A reactive molecular dynamics model of thermal decomposition in polymers: I. Poly(methyl methacrylate)

The theory and implementation of reactive molecular dynamics (RMD) are presented. The capabilities of RMD and its potential use as a tool for investigating the mechanisms of thermal transformations in materials are demonstrated by presenting results from simulations of the thermal degradation of poly(methyl methacrylate) (PMMA). While it is known that depolymerization must be the major decomposition channel for PMMA, there are unanswered questions about the nature of the initiation reaction and the relative reactivities of the tertiary and primary radicals formed in the degradation process. The results of our RMD simulations, performed directly in the condensed phase, are consistent with available experimental information. They also provide new insights into the mechanism of the thermally induced conversion of this polymer into its constituent monomers.     

Design and architecture of a new space priority mechanism for ATM network nodes

This paper presents the architecture of a new space priority mechanism intended to control cell loss in ATM switches. Our mechanism is a new generic concept called: the multiple pushout. It is based on the utilization of both AAL and ATM features and on a particular definition of the priority bit. Whenever one cell of a message overflows the buffer of an ATM switch, the algorithm causes the switch to discard other cells of the message (including later arrivals). Such discarding frees buffer spaces for cells of other messages that have a chance of arriving at their destination intact. Our objective is to emphasize that in case of overload, with most of proposed mechanisms, cells are discarded without any semantic information about the type of cells. Therefore, at the destination, all the fragments of the corrupted messages will be discarded anyway. Finally, we present simulation results comparing cell loss rates and message loss rates of several space priority mechanisms.     

Pyramid collaborative filtering technique for an intelligent autonomous guide agent

This article presents an autonomous guide agent that can observe a community of learners on the web, interpret the learners' inputs, and then assess their sharing. The goal of this agent is to find a reliable helper (tutor or other learner) to assist a learner in solving his task. Despite the growing number of Internet users, the ability to find helpers is still a challenging and important problem. Although helpers could have much useful information about courses to be taught, many learners fail to understand their presentations. For that, the agent must be able to deal autonomously with the following challenges: Do helpers have information that the learners need? Will helpers present information that learners can understand? And can we guarantee that these helpers will collaborate effectively with learners? We have developed a new filtering framework, called a pyramid collaborative filtering model, to whittle the number of helpers down to just one. We have proposed four levels for the pyramid. Moving from one level to another depends on three filtering techniques: domain model filtering, user model filtering, and credibility model filtering. A new technique is filtering according to helpers' credibilities. Our experiments show that this method greatly improves filtering effectiveness. © 2007 Wiley Periodicals, Inc. Int J Int Syst 22: 1065–1082, 2007.     

Bile acids as constituents for dental composites: in vitro cytotoxicity of (meth)acrylate and other ester derivatives of bile acids.

Methacrylic derivatives of bile acids have been synthesized for use as monomers in dental composites. Polymeric dental materials are known to leach cytotoxic unreacted monomers and degradation products. In this study, the in vitro cytotoxicity of bile acids and their derivatives towards 3T3 fibroblasts has been evaluated by colorimetric MTT assay and compared with that of the common dental monomers BisGMA, UDMA and TEGDMA. In general, the bile acids and their derivatives induced mitochondrial dysfunction at similar or higher concentrations than the commercial dental monomers. Certain monomers did not influence MTT response over their entire range of solubility.     

Stratified institutions and elementary homomorphisms

For conventional logic institutions, when one extends the sentences to contain open sentences, their satisfaction is then parameterized. For instance, in the first-order logic, the satisfaction is parameterized by the valuation of unbound variables, while in modal logics it is further by possible worlds. This paper proposes a uniform treatment of such parameterization of the satisfaction relation within the abstract setting of logics as institutions, by defining the new notion of stratified institutions. In this new framework, the notion of elementary model homomorphisms is defined independently of an internal stratification or elementary diagrams. At this level of abstraction, a general Tarski style study of connectives is developed. This is an abstract unified approach to the usual Boolean connectives, to quantifiers, and to modal connectives. A general theorem subsuming Tarski's elementary chain theorem is then proved for stratified institutions with this new notion of connectives.     

Biological vulnerability to alcoholism.

This article reviews the role of biological factors in the risk for alcoholism. The discussion notes the importance of the definition of primary alcoholism and highlights data indicating that this disorder is genetically influenced. The major emphasis is on studies of men at high risk for the future development of alcoholism. The most promising trait markers of a biological vulnerability to alcoholism include a decreased intensity of reaction to modest ethanol doses for sons of alcoholics compared with control subjects, a decreased amplitude of certain brain waves of the event-related potential, and a different pattern of background cortical electroencephalograms for young men at high risk for future alcoholism. (PsycINFO Database Record (c) 2010 APA, all rights reserved)     

A fast block Hankel solver based on an inversion formula for block Loewner matrices

We propose a newO(p ³ n ²) algorithm for solving complexnp×np linear systems that have block Hankel structure, where the blocks are square matrices of sizep×p. Via FFTs the block Hankel system is transformed into a block Loewner system. An inversion formula enables us to calculate the inverse of the block Loewner matrix explicitely. The parameters that occur in this inversion formula are calculated by solving two rational interpolation problems on the unit circle. We have implemented our algorithm in Fortran 90. Numerical examples are included.     

High nutrient loading and climatic parameters influence the dominance and dissimilarity of toxigenic cyanobacteria in northern bays of Lake Victoria

Eutrophication of Lake Victoria led to changes in its phytoplankton communities. However, different levels of eutrophication exist in the open lake and the bays, and between embayments. This study utilized spatial and temporal sampling of Napoleon Gulf and Murchison Bay, exhibiting different trophic conditions. Over one year, we investigated phytoplankton biomass, richness, diversity and dissimilarity, and related the dynamics of the dominant species to the limnological and climatic conditions. The results confirmed that Napoleon Gulf and Murchison Bay showed large differences in eutrophication status, with lower nutrient concentrations in Napoleon Gulf than in Murchison Bay, where a strong gradient was observed from inshore to offshore areas. These nutrient dynamics resulted in a 4 to 10 fold higher chlorophyll-a in Murchison Bay than in Napoleon Gulf. From the embayments, 135 phytoplankton taxa were recorded with no significant differences in alpha diversity. However, high dissimilarity in community structure was observed in beta diversity, mostly due to a turnover among the dominant toxigenic species. Thus, from a similar species pool, there was a shift in the dominant toxigenic cyanobacteria from Microcystis flos-aquae and M. aeruginosa in Murchison Bay, Dolichospermum circinale and Planktolyngbya circumcreta in Napoleon Gulf to D. circinale in the offshore stations. These cyanobacteria are toxigenic taxa with known health hazards. Using partial least square models, we showed that both climatic variables (e.g. wind, solar radiation) and levels of inorganic dissolved nutrients (e.g. SRP, NO₃^–, and NH₄⁺) are the main drivers of differences and dominance in cyanobacteria communities in northern Lake Victoria.