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91.
In this work, we show that lattice Monte Carlo simulations can be used to span the time and distance scales between underlying atomistic processes and macroscopic diffusion behavior. We use ab- initio calculations of binding energies versus configuration to calculate hopping rates of vacancies for use in lattice Monte Carlo (LMC) simulations of diffusion and aggregation in silicon. The LMC simulations consider the biased nature of vacancy hop frequencies in the neighborhood of dopants, with interactions up to sixth-nearest- neighbor distances included. We use these simulations to investigate the expected macroscopic diffusion behavior, as well as the process by which dopant/defect aggregation occurs. Specific phenomena investigated include collective behavior leading to greatly enhanced diffusivity at high doping levels, the time dependence of effective diffusivity due to the formation of dopant/vacancy clusters, and dopant fluxes in the presence of a vacancy gradient. 相似文献
92.
Delphine Antoni Jean-Baptiste Clavier Marius Pop Catherine Schumacher Fran?ois Lefebvre Georges No?l 《International journal of molecular sciences》2014,15(5):7554-7562
Purpose
to evaluate the role of whole brain radiotherapy (WBRT) and radiation boost (RB) for 208 patients recursive partitioning analysis (RPA) II with 1 or 2 brain metastases (BM) at a single institution.Methods and Materials
the dose of WBRT was 30 Gy (10 fractions of 3 Gy). One hundred thirty-two patients (63.5%) benefited from RB of 9 Gy in 3 fractions of 3 Gy at the metastatic site. Patients had 1 or 2 BM in 122 (58.7%) and 86 cases (41.3%), respectively.Results
patients with one or two metastases had similar survival (4.6 and 5.1 months, respectively) (p = 0.4). Median overall survival (OS) for patients treated with WBRT and RB, and with WBRT alone was 5.9 and 3.7 months, respectively (p = 0.03). The 6-, 12- and 24-month OS rates after WBRT and RB were 48.5%, 25% and 10.6%, respectively, while WBRT alone resulted in OS rates of 34%, 22.4% and 3.2%, respectively (p = 0.03). After WBRT and RB, the 6-, 12- and 24-month local control rates were 92%, 82% and 67%, respectively, while they were 81.2%, 75% and 37.5%, respectively, after WBRT alone (p = 0.03). The 6-, 12- and 24-month brain control rates after WBRT and RB were 88.7%, 75.8% and 62%, respectively, and after WBRT alone they were 78.5%, 59% and 37.7%, respectively (p = 0.03).Conclusion
additional boost delivered with 3D conformal radiotherapy improves local and brain control rates significantly as well as overall survival for RPA II patients with 1 or 2 unresectable BM. 相似文献93.
Stefan M Marius S Hritcu L Lucian H Mihasan M Marius M Pricop D Daniela P Gostin I Irina G Olariu RI Romeo-Iulian O Dunca S Simona D Melnig V Viorel M 《Journal of materials science. Materials in medicine》2011,22(4):789-796
In the present study, we report enhanced antimicrobial properties of 29 and 23 nm silver nanoparticles (Ag NPs) obtained by
electrochemical synthesis in poly(amide-hydroxyurethane) media. Antibacterial activity assessed by disk diffusion method indicates
that silver nanoparticles produced inhibition zones for both Escherichia coli and Staphylococcus aureus depending on silver concentration. The bacterial growth curve performed in the presence of silver nanoparticles showed a
stronger antibacterial effect at lower concentrations than those described in the earlier reports. The effect was both dose
and size dependent and was more pronounced against Gram negative bacteria than Gram positive one. The smallest Ag NPs used
had a bactericidal effect resulting in killing E. coli cells. Scanning electron microscopy analysis indicated major damage and morphology changes of the silver nanoparticles treated
bacterial cells. The major mechanism responsible for the antibacterial effect probably consists in clusters formation and
nanoparticles anchorage to the bacterial cell surface. 相似文献
94.
95.
96.
A Direct Approach to Organic/Inorganic Semiconductor Hybrid Particles via Functionalized Polyfluorene Ligands
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Tjaard de Roo Johannes Haase Janine Keller Christopher Hinz Marius Schmid Denis V. Seletskiy Helmut Cölfen Alfred Leitenstorfer Stefan Mecking 《Advanced functional materials》2014,24(18):2714-2719
Controlled Suzuki–Miyaura coupling polymerization of 7′‐bromo‐9′,9′‐dioctyl‐fluoren‐2′‐yl‐4,4,5,5‐tetramethyl‐[1,3,2]dioxaborolane initiated by bromo(4‐tert‐butoxycarbonylamino‐phenyl)(tri‐tert‐butylphosphine)palladium ( 1 ) or bromo(4‐diethoxyphosphoryl‐phenyl)(tri‐tert‐butylphosphine)palladium ( 2 ) yields functionalized polyfluorenes (Mn = 4 × 103 g mol?1, Mw/Mn < 1.2) with a single amine or phosphonic acid, respectively, end‐group. High temperature synthesis of cadmium selenide quantum dots with these functionalized polyfluorenes as stabilizing ligands yields hybrid particles consisting of good quality (e.g. emission full width at half maximum of 30 nm; size distribution σ < 10%) inorganic nanocrystals with polyfluorene attached to the surface, as corroborated by transmission electron microscopy analysis and analytical ultracentrifugation. Sedimentation studies on particle dispersions show that a substantial portion (ca. half) of the phosphonic acid terminated polyfluorene ligands is bound to the inorganic nanocrystals, versus ca. 5% for the amino‐functionalized polyfluorene ligands. Single particle micro‐photoluminescence spectroscopy shows an efficient and complete energy transfer from the polyfluorene layer to the inorganic quantum dot. 相似文献
97.
Bogdan C. Gagea Andrei N. Pârvulescu Georges Poncelet Vasile I. Pârvulescu 《Catalysis Letters》2005,102(3-4):219-222
Friedel-Crafts alkylations of α-methylnaphthalene with various alkylating agents were first carried out in the presence of methanesulfonic acid (MeSA). The Brønsted acid catalyst MeSA exhibited outstanding catalytic performance, and was found to be excellent catalyst and solvent for alkylation reaction of aromatic hydrocarbon. It’s found that alkenes can be used as excellent alkylating agent for alkylation of α-methylnaphthalene. The effects of various reaction parameters like type of alkylating agent, dosages of catalysts, reaction temperature and reaction time were investigated in detail. Moreover, the performance of reuse for catalysts was also studied. It’s found that, under the optimal reaction conditions, more than 90% of conversion for olefins and 100% of selectivity for the desired products were obtained. Compared with traditional catalysis technology, the reaction, catalyzed by MeSA catalyst, no volatile solvents needed, good selectivity for desired products could be obtained. The catalyst can be isolated easily from the reaction mixtures by decantation, and was successfully reused. The methanesulfonic acid could be considered as environmentally friendly novel catalyst and solvent for long-chain alkylation of α-methylnaphthalene with alkenes. The catalytic reaction mechanism for alkylation in the presence of MeSA was proposed as well. 相似文献
98.
High aspect ratio microstructures are currently created by several processes which include lithography (X-ray, deep ultraviolet,
etc.) and mechanical machining (diamond machining, microdrilling, etc.) The lithographic processes require more extensive
processing equipment such as an energy source, mask/mask holder/mask aligner, photoresist and substrate, and chemical development
capacity. In addition, these processes are serial in nature and each adds to the tolerances of the finished structure. The
current mechanical processes provide for the direct removal of the substrate material in a single step but are more limited
in the geometric patterns which can be created. In conventional machining, the process which provides the most versatility
in geometric patterns is milling. The micromilling process has two basic components. The first is the fabrication of small
milling cutters with very sharp cutting edges. The second is the actual removal of the workpiece material with a very precise
and repeatable machine tool. Several basic cutter designs have been fabricated using focused ion beam micromachining and are
undergoing testing. The cutter diameters are nominally 100 micrometers and 22 micrometers. Results have been obtained which
show that this process can be very effective for the rapid fabrication of molds and mask structures. 相似文献
99.
Micrometer-scale machining: tool fabrication and initial results 总被引:3,自引:0,他引:3
Michael J. Vasile Craig R. Friedrich Bharath Kikkeri Rob McElhannon 《Precision Engineering》1996,19(2-3):180-186
Conventional milling techniques scaled to ultrasmall dimensions have been used to machine polymethyl methacrylate (PMMA) with micrometer-sized milling tools. The object of this work is to achieve machining of a common material over dimensions exceeding 1 mm while holding submicrometer tolerances and micrometer size features. Fabricating the milling tools themselves was also an object of the study. A tool geometry for nominal 25 micrometer diameter cutting tools was found that cuts PMMA with submicrometer tolerances over trench lengths of 2 mm. The tool shape is a simple planar facet cut by focused ion beam milling on ground and polished 25 micrometer diameter steel tool blanks. Pairs of trenches 24 micrometers wide, 26 micrometers deep, 2.3 mm long, with a 14 micrometer separation were milled under various machining conditions. The results indicate that the limits of the machining process in terms of speed, pattern complexity, and tolerances have not been approached. This is the first demonstration of a generic method for microtool making by focused ion beam machining combined with ultraprecision numerically controlled milling. The method is shown to be capable of producing structures and geometries that are considered inaccessible by conventional materials removal techniques, and generally regarded as applications for deep X-ray lithography. 相似文献
100.
The total neutron cross-section of chromium has been measured in the range 1.3 × 10?4 to 30 eV by the transmission method with pulsed neutron time of flight techniques. A theoretical fit was performed giving a value of (3.25 ± 0.15) b for σabs at 0.0253 eV. 相似文献