Traditional organizations and crisis management in transition—Organizational perspectives on new dynamics of independent civil engagement

Digitalization and the trend towards more short‐term and project‐oriented social engagement have had a direct impact on traditional crisis management. This societal change has supported the evolution of new types of volunteers who use low‐threshold potentials to organize and maintain support independently. Traditional institutions like the German Red Cross are challenged to deal with these rapid changes regarding their own organizational culture in relation to the new phenomenon of so‐called unaffiliated volunteers. This paper investigates how unaffiliated volunteers influence and change the organizational culture of German disaster management by analysing and reflecting organizational adaptation processes in the aftermath of the German floods in 2013, the storm events in the west of Germany in 2014 and the refugee relief mission in 2015–2016. Therefore, semi‐structured interviews with experts of the German Red Cross were held to analyse their reactions towards unaffiliated Volunteers during the Floods in 2013 and the refugee relief missions, and further focus group interviews were conducted to validate the extracted results. Findings suggest that among professionals and leading entities in the German Red Cross, a process of rethinking has emerged, recognizing the importance and necessity to open up organizational structures for the collaboration and coordination of unaffiliated volunteers.     

Hydrogen Sulfide Metabolite,Sodium Thiosulfate: Clinical Applications and Underlying Molecular Mechanisms

Thiosulfate in the form of sodium thiosulfate (STS) is a major oxidation product of hydrogen sulfide (H₂S), an endogenous signaling molecule and the third member of the gasotransmitter family. STS is currently used in the clinical treatment of acute cyanide poisoning, cisplatin toxicities in cancer therapy, and calciphylaxis in dialysis patients. Burgeoning evidence show that STS has antioxidant and anti-inflammatory properties, making it a potential therapeutic candidate molecule that can target multiple molecular pathways in various diseases and drug-induced toxicities. This review discusses the biochemical and molecular pathways in the generation of STS from H₂S, its clinical usefulness, and potential clinical applications, as well as the molecular mechanisms underlying these clinical applications and a future perspective in kidney transplantation.     

Preparation of glycol derivatives of partially hydrogenated soybean oil fatty acids and their potential as lubricants

Glycol diesters and mixtures of mono- and diesters have been prepared from methyl esters of partially hydrogenated soybean oil fatty acids and diethylene, dipropylene, neopentyl and triethylene glycols. The catalyst used in these reactions was a mixture of calcium acetate/barium acetate (3∶1, w/w). The reactions were carried out under nitrogen with 0.5% catalyst at temperatures in the range of 190–275°C. Borated esters of mixed mono- and diesters were prepared with 0.33 equivalent of boric acid per 1.0 equivalent hydroxyl group on the ester. Refractive indices, viscosities, and flash and fire points were determined for diesters, mixed mono- and diesters, and mixed diesters and borated esters. The viscosities, flash points and fire points indicate that these esters can be used as a component of lubricating oils. Wear-prevention characteristics of mixed diesters and borated esters indicated that they can be used as antifriction additives in lubricating oils. Lecture presented at the joint meeting of the International Society for Fat Research and the American Oil Chemists' Society in Toronto, May 10, 1992.     

What defense doesSchouwia purpurea (Cruciferae) have against the desert locust?

A field study of the food eaten by solitary desert locusts was carried out in a winter breeding area in Mauritania. The food eaten, determined by the plant epidermis found in fecal pellets, was compared to the plant's availability in the habitat.Schouwia purpurea, well represented in the diets, was dominant at the study site. Adults had a preference forTribulus terrester. Growth and feeding on these two plants were compared. The high water content ofS. purpurea leaves limited the dry matter eaten and slowed down growth. Glucosinolates were separated and quantified by gas chromatography. There are 132mol/g dry matter in green leaves. In multiple choice tests, with paper disks, glucosinolate extracts were phagostimulant at a low concentration (21mol/g dry matter) and repulsive at a higher one (214mol/ g dry matter). Biting behavior onS. purpurea was recorded and analyzed on video. The importance ofSchouwia purpurea in desert locust habitats and its defenses is discussed.     

Studies on the response of ‘Tifblue’ and ‘Woodard’ rabbiteye blueberries to fertilizers

A field study was conducted to investigate the effects of three fertilizer placement methods and 11 fertilizer formulations on plant survival, economics of replanting, yield, and fruit size of two rabbiteye blueberry (Vaccinium ashei Reade) cultivars Tifblue and Woodard. Fertilizer rates were either mixed with the soil under plants (before planting), sidedressed, or half-rate was placed under plants with the other half sidedressed. Fertilizers at planting caused a total of 34% Woodard and 12% Tifblue plants to die as compared to 6% for Woodard and none for Tifblue when no fertilizer was applied. Fertilizer formulas 2-1-1 and 5-10-10 oxide ratios placed under Woodard plants caused 100% mortality whereas Tifblue fertilized with oxide ratios 2-2-2 and 5-10-10 under plants reached the maximum 50% mortality. Splitting fertilizer placement under the side of the plants resulted in less Woodard plant mortality (30%) than placing all the fertilizer under plants (54%). However, plant mortality for the side/under group was not different than sidedressing all fertilizer (23%). A planted hectare in this experiment consisted of 1852 Tifblue and 926 Woodard plants, providing one Woodard plant to pollinate two Tifblue plants. Based on the results obtained, the 5-10-10 fertilizer placed under plants would be expected to cause half the Tifblue (926 plants) and all the Woodard (926 plants) to be replanted. Plant costs alone was estimated to be $2315 with additional replanting costs of $93 for Tifblue and much higher for Woodard. Sidedressing 5-10-10 fertilizer eight weeks after planting would have prevented plant mortality. Placement of various fertilizers under Woodard or Tifblue plants resulted in a significant increase in plant mortality as compared to side placement of fertilizers. Yield loss due to plant mortality increased linearly with the N level of the fertilizers (ranging from 0 to 2) for both cultivars. Woodard fruit size was not affected by fertilizer placement but placing fertilizers under Tifblue plants produced smaller yields with larger fruit than sidedressed plants. Blueberry plants in a virgin acidic soil may experience no reduction in yield if fertilization is completely eliminated.     

Measurement of O2-N2 binary sorption on 5A zeolite by isotope tracer and perturbation chromatography

Isotope tracer chromatography allows to extract simply and quickly multi component adsorption data and is demonstrated for single component and binary adsorption equilibria for O₂ and N₂ on 5A zeolite as an example. In this modification of conventional tracer chromatography, a small pulse of an isotope tracer is injected in an adsorbable carrier gas (pure or multicomponent mixture) flowing through a column filled with adsorbent and is designed to operate at almost uniform pressure. Isotherm parameters are readily extracted by fitting measurements of residence times at various pressures and carrier composition. The isotherms were in excellent agreement with volumetric measurements. Isotope tracer chromatography is shown to be superior to perturbation chromatography since the influence of the injection volume on the carrier gas composition is substantially smaller for tracer experiments. Unfortunately, this new improved gas chromatographic technique requires rather expensive isotopes. The strength of this new approach lies in the advantage of working with small adsorbent samples (1 g) making a rapid screening of newly developed materials possible.Nomenclature K _exp,tr,i experimental tracer adsorption constant (mol/kg pure adsorbent/Pa) - K _i Henry adsorption equilibrium constant (mol/kg pure adsorbent/Pa) - K _i,part partition coefficient - K _pert composite Henry constant (mol/kg pure adsorbent/Pa) - L column length (m) - L _i Langmuir adsorption constant (1/Pa) - n _i amount adsorbed on the solid (mol/kg adsorbent) - N _i adsorbent loading (Pa) - p total pressure (Pa) - p _i partial pressure of component i (Pa) - p _in column inlet pressure (Pa) - p _out column outlet pressure (Pa) - q _i amount of component i in the micropores (Pa) - R gas constant (J/mol/K) - t time (s) - T temperature (K) - v _f superficial velocity in adsorbent column (m/s) - v _out velocity at the outlet of the column (m/s) - V _inlet volumetric flow rate at inlet conditions (ml/s) - x molar fraction of tracer - y molar fraction of component i in the carrier gas - z axial coordinate (m) Greek letters _ext bed voidage, external porosity - _macr macropore porosity [_macr= _p (1–_ext)] - _micr micropore porosity - _tot total porosity - _p pellet porosity - volume fraction of binder material - _d dead time (s) - _tracer tracer residence time (s) - _pert perturbation residence time (s) - _crys crystal density (kg/m³)     

Examination of the relationship between cracking resistance,hardness, and strength of steels at different temperatures and strain rates

The results are presented of measurements of Brinell hardness HB of 15Kh2NMFA and 10G2FB steels in the temperature range 77 T 373K. The resultant HB values are compared with strength, impact toughness, and cracking resistance in the entire temperature range examined. The relationship between cold brittleness of the steels and the form of the HB-T curves is analyzed on the basis of the concept of the characteristic temperature of contact deformation. The results show that the relationship between hardness and yield limit depends in a complicated manner on the test temperature and is determined by the plastic deformation mechanisms operating in each individual case. Correlation dependences are presented for determining the height of the stretching zone and stress intensity factor on the basis of HB values at different temperatures and strain rates. A criterion K_Ic/HB is introduced to predict the cracking resistance inside the examined temperature range on the basis of the values of K_Ic and HB at the boundaries of this range.Translated from Problemy Prochnosti, No. 2, pp. 14–17, February, 1991.     

Evaluation of Sensors and Mapping Approaches for Disasters in Tunnels

Ground or aerial robots equipped with advanced sensing technologies, such as three‐dimensional laser scanners and advanced mapping algorithms, are deemed useful as a supporting technology for first responders. A great deal of excellent research in the field exists, but practical applications at real disaster sites are scarce. Many projects concentrate on equipping robots with advanced capabilities, such as autonomous exploration or object manipulation. In spite of this, realistic application areas for such robots are limited to teleoperated reconnaissance or search. In this paper, we investigate how well state‐of‐the‐art and off‐the‐shelf components and algorithms are suited for reconnaissance in current disaster‐relief scenarios. The basic idea is to make use of some of the most common sensors and deploy some widely used algorithms in a disaster situation, and to evaluate how well the components work for these scenarios. We acquired the sensor data from two field experiments, one from a disaster‐relief operation in a motorway tunnel, and one from a mapping experiment in a partly closed down motorway tunnel. Based on these data, which we make publicly available, we evaluate state‐of‐the‐art and off‐the‐shelf mapping approaches. In our analysis, we integrate opinions and replies from first responders as well as from some algorithm developers on the usefulness of the data and the limitations of the deployed approaches, respectively. We discuss the lessons we learned during the two missions. These lessons are interesting for the community working in similar areas of urban search and rescue, particularly reconnaissance and search.     

Autonomy for Mars Rovers: Past, Present, and Future

The vehicles used to explore the Martian surface require a high degree of autonomy to navigate challenging and unknown terrain, investigate targets, and detect scientific events. Increased autonomy will be critical to the success of future missions.