Hydrochloric acid leaching of nickel sulfide precipitates

Nickel sulfide precipitates produced by the AMAX Acid Leach Process for oxide nickel ores were leached in hydrochloric acid. The effects of process variables such as temperature, acid concentration, stoichiometric excess of HCl, gas sparging and heat treatment of feed were investigated. The nickel leachability was found to be in the 60–80% range. Chemical and mineralogical examination of the leach residues indicated the presence of NiS₂. This higher nickel sulfide is insoluble in hydrochloric acid, and its presence hinders the leaching of NiS. Several methods are suggested to reduce the sulfur content in order to attain complete dissolution. The thermodynamics and kinetics of nickel sulfide leaching are briefly discussed.     

Towards a generic distributed and collaborative digital manufacturing

A framework for distributed manufacturing is proposed to facilitate collaborative product development and production among geographically distributed functional agents using digitalized information. Considering the complexity of products created in a distributed manufacturing scenario, it often requires close collaborations among a number of facilities. In this research work, various functional agents, such as the manufacturability evaluation agent (MEA), manufacturing resource agent (MRA), process-planning agent (PPA), manufacturing scheduling agent (MSA), shop floor agent (SFA), fault diagnosis agent (FDA), etc., can interact coherently for distributed manufacturing. With specific agents having unique functionalities, a manufacturing managing agent (MMA) acts as the centre of this distributed manufacturing system. The MMA agent assists the specific agents’ to work seamlessly and also to collaborate closely with the participating agents. In this way, the production cycle of a part can be optimized from product design to final manufacturing since all the production procedures are considered logically and every procedure is correlated. The agent language based on the knowledge query manipulation language (KQML) includes many pre-defined performatives that ease the participating agents to carry out their tasks intelligently by interpreting commands from one another. Additionally, to ensure the adaptiveness and upgradeability of the system, the internal structure of each functional agent that is based on JATLite is modularized into several components, including a communication interface, central work engine, knowledge base pool, and input/output modifier for possible future methodology enhancements.     

Resolving the Micropayment Problem

Cryptography-based alternatives are the most appropriate long-term solution to the micropayment problem, especially compared to the business solution of restructuring transaction fees. We acknowledge that the business solution is easier to deploy in the short term. Cryptography-based solutions face tremendous deployment challenges: they need more market testing, they significantly change payment-ecosystem processes, their legal implications are unclear, and they require new kinds of devices and processes for merchants. Nonetheless, the long-term payoff of investing in such sound solutions are be tremendous     

A Novel Electroless Process for Embedding a Thin Film Resistor on the Benzocyclobutene Dielectric

To realize embedded resistors on multilayer benzocyclobutene (BCB) either on-chip or on-board, a low-cost large format electroless process for deposition of NiP and NiWP thin-film resistors using both low-temperature (25°C) and high-temperature (90°C) baths has been developed. The electroless process exhibits uniform resistor thickness in the submicron range and offers low profile and excellent adhesion to the BCB dielectric layer. The resistor films also act as a seed layer for direct electroplating of copper traces. The NiP alloys can also be tailored to a variable temperature coefficient of resistance (TCR) with different alloy compositions. The electroless process can be adopted in the PCB manufacturing industries with no additional investment. This article is the first report on electroless plated thin film resistors on low loss BCB dielectric.     

Integrating ABM/TOC approaches for performance improvement: A framework and application

During the last 20 years, new philosophies such as the Theory of Constraints (TOC) and Activity-Based Management (ABM) have emerged as viable, distinct alternatives for measuring and improving the performance of world-class manufacturing companies. In the early phase of their evolution, these philosophies differed fundamentally in their approaches; but there is increasing evidence that both philosophies have now evolved to a stage where an integrated framework can be developed for enhancing cross-functional coordination, thereby improving organizational performance. In this paper, a general framework is presented that integrates the basic concepts, as well as recent advances of TOC and ABM philosophies, into a cohesive framework that can be used to guide performance improvement initiatives . A successful implementation in a world-class manufacturing company is described to validate the framework and to demonstrate that these philosophies can indeed work together in positive ways. Insights are provided into the reasons for implementing such an integrative framework, e.g. identifying the most profitable mix of products, allocating scarce resources optimally, establishing priorities for process improvements, analysing the strategic investment (or expansion) alternatives, and exploiting new market segments.     

Optimization of cellulases production by Trichoderma citrinoviride on marc of Artemisia annua and its application for bioconversion process

The production of cellulases by Trichoderma citrinoviride fermented on marc of Artemisia annua, and bioconversion of the same marc by produced cellulase system was studied. The effects of pretreatments, substrate concentration, particle size, initial pH, temperature and concentration of the medium components on production of FPase, endoglucanase and β-glucosidase were monitored and comparatively evaluated. Among the three pretreatment processes, alkali hydrolysis with autoclaving was found to be most suitable for production of all the three enzymes. Optimum production of FPase, endoglucanase and β-glucosidase was obtained at 96 h, 96 h and 72 h of fermentation period, respectively. Substrate concentration of 1% with particle size between 200 μm and 475 μm gave the higher yields. Higher production of all the three enzymes was obtained with initial pH value of 5.5, temperature of 28 °C and 75% of mineral salt solution. Partially purified enzyme system obtained by optimized fermentation procedure, was applied for saccharification. Forty six percent of saccharification was noticed after 48 h of incubation on alkali hydrolyzed and autoclaved substrate which was 3.26 fold more than that of unpretreated substrate.     

Catalytic activity of polymer-bound Ru(III)-EDTA complex

Chloromethylated styrene-divinylbenzene copolymer was chemically modified with ethylenediaminetetraacetic acid ligand. Catalytically active polymer containing Ru(III) moieties were synthesized from this polymeric ligand. They were characterized using FTIR, UV-vis, SEM, ESR and TGA. Other physico-chemical properties such as bulk density, surface area, moisture content and swelling behaviour in different solvents were also studied. The polymer bound complex was used to study hydrogenation of 1-hexene ton-hexane under mild conditions. Influence of [1-hexene], [catalyst], temperature and nature of the solvent on the rate of the reaction was investigated. A rate expression is proposed based on the observed initial rate data. Recycling efficiency of the catalyst has also been studied.     

Nitrophenoxy groups containing polybenzimidazoles as polymer electrolytes for fuel cells: Synthesis and characterization

Polybenzimidazoles containing different contents of pendant nitrophenoxy groups were prepared by condensation of 3,3′‐diamino‐benzidine with a mixture of 3,5‐dicarboxyl‐4′‐nitro diphenyl ether and isophthalic acid (IPA) in different ratios in polyphosphoric acid. The polymers are soluble in polar aprotic solvents, they have inherent viscosities in the range of 0.75–1.10 dL g^?1 and they form tough and transparent films on solution casting. They have good thermal stability with initial decomposition temperature ranging from 380 to 416°C in nitrogen, good tensile strength ranging from 56 to 65 MPa and reasonably good oxidative stability. Phosphoric acid uptake of these polymers is low compared with PBI and membranes doped with phosphoric acid exhibit good proton conductivity in the range of 6.6× 10^?3 to 1.9× 10^?2 S/cm at 25°C and 1.2× 10^?2 to 4.9× 10^?2 S/cm at 175°C, compared with 3.9× 10^?3 S/cm at 25°C and 3.2× 10^?2 S/cm at 175°C for PBI. These membranes are suitable for applications as polymer electrolyte for fuel cell and presumably for gas separation at high temperature. © 2010 Wiley Periodicals, Inc. J Appl Polym Sci, 2010