Influence of 2,6 (N-pyrazolyl)isonicotinic acid on the photovoltaic properties of a dye-sensitized solar cell fabricated using poly(vinylidene fluoride) blended with poly(ethylene oxide) polymer electrolyte

A novel method of introducing a synthesized organic nitrogenous compound 2,6 (N-pyrazolyl)isonicotinic acid (BNIN) and its effect on the conduction behavior of poly(vinylidene fluoride) (PVdF)–poly(ethylene oxide) (PEO) polymer-blend electrolyte with potassium iodide (KI) and iodine (I₂) and the corresponding performance of the dye-sensitized solar cells (DSSCs) were studied. A systematic investigation of the blends using FTIR provides evidence of interaction of BNIN with the polymer. Differential scanning calorimetry (DSC) study proves the miscibility of these polymers. Due to the coordinating and plasticizing effects of BNIN, the ionic conductivity of polymer blend electrolytes is enhanced. The efficiency of DSSC using BNIN doped polymer blend electrolyte was 7.3% under an illumination of 60 mW cm⁻² were observed for the best performance of a solar cell in this work.     

Synthesis and anti-bacterial activity of novel dihydrochromeno[8,7-e][1,3]oxazine-2(8H)-thiones

A novel series of sulfur-containing dihydrochromeno[8,7-e][1,3]oxazine-2(8H)-thiones has been synthesized through an eco-friendly Mannich-type condensation cyclization reaction of 7-hydroxy-4-methyl-2-thiocoumarin or 6-chloro-7-hydroxy-4-methyl-2-thiocoumarin with formaldehyde and primary amines in water at 80–90°C for 2 h. All the synthesized compounds were screened for their in vitro anti-bacterial efficacy against two Gram-positive and three Gram-negative bacterial strains by using the disc diffusion method. The compound (8c) was found to be most potent with the zone of inhibition of 16 and 15 mm against Staphylococcus aureus ATCC 2937 and Klebsiella pneumoniae ATCC 31488, respectively.     

Pseudo-Parallel Datapath Structure for Power Optimal Implementation of 128-pt FFT/IFFT for WPAN

An optimal implementation of 128-Pt FFT/IFFT for low power IEEE 802.15.3a WPAN using pseudo-parallel datapath structure is presented, where the 128-Pt FFT is devolved into 8-Pt and 16-Pt FFTs and then once again by devolving the 16-Pt FFT into 4×4 and 2×8. We analyze 128-Pt FFT/IFFT architecture for various pseudo-parallel 8-Pt and 16-Pt FFTs and an optimum datapath architecture is explored. It is suggested that there exists an optimum degree of parallelism for the given algorithm. The analysis demonstrated that with a modest increase in area one can achieve significant reduction in power. The proposed architectures complete one parallel-to-parallel (i.e., when all input data are available in parallel and all output data are generated in parallel) 128-point FFT computation in less than 312.5 ns and thereby meet the standard specification. The relative merits and demerits of these architectures have been analyzed from the algorithm as well as implementation point of view. Detailed power analysis of each of the architectures with a different number of data paths at block level is described. We found that from power perspective the architecture with eight datapaths is optimum. The core power consumption with optimum case is 60.6 MW which is only less than half of the latest reported 128-point FFT design in 0.18u technology. Furthermore, a Single Event Upset (SEU) tolerant scheme for registers is also explored. The SEU tolerant scheme will not affect the performance, however, there is an increase power consumption of about 42 percent. Apart from the low power consumption, the advantages of the proposed architectures include reduced hardware complexity, regular data flow and simple counter based control.     

High performance HTLNR/epoxy blend—Phase morphology and thermo-mechanical properties

An attempt was made to toughen diglycidyl ether of bisphenol A (DGEBA) type epoxy resin with liquid natural rubber possessing hydroxyl functionality (HTLNR). Epon 250 epoxy monomer is cured using nadic methyl anhydride as hardener in presence of N, N dimethyl benzyl amine as accelerator. HTLNR of different concentrations up to 20 wt % is used as modifier for epoxy resin. The addition HTLNR to an anhydride hardener/epoxy monomer mixture has given rise to the formation of phase-separated structure, consisting of small spherical liquid natural rubber particles bonded to the surrounding epoxy matrix. The particle size increased with increase in rubber content. The viscoelastic properties of the blends were analyzed using dynamic mechanical thermal analysis. The T_g corresponding to epoxy rich phase was evident from the dynamic mechanical spectrum, while the T_g of the rubber phase was overlapped by the β relaxation of epoxy phase. Glass transition of the epoxy phase decreased linearly as a function of the amount of rubber. The mechanical properties such as impact and fracture toughness were also carefully examined. The impact and fracture toughness increase with HTLNR content. A threefold increase in impact strength was observed with 15 wt % HTLNR/epoxy blend. © 2011 Wiley Periodicals, Inc. J Appl Polym Sci, 2012