Induction time,storage capacity,and rate of methane hydrate formation in the presence of SDS and silver nanoparticles

In this communication, the kinetic parameters of methane hydrate formation (induction time, quantity and rate of gas uptake, storage capacity (SC), and apparent rate constant) in the presence of sodium dodecyl sulfate (SDS), synthetized silver nanoparticles (SNPs), and mixture of SDS?+?SNPs have been studied. Experimental measurements were performed at temperature of 273.65?K and initial pressure of 7?MPa in a 460?cm³ stirred batch reactor. Our results show that adding SDS, SNPs and their mixture increases the quantity of gas uptake, water to hydrate conversion, and SC of methane hydrate formation, noticeably. Using 300?ppm SDS increases the SC and the quantity of methane uptake 615, and 770%, respectively, compared with pure water. Investigating the hydrate growth rate at the start of hydrate formation process shows that, using SNPs, SDS, and their mixture increases the initial apparent rate constant of hydrate rate, considerably. Our results show that the system of methane?+?water?+?SDS 500?ppm?+?SNPs 45?µM represents the maximum value of initial apparent rate constant, compared with other tested systems.     

Solving non-convex economic dispatch problem with valve point effects using modified group search optimizer method

This paper presents a novel solution based on the group search optimizer (GSO) methodology in order to determine the feasible optimal solution of the economic dispatch (ED) problem considering valve loading effects. The basic disadvantage of the original GSO algorithm is the fact that it gives a near-optimal solution rather than an optimal one in a limited runtime period. In this paper, a new modified group search optimizer (MGSO) is presented for improving the scrounger and ranger operators of GSO. The proposed MGSO is applied on different test systems and compared with most of the recent methodologies. The results show the effectiveness of the proposed method and prove that MGSO can be applicable for solving the power system economic load dispatch problem, especially in large scale power systems.     

Two-dimensional spin coating with a vertical centrifugal force and the effect of artificial gravity on surface leveling

This study focuses on an innovative method for spin coating called the two-dimensional (2D) spin coating method. Using a centrifugal force applied by a rotary machine perpendicular to the wafer surface body, a vertical centrifuge force (VCF) was generated. The VCF allowed controllable artificial gravity acceleration to be generated and caused the coating to face this elevated gravity acceleration to adjust and normalize the high and low surface tension stresses. Previous surface leveling mathematics were analyzed and modified. The modified calculations indicate that the effect of additional gravity exerted on the liquid’s surface can reduce the amplitude of surface leveling. To experimentally investigate this phenomenon, a 2D spin coater was designed and manufactured. Higher artificial gravity overcame some common coating defects, such as cloudiness, edge beading, inner layer bubbling, and unsmooth surface leveling. Photoresist (AZP4620) was used as the coating material. The surface roughness was analyzed by atomic force microscopy (AFM) and the layer properties were also imaged by scanning electron microscopy (SEM). The AFM results (average and root-mean-square roughness) indicated a decrease in surface leveling amplitude by increasing the VCF. SEM images showed condensed layers without any porosity or rupture. The experimental results agreed with the simulations and calculated values.     

Thermal Stability Investigation of Synthesized Epoxy-Polyurethane/Silica Nanocomposites

Silicon - In this research, epoxy polyurethane-nano silica nanocomposites have been synthesized using an in-situ method, for which SiO2 nanocomposites had been initially ready in N,...     

Force and position control of grasp in multiple robotic mechanisms

One of the approaches to increase the dexterity of a robot manipulating system is a design philosophy that consists of multiple robotic mechanisms. Applications of such a collection of manipulators can be in the design of a dextrous end-effector, a reconfigurable fixture to locate and grip various sized objects, or cooperative robotic arms which through their coordinated motions are able to accomplish a given task. Although the applications of such a design philosophy are endless, many problems still remain to be addressed. One of these problems is the control of the contact forces (grasping forces) between the mechanisms and the position of the grasped object. This article addresses this problem. First, a model of the mechanisms in contact with the grasped object is postulated; second, the problem of controlling the grasping forces and the position of the grasped object is formulated in the linear multi-input/multi-output system, and, finally, a centralized optimal controller is proposed for controlling the desired variables. The results of this article are demonstrated using two examples. One of the main advantages of the proposed controller is that it also shapes the transient response of the grasping force, which is an important consideration in cases when grasping fragile objects. © 1996 John Wiley & Sons, Inc.     

Experimental and numerical investigation of sands and Geldart A biomass co-fluidization

This article investigated the fluidization of sands and small Geldart A biomass mixtures. The mixture fluidized like Geldart A type particles with a uniform bed expansion regime before bubbling. The video recorded color distance between pure sands and sands–biomass mixtures was used to estimate the sands–biomass mixing. The coarse-grained computational fluid dynamics–discrete element method with a hybrid drag model which couples the Syamlal–O'Brien drag and a filtered drag can capture the mixing while the simulation with Gidaspow drag predicted a segregated bed. The simulations were further validated with experimental measured pressure drops. The time averaged pressure drop equals the weight of the bed material, however, its fluctuation is about three times of the bed material fluctuation.     

In situ emulsion polymerization and characterization of PVAc nanocomposites including colloidal silica nanoparticles for wood specimens bonding

Polyvinyl acetate (PVAc) nanocomposites for wood adhesives containing different amounts of colloidal silica nanoparticles (CSNs) were synthesized via in situ one-step emulsion polymerization. The adhesion strength of wood specimens bonded by PVAc nanocomposites was investigated by the tensile test. Thermal properties of PVAc nanocomposites were also characterized by differential scanning calorimetry and thermogravimetric analysis. Rheological and morphological properties of the PVAc nanocomposites were investigated using rheometric mechanical spectrometry and field emission scanning electron microscopy (FESEM), respectively. The obtaining results showed that the shear strength of PVAc nanocomposite including 1 wt. % CSNs has the highest shear and tensile strength about 4.7 and 3.2 MPa, respectively. A small increment of T_g (~3 °C) and considerable increment of the ash content proved the enhancement of PVAc thermal characterization in the presence of CSNs. FESEM results showed uniform dispersion of nanoparticles throughout the PVAc matrix due to using the in situ emulsion polymerization process. © 2019 Wiley Periodicals, Inc. J. Appl. Polym. Sci. 2020 , 137, 48570.     

Compositional analysis and rheological characterization of gum tragacanth exudates from six species of Iranian Astragalus

The sugar composition and viscoelastic behaviour of Iranian gum tragacanth exuded by six species of Astragalus was investigated at a concentration of 1.3% and varying ionic strength using a controlled shear-rate rheometer. Compositional analysis of the six species of gum tragacanth by high-performance anion-exchange chromatography with pulsed amperometric detection suggested the occurrence of arabinose, xylose, glucose, galactose, fucose, rhamnose and galacturonic acid residues in the gum structure; however, the proportions of each sugar varied significantly among the gums from the different species of Astragalus, and this variation led to interesting differences in functional properties. Rheological measurements performed on dispersions of the six species of gum tragacanth demonstrated viscoelastic properties. The mechanical spectra derived from strain sweep and frequency sweep measurements indicated that the different gum tragacanth dispersions had distinctive viscoelastic behaviours. Investigation of the viscoelastic properties of the different gum dispersions in the presence of NaCl revealed that the addition of NaCl could lead to slight to drastic decreases in the G′, G″ or η^∗ values of the various gums. In general, the results indicated that the six varieties of gum tragacanth studied exhibited significantly different rheological properties; therefore, these different gums may find use in a variety of applications as stabilisers, thickeners, emulsifiers and suspending agents depending on their rheological behaviour.     

State identification of home appliance with transient features in residential buildings

Nonintrusive load monitoring (NILM) is crucial for extracting patterns of electricity consumption of household appliance that can guide users’ behavior in using electricity while their privacy is respected. This study proposes an online method based on the transient behavior of individual appliances as well as system steady-state characteristics to estimate the operating states of the appliances. It determines the number of states for each appliance using the density-based spatial clustering of applications with noise (DBSCAN) method and models the transition relationship among different states. The states of the working appliances are identified from aggregated power signals using the Kalman filtering method in the factorial hidden Markov model (FHMM). Thereafter, the identified states are confirmed by the verification of system states, which are the combination of the working states of individual appliances. The verification step involves comparing the total measured power consumption with the total estimated power consumption. The use of transient features can achieve fast state inference and it is suitable for online load disaggregation. The proposed method was tested on a high-resolution data set such as Labeled hIgh-Frequency daTaset for Electricity Disaggregation (LIFTED) and it outperformed other related methods in the literature.