全文获取类型
收费全文 | 464篇 |
免费 | 32篇 |
国内免费 | 2篇 |
专业分类
电工技术 | 5篇 |
化学工业 | 179篇 |
金属工艺 | 4篇 |
机械仪表 | 8篇 |
建筑科学 | 16篇 |
能源动力 | 9篇 |
轻工业 | 86篇 |
水利工程 | 2篇 |
石油天然气 | 1篇 |
无线电 | 39篇 |
一般工业技术 | 58篇 |
冶金工业 | 28篇 |
原子能技术 | 1篇 |
自动化技术 | 62篇 |
出版年
2023年 | 10篇 |
2022年 | 38篇 |
2021年 | 66篇 |
2020年 | 18篇 |
2019年 | 18篇 |
2018年 | 22篇 |
2017年 | 23篇 |
2016年 | 25篇 |
2015年 | 9篇 |
2014年 | 25篇 |
2013年 | 42篇 |
2012年 | 19篇 |
2011年 | 30篇 |
2010年 | 16篇 |
2009年 | 18篇 |
2008年 | 20篇 |
2007年 | 16篇 |
2006年 | 14篇 |
2005年 | 11篇 |
2004年 | 7篇 |
2003年 | 8篇 |
2002年 | 6篇 |
2001年 | 4篇 |
2000年 | 4篇 |
1999年 | 2篇 |
1998年 | 8篇 |
1997年 | 7篇 |
1996年 | 2篇 |
1995年 | 1篇 |
1994年 | 2篇 |
1993年 | 1篇 |
1990年 | 2篇 |
1989年 | 1篇 |
1988年 | 1篇 |
1985年 | 1篇 |
1984年 | 1篇 |
排序方式: 共有498条查询结果,搜索用时 265 毫秒
41.
A new algorithm for the retrieval of columnar water vapor content is presented. The proposed procedure computes the area of the H2O absorption centered about 940 nm to allow its integrated columnar abundance as well as its density at ground level to be assessed. The procedure utilizes the HITRAN 2000 database as the source of H2O cross-section spectra. Experimental results were derived from radiometrically calibrated hyperspectral images collected by the Airborne Visible-Infrared Imaging Spectrometer (AVIRIS) sensor over the Cuprite mining district in Nevada. Numerical simulations based on the MODTRAN 4 radiative transfer code were also employed for investigating the algorithm's performance. An additional empirical H2O retrieval procedure was tested by use of data gathered by the VIRS-200 imaging spectrometer. 相似文献
42.
Silvia Cincera Silvia Barella Mattia Bellogini Elena Bresciani 《Journal of Failure Analysis and Prevention》2012,12(3):300-304
A cupronickel heat exchanger failed after 10?years of service. The cooling heat exchanger was in service in a marine environment, with water flowing along shellside and natural gas along tubeside. Many tubes showed leakages during a regular maintenance test. A comprehensive failure analysis of the heat exchanger revealed the de-nickelification process on the external side of the damaged tubes (shellside). The de-nickelification originated from a large deposit of sea water scale, over tube lengths, which completely covered the area just outside the internal portion of the tubesheet, and occurred because of a failure of the regular cleaning operation. Stagnant water and possible hot spot formations on the tubes probably caused the phenomenon. 相似文献
43.
Alfonso Ranalli Gabriella De Mattia & Maria L. Ferrante 《International Journal of Food Science & Technology》1997,32(4):289-297
To evaluate the level of quality of the olive oil given by a new processing system we compared it with the percolation oil, which is known to be of high quality. The new product was characterized by the following: (i) higher contents of tocopherols, tyrosol- and hydroxytyrosol-aglycones, volatile aromatic substances, sterols, triterpene alcohols and lipochromes, and higher values of 1,2-diglycerides/1,3-diglycerides and campesterol/stigmasterol ratios, colour indices and turbidity; (ii) lower contents of waxes and triterpene dialcohols, and lower values for spectrophotometric indices, carbonyl index, Wolff's ratio (K232 /K270 ), acidity, and peroxide number; (iii) similar contents of phenols, o- diphenols, free tyrosol, free hydroxytyrosol, triglycerides, stigmastadienes, and aliphatic alcohols, similar sensory score, and similar value of resistance to autoxidation, alcohol index, overall quality indices, and fatty acid composition. 相似文献
44.
PW Callas KO Leslie AR Mattia DL Weaver D Cook B Travis DE Stanley LA Rogers SL Mount TD Trainer MA Zarka RM Belding 《Canadian Metallurgical Quarterly》1997,21(7):812-819
Accuracy of diagnoses rendered using a live video telepathology network was assessed for permanent sections of surgical pathology specimens. To determine accuracy, telepathology diagnoses were compared with those obtained by directly viewing the glass slide using a standard microscope. A total of 294 cases were read via both telepathology and glass slide by attending pathologists at a tertiary care medical center. Overall accuracy was defined as exact concordance between diagnoses. Clinically insignificant differences in diagnoses were excluded to determine clinically significant accuracy. For the 285 cases with complete data, the overall accuracy for telepathology was 0.912 (95% confidence interval [CI], 0.872-0.941), whereas the overall accuracy for glass slide readings was 0.968 (95% CI, 0.939-0.985). This difference is statistically significant (p = 0.009). When focusing on clinically significant discrepancies, where the difference in diagnosis might affect therapeutic decisions, the video accuracy was only slightly less than the glass slide accuracy (0.965 [95% CI, 0.934-0.982] vs. 0.982 [95% CI, 0.957-0.994], respectively), but this difference is not statistically significant (p = 0.302). Most of the cases with clinically significant differences involved lesions with inherently high interobserver variation. Certainty of diagnosis did not differ between video and glass slide readings (p = 0.911), but there was an association between certainty of diagnosis and diagnostic accuracy for video (p = 0.003 for clinically significant accuracies). Based on these findings, we recommend when using this telepathology system that only preliminary diagnoses should be given in the following situations: for diagnostic areas with known high interobserver variability; when the consultant has any degree of uncertainty about the presence or absence of the lesion in question; and when there is insufficient experience using telepathology as a diagnostic medium. 相似文献
45.
Loredana Elena Nita Aurica P Chiriac Sossio Cimmino Clara Silvestre Donatella Duraccio Cornelia Vasile 《Polymer International》2008,57(2):342-349
BACKGROUND: The possibility to use β‐cyclodextrin as biodegradable tensioactive and an electromagnetic field in order to improve the kinetic parameters of radical emulsion polymerization is of interest. Thus, the influence of different surfactants—sodium lauryl sulfate (SLS) and β‐cyclodextrin (CD)—on the pathway of emulsion polymerization of methyl methacrylate (MMA) and emulsion copolymerization of MMA with 2,3‐epoxypropyl methacrylate (GMA) performed with or without the presence of a continuous electromagnetic field (MF) was studied. RESULTS: The presence of the MF leads to a considerable increase of the conversion during the first part of the reaction if the classic surfactant (SLS) is used. The reactions performed without MF and with CD exhibit a decrease of the conversion and of the polymerization rate as compared with the variants using SLS. The swelling rate and the maximum degree of swelling vary with the surfactant nature and with the reaction conditions and MF presence. Data from thermogravimetry and differential scanning calorimetry evidence the dependences between the polymer characteristics and the preparation conditions. CONCLUSION: This research underlines the coupling possibilities of the influence of a MF—growth of the reaction rate and conversion explained through radical pairs mechanism—with a combination of the ‘cage’ effect and ‘conformational control’ afforded by CD. The presence of MF and CD during the syntheses leads to an increase of Tg and an increase of PMMA and P(MMA‐co‐GMA) thermal stability. Copyright © 2007 Society of Chemical Industry 相似文献
46.
Synthesis and Antiplasmodial Activity of Novel Chloroquine Analogues with Bulky Basic Side Chains
下载免费PDF全文
![点击此处可从《ChemMedChem》网站下载免费的PDF全文](/ch/ext_images/free.gif)
Dr. Bruno Tasso Dr. Federica Novelli Dr. Michele Tonelli Dr. Anna Barteselli Dr. Nicoletta Basilico Dr. Silvia Parapini Prof. Donatella Taramelli Prof. Anna Sparatore Prof. Fabio Sparatore 《ChemMedChem》2015,10(9):1570-1583
Chloroquine is commonly used in the treatment and prevention of malaria, but Plasmodium falciparum, the main species responsible for malaria‐related deaths, has developed resistance against this drug. Twenty‐seven novel chloroquine (CQ) analogues characterized by a side chain terminated with a bulky basic head group, i.e., octahydro‐2H‐quinolizine and 1,2,3,4,5,6‐hexahydro‐1,5‐methano‐8H‐pyrido[1,2‐a][1,5]diazocin‐8‐one, were synthesized and tested for activity against D‐10 (CQ‐susceptible) and W‐2 (CQ‐resistant) strains of P. falciparum. Most compounds were found to be active against both strains with nanomolar or sub‐micromolar IC50 values. Eleven compounds were found to be 2.7‐ to 13.4‐fold more potent than CQ against the W‐2 strain; among them, four cytisine derivatives appear to be of particular interest, as they combine high potency with low cytotoxicity against two human cell lines (HMEC‐1 and HepG2) along with easier synthetic accessibility. Replacement of the 4‐NH group with a sulfur bridge maintained antiplasmodial activity at a lower level, but produced an improvement in the resistance factor. These compounds warrant further investigation as potential drugs for use in the fight against malaria. 相似文献
47.
The ellagitannin colonic metabolite urolithin D selectively inhibits EphA2 phosphorylation in prostate cancer cells
下载免费PDF全文
![点击此处可从《Molecular nutrition & food research》网站下载免费的PDF全文](/ch/ext_images/free.gif)
48.
Giuseppina Adiletta Loredana Liguori Donatella Albanese Paola Russo Marisa Di Matteo Alessio Crescitelli 《Food and Bioprocess Technology》2017,10(9):1631-1641
A preliminary characterization of two new soft-seeded pomegranate varieties (MR-100® and KINGDOM®) based on their main physico-chemical and nutritional parameters was reported. The two varieties showed significant differences (p ≤ 0.05) in polyphenols, anthocyanins and antioxidant activity. Kingdom pomegranate had higher polyphenols (2524.73 mg GAE/L), anthocyanins (752.49 mg C3gE/L) and antioxidant activity (EC50 13.58 μL/mL) than MR-100 (1792.74 mg GAE/L, 141.29 mg C3gE/L and EC50 47.53 μL/mL, respectively). Moreover, minimally processed arils of the two varieties were packaged in semipermeable and micro-perforated film at 5 °C, and the quality changes that occurred during storage condition (15 days) were investigated. During storage, Kingdom arils exhibited a better performance in terms of antioxidant activity, polyphenols and anthocyanin content with respect to MR-100. Furthermore, the packaging systems did not affect the estimated quality parameters for both varieties. Based on the sensory evaluation and microbial counts, both aril varieties reached, at 15-day storage, suitable values for commercial purpose. 相似文献
49.
Mattia Boniardi Daniele IelminiInnocenzo Tortorelli Andrea RedaelliAgostino Pirovano Mario AllegraMichele Magistretti Camillo BresolinDavide Erbetta Alberto ModelliEnrico Varesi Fabio PellizzerAndrea L. Lacaita Roberto Bez 《Solid-state electronics》2011,58(1):11-16
The phase-change memory (PCM) technology is considered as one of the most attractive non-volatile memory concepts for next generation data storage. It relies on the ability of a chalcogenide material belonging to the Ge-Sb-Te compound system to reversibly change its phase between two stable states, namely the poly-crystalline low-resistive state and the amorphous high-resistive state, allowing the storage of the logical bit. A careful study of the phase-change material properties in terms of the set operation performance, the program window and the electrical switching parameters as a function of composition is very attractive in order to enlarge the possible PCM application spectrum. Concerning the set performance, a crystallization kinetics based interpretation of the observed behavior measured on different Ge-Sb-Te compounds is provided, allowing a physics-based comprehension of the reset-to-set transition. 相似文献
50.
Mattia Gazzola Oleg V. Vasilyev Petros Koumoutsakos 《Computers & Structures》2011,89(11-12):1224-1231
We present results from the shape optimization of linked bodies for drag reduction in simulations of incompressible flow at moderate Reynolds numbers. The optimization relies on the covariance matrix adaptation evolution strategy (CMA-ES) and the flow simulations use vortex methods with the Brinkman penalization to enforce boundary conditions in complex bodies. We exploit the inherent parallelism of CMA-ES, by implementing a multi-host framework which allows for the distribution of the expensive cost function evaluations across parallel architectures, without being limited to one computing facility. This study repeats in silico for the first time Ingo Rechenberg’s pioneering wind tunnel experiments for drag reduction that led to the inception of evolution strategies. The simulations confirm that the results of these experimental studies indicate a flat plate is not the optimal solution for drag reduction in linked bodies. We present the vorticity field of the flow and identify the governing mechanisms for this drag reduction by the slightly corrugated linked plate configuration. 相似文献