Chemical images

Chemical sensors can be used to generate a vast amount of information about the emissions from bio- and chemical processes, from food and bacteria and from a number of products. These emissions are either wanted or should be avoided. Wolfgang Göpel was one of those who recognized early the large potential of chemical sensor arrays and different modes of operation of a given sensor. We describe how large area field effect devices, with catalytic metal gates, can be used for the construction of a response image of a gaseous emission. More specifically, we discuss the new possibilities obtained through the use of catalytic metals with a gradient in thickness. Some basic features of such sensing surfaces are demonstrated and, finally, time-dependent response images from aging meat are used to demonstrate the potential of the method used. It is based on a scanning light pulse technique (SLPT) which measures local polarization or work function changes in two dimensions and, e.g. a sensing surface consisting of bands of different catalytic metals with a gradient in thickness.     

Separate versus Simultaneous Saccharification and Fermentation of Two‐Step Steam Pretreated Softwood for Ethanol Production

Abstract

In two previous studies, optimal conditions were identified for two‐step steam pretreatment of SO₂‐ and H₂SO₄‐impregnated softwood. In the present study the yield of sugar and ethanol was determined in a process development unit where pretreatment was performed in a 10‐L reactor and simultaneous saccharification and fermentation (SSF) or enzymatic hydrolysis (EH) were performed in 30‐L reactors. The study showed that a steam pretreatment reactor should be larger than 2 L to yield acceptable results. Two pretreatment combinations were studied. In the H₂SO₄ case, the first pretreatment step was at 180°C for 10 min with 0.5% H₂SO₄ and the second step at 210°C for 2 min with 1% H₂SO₄. In the SO₂ case, first step was at 190°C for 2 min followed by a second step at 210°C for 5 min. The concentration of SO₂ was 3% in both steps. EH and SSF were performed on the whole slurry after the second pretreatment step to determine the yield of sugars and ethanol. The liquid after the first pretreatment step was also analyzed and fermented. When SSF and EH were performed at the same dry matter content and enzymatic activity, the ethanol yield in SSF exceeded the yield obtained with EH in both pretreatment cases, even when 100% yield in the fermentation step was assumed. Thus SSF is a better process if yield is the main priority. Comparison of the yields with the two acid catalysts showed higher yields with SO₂ in both SSF and EH. The overall ethanol yield following SSF of SO₂‐impregnated and pretreated wood reached 81% of the theoretical, that is, 357 liters per metric ton of dry raw material.     

On the physics of power,energy and economics of renewable electric energy sources - Part II

Renewable Energy Technologies (RETs) are often recognized as less competitive than traditional electric energy conversion systems. Obstacles with renewable electric energy conversion systems are often referred to the intermittency of the energy sources [1] and the relatively high maintenance cost. However, due to an intensified discourse on climate change and its effects, it has from a societal point of view, become more desirable to adopt and install CO₂ neutral power plants. Even if this has increased the competitiveness of RETs in a political sense, the new goals for RET installations must also be met with economical viability. We propose that the direction of technical development, as well as the chosen technology in new installations, should not primarily be determined by policies, but by the basic physical properties of the energy source and the associated potential for inexpensive energy production. This potential is the basic entity that drives the payback of the investment of a specific RET power plant. With regard to this, we argue that the total electric energy conversion system must be considered if effective power production is to be achieved, with focus on the possible number of full loading hours and the Degree of Utilization [2]. This will increase the cost efficiency and economical competitiveness of RET investments, and could enhance faster diffusion of new innovations and installations without over-optimistic subsidies. This paper elaborates on the overall problem of the economy of renewable electric energy conversion systems by studying the interface between physics, engineering and economy reported for RET power plants in different scientific publications. The core objective is to show the practical use of the Degree of Utilization and how the concept is crucial for the design and economical optimization disregarding subsidies. The results clearly indicate that the future political regulative frameworks should consider the choice of renewable energy source since this strongly affects the economical output from the RET power plants.     

Experimental evaluation of radiator control based on primary supply temperature for district heating substations

In this paper, we evaluate whether the primary supply temperature in district heating networks can be used to control radiator systems in buildings connected to district heating; with the purpose of increasing the ΔT. The primary supply temperature in district heating systems can mostly be described as a function of outdoor temperature; similarly, the radiator supply temperature in houses, offices and industries can also be described as a function of outdoor temperature. To calibrate the radiator control system to produce an ideally optimal radiator supply temperature that produces a maximized ΔT across the substation, the relationship between the primary supply temperature and outdoor temperature must be known. However, even if the relation is known there is always a deviation between the expected primary supply temperature and the actual temperature of the received distribution media. This deviation makes the radiator control system incapable of controlling the radiator supply temperature to a point that would generate a maximized ΔT.     

Options for the Swedish steel industry - Energy efficiency measures and fuel conversion

The processes of iron and steel making are energy intensive and consume large quantities of electricity and fossil fuels. In order to meet future climate targets and energy prices, the iron and steel industry has to improve its energy and resource efficiency. For the iron and steel industry to utilize its energy resources more efficiently and at the same time reduce its CO₂ emissions a number of options are available. In this paper, opportunities for both integrated and scrap-based steel plants are presented and some of the options are electricity production, fuel conversion, methane reforming of coke oven gas and partnership in industrial symbiosis. The options are evaluated from a system perspective and more specific measures are reported for two Swedish case companies: SSAB Strip Products and Sandvik AB. The survey shows that both case companies have great potentials to reduce their CO₂ emissions.     

A probabilistic fracture mechanics method and strength analysis of glulam beams with holes

A probabilistic fracture mechanics method is presented and applied to glulam beams with holes. The method is based on a combination of Weibull weakest link theory and a mean stress method which is a generalization of linear elastic fracture mechanics. Combining these two methods means that the global strength will be governed by both fracture energy and material strength and also that the stochastic nature of the material properties are taken into account. The probabilistic fracture mechanics method is evaluated by comparison to experimental test results. The method shows good ability to predict strength, with the exception of very small beams where the capacity is overestimated. The comparison to experimental tests deals also with other methods for strength analysis including code design methods.     

Indetermined chair frames of ash wood

During recent years more interest has been emphasised on wood as a construction material. This is so because wood is a renewable resource and also because problems with waste do not emerge when the wooden structure is taken out of operation. On the contrary this waste is still a resource even if the structure is demolished. Wood could always be used as a biomass fuel which is not expected to contribute to the greenhouse effect. In Sweden most of the interest has been emphasised on our conifers while broad leaved species are much less examined. This paper shows the result from the Finite Element Method applied on indetermined chair frames and compares these findings with actual testing in our laboratory. The conclusion is that there are considerable discrepancies between calculations and real behaviour even for relatively simple structures such as a chair frame. It seems that the real chair is stronger than expected even if the joints between the furniture members must reduce the overall strength found by the FEM calculations.     

Analysis of variant forms of porcine surfactant polypeptide-C by nano-electrospray mass spectrometry

Electrospray (ES) mass spectrometry has been used to analyse preparations of porcine pulmonary surfactant polypeptide-C (SP-C). A number of variant forms of the native 35-residue dipalmitoylated peptide were detected including (a) C-terminally methylated SP-C, (b) C-terminally methylated and methionine oxidized SP-C, (c) N-terminally truncated, C-terminally methylated and methionine oxidized SP-c, (d) C-terminally elongated, C-terminally methylated and methionine oxidized SP-C, and (e) tripalmitoylated, C-terminally methylated and methionine oxidized SP-C. C-terminal methylation and methionine oxidation are probably a consequence of the sample handling procedure. The occurrence of the C-terminally elongated form of SP-C has implications for the in vivo processing of proSP-C and the Tandem mass spectrometry (MS/MS) was used to confirm the amino acid sequence of SP-C and the presence of palmitoyl groups covalently linked to the peptide. Some of the structures of the variant forms of SP-C were determined by MS/MS.