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排序方式: 共有395条查询结果,搜索用时 18 毫秒
1.
Dr. Tomasz Ratajczyk Prof. Dr. Gerd Buntkowsky Dr. Torsten Gutmann Dr. Bartłomiej Fedorczyk Dr. Adam Mames Dr. Mariusz Pietrzak Zuzanna Puzio Piotr Grzegorz Szkudlarek 《Chembiochem : a European journal of chemical biology》2021,22(5):855-860
The biorelevant PyFALGEA oligopeptide ligand, which is selective towards the epidermal growth factor receptor (EGFR), has been successfully employed as a substrate in magnetic resonance signal amplification by reversible exchange (SABRE) experiments. It is demonstrated that PyFALGEA and the iridium catalyst IMes form a PyFALGEA:IMes molecular complex. The interaction between PyFALGEA:IMes and H2 results in a ternary SABRE complex. Selective 1D EXSY experiments reveal that this complex is labile, which is an essential condition for successful hyperpolarization by SABRE. Polarization transfer from parahydrogen to PyFALGEA is observed leading to significant enhancement of the 1H NMR signals of PyFALGEA. Different iridium catalysts and peptides are inspected to discuss the influence of their molecular structures on the efficiency of hyperpolarization. It is observed that PyFALGEA oligopeptide hyperpolarization is more efficient when an iridium catalyst with a sterically less demanding NHC ligand system such as IMesBn is employed. Experiments with shorter analogues of PyFALGEA, that is, PyLGEA and PyEA, show that the bulky phenylalanine from the PyFALGEA oligopeptide causes steric hindrance in the SABRE complex, which hampers hyperpolarization with IMes. Finally, a single-scan 1H NMR SABRE experiment of PyFALGEA with IMesBn revealed a unique pattern of NMR lines in the hydride region, which can be treated as a fingerprint of this important oligopeptide. 相似文献
2.
Results of a study on the modifying mechanical properties of loose optical‐fiber poly(butylene terephthalate) (PBT) tubes, produced during the standard industrial extrusion process, show that heat treatment make the structure of their material to change. The study comprised measurements of mechanical strengths properties of the tubes (tensile strength, compression strength, kinking) and determination of tube material structure [by differential thermal analysis (DTA), wide angle X‐ray scattering analysis (WAXD), and scanning electron microscopy (SEM)]. Results of the study allowed observation that the annealing at 70°C for 34 h of the tubes caused the crystalline α phase to increase in the tube material from ~28.5% to ~31.5% and the structure of the existing crystallites to become more perfect. This made the values of certain mechanical properties of the tubes to increase even by as much as 30%. The tubes following such thermal treatment could be used in cables exposed to heavy‐duty operation in arduous environments, where a larger margin from the standpoint of mechanical properties is required. © 2002 Wiley Periodicals, Inc. J Appl Polym Sci 86: 2130–2134, 2002 相似文献
3.
S. Suppan J. Trawczyski J. Kaczmarczyk G. Djga-Mariadassou A. Hynaux C. Sayag 《Applied Catalysis A: General》2005,280(2):209-214
Carbon black composites (CBCs) have been prepared by pyrolyzing mixture of a carbon black with polyfurfuryl alcohol and then pretreated by oxidation with nitric acid, gasification with water steam or ammoxidation. The effects of the chemical character of the carrier surface, nature of the active metal phase and pH value of the impregnation solution on the catalytic activity towards the hydrodesulfurization (HDS) of thiophene of the CBC supported Mo (Co) catalysts were determined. It was stated that the catalytic properties of the CBC supported sulfides of Mo or Co and of Mo carbides are affected by the chemical character of the carrier surface. Generally, catalysts supported over basic surface CBC exhibit higher activity than those ones supported over CBC possessing acidic surface character. Co catalysts supported on acidic surface show lower activity (per mol of active metal) than Mo based ones supported on the same carrier. In the case of catalysts supported on basic CBC, Co exhibits distinctly higher activity than Mo. At the experimental conditions adopted for this study, CBC surface properties, active phase nature, and catalyst impregnation pH were found to exert a relatively small influence on both HDS and hydrogenation activities. 相似文献
4.
The article proposes an analytical method for determining occupancy distribution and blocking probability in systems which are offered overflow traffic composed of multi-service traffic streams. The described analytical model enables determination of parameters of traffic overflowed from primary groups in hierarchically constructed telecommunication networks. The proposed method is based on an appropriate modification of the Kaufman-Roberts recursion for the full-availability group with multi-rate traffic and uses the modified Fredericks & Hayward’s approximation. Additionally, an approximate method for dimensioning systems with multi-service overflow traffic is also presented. The analytical results of the blocking probability and the results obtained in the dimensioning processes calculated using the presented methodology are compared with the data obtained from the system simulation process. 相似文献
5.
Teresa Mikołajczyk Grażyna Janowska Mariusz Wójcik Maciej Boguń Andrzej Kurzak 《应用聚合物科学杂志》2008,109(4):2513-2521
The rheological properties of spinning solutions of polyacrylonitrile in dimethyl formamide (DMF) containing various amounts of a ferromagnetic nanoaddition were investigated. The porous structure, the strength and thermal properties of fibers obtained from these solutions were assessed, as well as the uniformity of the nanoaddition distribution on the fiber surface was estimated. © 2008 Wiley Periodicals, Inc. J Appl Polym Sci, 2008 相似文献
6.
7.
Klaudia Zeranska-Chudek Anna Lapinska Agnieszka Siemion Agnieszka M. Jastrzębska Mariusz Zdrojek 《应用聚合物科学杂志》2021,138(10):49962
The rising demand for faster and more efficient electronic devices forces electronics industry to shift toward terahertz frequencies. Therefore there is a growing need for efficient, lightweight, and easy to produce absorbing materials in the terahertz range for electromagnetic interference (EMI) shielding and related applications. This study presents a study on basic optical properties of two types polymer-based composites loaded with two-dimensional structures—graphene and MXene phases (Ti2C). In said range, total EMI shielding efficiency (SE) and its components, the absorption coefficient (α ), refractive index, and complex dielectric function are investigated. The ratio of SE absorption component to reflection component (SEABS :SER ) of fabricated composites is equal or higher than 30:1 in over 80% of studied range. The fabricated composites exhibit low (<0.1) loss tangent in studied range. The addition of 1 wt% of graphene increases the composite α over 10-fold in respect to pure polymer–up to 60 cm−1 for frequency higher than 2 THz. 相似文献
8.
We consider deterministic distributed broadcasting on multiple access channels in the framework of adversarial queuing. Packets
are injected dynamically by an adversary that is constrained by the injection rate and the number of packets that may be injected
simultaneously; the latter we call burstiness. A protocol is stable when the number of packets in queues at the stations stays
bounded. The maximum injection rate that a protocol can handle in a stable manner is called the throughput of the protocol.
We consider adversaries of injection rate 1, that is, of one packet per round, to address the question if the maximum throughput
1 can be achieved, and if so then with what quality of service. We develop a protocol that achieves throughput 1 for any number
of stations against leaky-bucket adversaries. The protocol has
O(n2+\textburstiness){\mathcal{O}(n^2+\text{burstiness})} packets queued simultaneously at any time, where n is the number of stations; this upper bound is proved to be best possible. A protocol is called fair when each packet is
eventually broadcast. We show that no protocol can be both stable and fair for a system of at least two stations against leaky-bucket adversaries. We study in detail small systems of exactly
two and three stations against window adversaries to exhibit differences in quality of broadcast among classes of protocols.
A protocol is said to have fair latency if the waiting time of packets is
O(\textburstiness){\mathcal{O}(\text{burstiness})}. For two stations, we show that fair latency can be achieved by a full sensing protocol, while there is no stable acknowledgment
based protocol. For three stations, we show that fair latency can be achieved by a general protocol, while no full sensing
protocol can be stable. Finally, we show that protocols that either are fair or do not have the queue sizes affect the order
of transmissions cannot be stable in systems of at least four stations against window adversaries. 相似文献
9.
Mariusz Janiak Krzysztof Tchoń 《Systems & Control Letters》2011,60(8):625-631
This paper addresses the constrained motion planning problem for nonholonomic systems represented by driftless control systems with output. The problem consists in defining a control function driving the system output to a desirable point at a given time instant, whereas state and control variables remain over the control horizon within prescribed bounds. The state and control constraints are handled by extending the control system with a pair of state equations driven by the violation of constraints, and adding regularizing perturbations. For the regularized system a Jacobian motion planning algorithm is designed, called imbalanced. Solutions of example constrained motion planning problems for the rolling ball illustrate the theoretical concepts. 相似文献
10.