色金属学会会刊》2022,32(3):908-926
研究使用不同的中间层瞬时液相连接两种异种高温合金的适用性.在1100℃、不同时间下瞬时液相连接GTD-111/IN-718体系,研究BNi-2、BNi-3和BNi-9三种类型的中间层对该体系显微组织和力学性能的影响.采用场发射扫描电子显微镜和能量色散光谱技术,研究接头区域的成分变化和显微组织.结果表明,非热凝固区Ni3... 相似文献
106.
Masoud Hasany Soheila Yaghmaei Mohammad Mahdi Mardanpour Zahra Ghasemi Naraghi 《中国化学工程学报》2017,25(12):1847-1855
A successful design, previously adapted for treatment of complex wastewaters in a microbial fuel cell (MFC), was used to fabricate two MFCs, with a few changes for cost reduction and ease of construction. Performance and electrochemical characteristics of MFCs were evaluated in different environmental conditions (in complete darkness and presence of light), and different flow patterns of batch and continuous in four hydraulic retention times from 8 to 30 h. Changes in chemical oxygen demand, and nitrate and phosphate concentrations were evaluated. In contrast to the microbial fuel cell operated in darkness (D-MFC) with a stable open circuit voltage of 700 mV, presence of light led to growth of other species, and consecutively low and unsteady open circuit voltage. Although the performance of theMFC subjected to light (L-MFC)was quite lowand unsteady in dynamic state (internal resistance = 100 Ω, power density = 5.15 W·m-3), it reached power density of 9.2 W·m-3 which was close to performance of D-MFC (internal resistance = 50 Ω, power density = 10.3 W·m-3). Evaluated only for D-MFC, the coulombic efficiency observed in batch mode (30%) was quite higher than the maximum acquired in continuous mode (9.6%) even at the highest hydraulic retention time. In this study, changes in phosphate and different types of nitrogen existing in dairy wastewater were investigated for the first time. At hydraulic retention time of 8 h, the orthophosphate concentration in effluent was 84% higher compared to influent. Total nitrogen and total Kjeldahl nitrogen were reduced 70% and 99% respectively at hydraulic retention time of 30 h, while nitrate and nitrite concentrations increased. The microbial electrolysis cell (MEC), revamped from D-MFC, showed the maximum gas production of 0.2 m3 H2·m-3·d-1 at 700 mV applied voltage. 相似文献
107.
Ali Akbar Ramezanianpour Amirreza Pilvar Mahdi Mahdikhani Faramarz Moodi 《Construction and Building Materials》2011,25(5):2472-2479
There are several factors and test methods for evaluating the durability of concrete. In recent years a great deal of attention has been paid to research and development of relationships of these parameters for production of sustainable concretes: water penetration and Rapid Chloride Penetration Test (RCPT) methods which are most commonly used to evaluate the permeability of concrete are two of the most famous methods specified by BS EN-12390-8:2000 and ASTM C1202 respectively. Concrete surface resistivity (SR) test is also a suitable indicator for concrete penetration and chloride ion permeability. It is a non-destructive, simple, rapid and economical method that can also be used on site.The present study is an exploratory research concerned with the relationship of these methods. Based on the correlation of concrete resistivity with water penetration and Rapid Chloride Penetration Test (RCPT) results, two new models for relating these parameters are presented. 相似文献
108.
Simulation of multiphase mass transport in large field-scale heterogeneous, naturally fractured reservoirs with common grid-based methods is very time consuming and costly. An in-house streamline-based simulator is extended to simulate two-phase flow of oil and water in 3D heterogeneous, naturally fractured reservoirs. Different waterflooding problems have been simulated in 2D and 3D fractured reservoirs, and their results are compared with those of the grid-based commercial software. It has been shown that the streamline-based simulator can predict the results of the grid-based software with an acceptable accuracy, while its computational time and required memory is exceptionally less than the grid-based method. 相似文献
109.
Mahdi N. Mahyari Hasan Karimi Hasan Naseh Mehran Mirshams 《Journal of Mechanical Science and Technology》2010,24(10):1997-2006
The focus of the present study is to investigate the effectiveness of installing vortex breakers at the outlet of launch vehicle
tanks on postponing vortex formation and decreasing the critical height of propellants while discharging. Analytical results
in the absence of a vortex breaker show that the effects of the Weber and Reynolds numbers in the flow field can be ignored
for values greater than 720 and 1.1 × 105, respectively; and critical height can be considered as a function of Froude number under aforementioned conditions. The
analytical criteria are verified by two-dimensional, axis symmetrical, transient and two-phase numerical model. Eventually,
some experiments are conducted to examine the effectiveness of the applied vortex breakers in reduction of the critical height
of propellant. Experimental results show that a 30% decrease can be achieved in critical height by using a particular type
of vortex breaker. Additionally, the carried out simulations for an existing two-stage launch vehicle indicate a 13% increase
in orbital altitude, which in turn proves the considerable improvement in launch vehicle mass/energetic capabilities. 相似文献
110.
The effects of hydrocolloids in rice–wheat flour were studied. Hydrocolloids at 0%, 0.3%, 0.6% and 1% w/w (flour basis) and guar (G), Lepidium sativum seed (L) and guar-L. sativum seed (GL) gum were tested as additives to the rice/flour in various combinations. The quality parameters for the experiment were assessed with farinography, extensography, amylography and texture profile analysis. The evaluation of dough rheology showed that water absorption, dough development time, dough stability and viscosity all increased with the addition of hydrocolloids alone or in a combination. It was demonstrated that G1L1 promoted the highest effect. The mixing tolerance index and gelatinization temperature decreased with an increased hydrocolloid concentration. Extensibility value for the dough that incorporated guar and L. sativum seed gum increased with increasing hydrocolloid concentration from 0.3% to 0.6% and then decreased at 1%. The water activity of all bread didn't have significant differences with increasing hydrocolloids concentration but this parameter 24 decreased during storage. Firmness decreased with increasing hydrocolloid concentration and increased with increasing storage time. The sensory evaluation by a consumer panel gave the higher score for overall acceptability to G0.3L0.3 and G0.3L0.6 samples. The results also showed that G1L1, G1L0.6 and G0.6L1 samples had high specific volume and porosity. 相似文献