Untersuchung von Buchenschnittholz (Fagus sylvatica L.) hinsichtlich der Eignung für Brettschichtholz

Beech glulam for structural purposes has to be manufactured from strength graded beech lumber. At present one can assume that such material is not available on the market: There is not only a lack of practice in strength grading of beech lumber but also a lack of clearly defined raw material to be strength graded for beech glulam. This article aims to show that beech lumber graded following the Rules of the Measurement and Inspection of Hardwood and Cypress (published by the National Hardwood Lumber Association) has a potential as raw material for beech glulam. 218 beech boards approximately complying with two different grades, an upper and a common grade, were examined in regard to visual strength grading according to DIN 4074-5 (2003). The results show that 90% of the upper grade and 50% of the common grade boards fulfil the requirements for grade LS10 in DIN 4074-5 (2003). This finally enables the manufacture of beech glulam in accordance with strength class GL28. In addition, mechanical strength grading taking into account the modulus of elasticity even enables grading of 80% of the upper and 40% of the common grade boards for GL40.     

Determination of water-soluble vitamins in soft drinks and vitamin supplements using capillary electrophoresis

A method for the determination of six water-soluble vitamins based on capillary electrophoresis (CE) operated in micellar mode was developed. Thiamine hydrochloride (vitamin B1), riboflavin (vitamin B2), pyridoxine hydrochloride (vitamin B6), pantothenic acid (vitamin B5), nicotinamide (vitamin B3), and cobalamin (Vitamin B12) could be separated in a single run. All CE parameters such as buffer composition and operation temperature were optimized in order to achieve better separation. Relative standard deviations (RSDs) of the described method ranged from 1.08 to 3.68% (intra-day precision) and 1.26 to 3.35% (inter-day precision). The method was then used for measuring various soft drinks and vitamin supplements directly without any step of sample cleanup. The determination of niacin was successful for all samples tested, reaching recoveries near 100%. Riboflavin and pyridoxine were quantified successfully in some but not all samples. Therefore, an evaluation on a case-by-case basis is mandatory. When applicable, this method provides a fast, accurate, simple, and inexpensive way to quantify selected vitamins, and is therefore well suited for routine analysis in soft drink industry.     

Molecular Characterization and Quantification of Saponins from Sugar Beet (Beta vulgaris ssp. vulgaris var. altissima)

Consumer demand for sustainably and ecologically produced food has grown in recent years. However, for numerous reasons, this demand has not always been met. New solutions are still being sought, particularly in the area of emulsifiers, an integral ingredient of many food products. The biggest challenge is the limited scope of application offered by current alternatives. While some progress has been made using foam active quillaja saponins, they are neither pleasant-tasting nor sustainably produced. Only very little is known about other alternatives, and especially the behavior of saponins, particularly on a molecular level, is not very well understood. Moreover, it is often not known which parts of a plant contain the highest levels of saponins and are therefore most suitable for extraction. To expand the current level of knowledge about emulsifying and foam active extracts, saponin extracts were made from oat bran, beetroot as well as sugar beet and characterized in close cooperation with the Department of Food Physics and Meat Science at the University of Hohenheim. Measurements conducted on these extracts showed that foam activity is a good indicator of their emulsifying ability. The most promising one - sugar beet extract - was examined in more detail using taste dilution analysis, which revealed saponin fractions with a slight off-taste and high foam activity. A series of eight saponins was obtained from these fractions and further characterized, together with three commercially available ones that were identified using non-targeted screening. The unequivocal identification and structure elucidation was performed using a combination of liquid chromatography-tandem mass spectrometry (LC-MS/MS) and both one-dimensional (1D) and two-dimensional (2D) nuclear magnetic resonance (NMR) spectroscopy. For most substances, this was the first time that a complete assignment of ¹H and ¹³C NMR signals had been made. All of these saponins possess taste recognition values above 1000 μmol/L, which is higher than most values for the taste- active saponins reported in the literature. The foam activity of these substances was measured using a self-developed small-scale foam activity assay. It was measured for different concentrations of saponins in a buffer solution. The foam activity of numerous other saponins was also determined, resulting in the most comprehensive overview of the foam activities of individual saponins. In addition to these isolation and characterization activities, an LC-MS/MS method of performing simultaneous quantitative analyses of all the obtained sugar beet saponins was developed and validated. These were quantified in several sugar beet varieties (root and leaves), different sugar beet compartments, and side streams originating during the sugar beet converting process. Great variations in mass fractions were found in these materials, ranging from 862 mg/kg to 2,452 mg/kg for the various sugar beet root varieties and from 907 mg/kg to 5,398 mg/kg for the sugar beet leave varieties. Sugar beet fiber was identified as the best saponin source, with a total saponin quantity of 12.7 g/kg, followed by dried sugar beet pulp, with a total quantity of 10.3 g/kg. As a by-product stream, dried sugar beet pulp is highly suitable for the sustainable manufacture of saponins. The results obtained are of key significance to the utilization of sugar beet saponins as well as saponins extracted from other plant materials or by-product streams for use as food additives.     

From Meso to Macro: Controlling Hierarchical Porosity in Supraparticle Powders

A drying droplet containing colloidal particles can consolidate into a spherical assembly called a supraparticle. Such supraparticles are inherently porous due to the spaces between the constituent primary particles. Here, the emergent, hierarchical porosity in spray-dried supraparticles is tailored via three distinct strategies acting at different length scales. First, mesopores (<10 nm) are introduced via the primary particles. Second, the interstitial pores are tuned from the meso- (35 nm) to the macro scale (250 nm) by controlling the primary particle size. Third, defined macropores (>100 nm) are introduced via templating polymer particles, which can be selectively removed by calcination. Combining all three strategies creates hierarchical supraparticles with fully tailored pore size distributions. Moreover, another level of the hierarchy is added by fabricating supra-supraparticles, using the supraparticles themselves as building blocks, which provide additional pores with micrometer dimensions. The interconnectivity of the pore networks within all supraparticle types is investigated via detailed textural and tomographic analysis. This work provides a versatile toolbox for designing porous materials with precisely tunable, hierarchical porosity from the meso- (3 nm) to the macroscale (≈10 µm) that can be utilized for applications in catalysis, chromatography, or adsorption.     

ARAP Revisited Discretizing the Elastic Energy using Intrinsic Voronoi Cells

As-rigid-as-possible (ARAP) surface modelling is widely used for interactive deformation of triangle meshes. We show that ARAP can be interpreted as minimizing a discretization of an elastic energy based on non-conforming elements defined over dual orthogonal cells of the mesh. Using the intrinsic Voronoi cells rather than an orthogonal dual of the extrinsic mesh guarantees that the energy is non-negative over each cell. We represent the intrinsic Delaunay edges extrinsically as polylines over the mesh, encoded in barycentric coordinates relative to the mesh vertices. This modification of the original ARAP energy, which we term iARAP, remedies problems stemming from non-Delaunay edges in the original approach. Unlike the spokes-and-rims version of the ARAP approach it is less susceptible to the triangulation of the surface. We provide examples of deformations generated with iARAP and contrast them with other versions of ARAP. We also discuss the properties of the Laplace-Beltrami operator implicitly introduced with the new discretization.     

Can support by digital technologies stimulate intrapreneurial behaviour? The moderating role of management support for innovation and intrapreneurial self-efficacy

Drawing on theorising on digital technologies as external enablers of entrepreneurial activities and an interactionist perspective on corporate entrepreneurship, this article examines the relationship between digital technology support and employee intrapreneurial behaviour. We propose that management support for innovation as an organisational characteristic and intrapreneurial self-efficacy as an individual characteristic moderate this relationship. Findings from a metric conjoint experiment with 1360 decisions nested within 85 employees showed that support by social media, support by collaborative technologies, and support by intelligent decision support systems were significant predictors of employee intrapreneurial behaviour. However, the relative impact of support by these digital technologies varied with different levels of management support for innovation and intrapreneurial self-efficacy.     

Direct Observation of Photoinduced Ion Migration in Lead Halide Perovskites

Unique optoelectronic, electronic, and sensing properties of hybrid organic–inorganic perovskites (HOIPs) are underpinned by the complex interactions between electronic and ionic states. Here, the photoinduced field ion migration in HOIPs is directly observed. Using newly developed local probe time-resolved techniques, more significant CH₃NH₃⁺ migration than I⁻/Br⁻ migration in HOIPs is unveiled. It is found that light illumination only induces CH₃NH₃⁺ migration but not I⁻/Br⁻ migration. By directly observing temporal changes in bias-induced and photoinduced ion migration in device conditions, it is revealed that light illumination suppresses the bias-induced ion redistribution in the lateral device. These findings, being a necessary compensation of previous understandings of ion migration in HOIPs based on simulations and static and/or indirect measurements, offer advanced insights into the distinct light effects on the migration of organic cation and halides in HOIPs, which are expected to be helpful for improving the performance and the long-term stability of HOIPs optoelectronics.     

DFT modeling approach for operational risk assessment of railway infrastructure

International Journal on Software Tools for Technology Transfer - Reliability engineering of railway infrastructure aims to understand failure processes and to improve the efficiency and...