Palmqvist Crack Extension and the Center-Loaded Penny Crack Analogy

Palmqvist crack extension in WC-Co can be described using the center-loaded penny crack analogy. When Palmqvist cracks are represented by semicircles of diameter l (l=crack length measured from an impression corner), the stress intensity factor which controls crack extension differs from that of a half-penny crack of radius l+a (2a = impression size) by only a slowly varying factor m=2^1/2 (l/a)^1/2; m≅1.0 to 2.4 for WC-Co and m≅0.8 to 1.4 for ceramics.     

Sintering TiO2 in HCl Atmospheres

TiO₂ was sintered in HCl atmospheres to enhance the effects of vapor transport. Little or no densification is observed for temperatures between 1000° and 1300°C. Particle coarsening occurs at temperatures above 1200°C. The apparent activation energy for particle growth is 114 kJ/mol. It is concluded that the primary mass-transport mechanism is vapor transport while the particle growth rate is limited by grain-boundary mobility .     

Effects of Particle Size on the Fusion of Soda–Lime–Silicate Glass Containing NaCl

The coupled effects of particle size and 1 wt% NaCl additions on the sequence of melting reactions in a multicomponent system (sand–soda ash–calcite–dolomite–feldspar) were studied using data from DTA, DTGA, and XRD interactively. Glass batches varied in average particle size from 250 μm to finer than 45 μm. Milestone events in the fusion process of the coarse particle base glass were elucidated. The termination temperature of the last significant reaction associated with CO₂ release was 35°C lower in the fine particle size batch than with the coarsest batch. Liquid-phase formation at ∼523°C in the batch with 1 wt% NaCl occurred to an increasingly sizable extent with decreasing particle size. This contrasts with a similar effect at ∼630°C for a comparable batch without NaCl via eutectic melting between soda ash and dolomite. Sodium chloride additions significantly enhanced dissolution of CaO relic.     

Surface Chemistry of Lead Titanate and Its Impact on Binder Removal

Carbon residue after binder burnout was characterized for several nonstoichiometric lead titanate powders. Thermal decomposition of the poly(methyl methacrylate) (PMMA) binder was performed in nitrogen at 600°C. A drastic decrease in carbon retention was obtained in the case of the titanium-rich samples. The amount of carbon retention varies from 0.2 mg/m² to 1.2 mg/m² by changing the Pb/Ti molar ratio from 0.92 to 1.08. The surface reaction between PMMA and lead titanate particles was studied by diffuse reflectance Fourier transform infrared spectroscopy (DRIFTS). Surface hydroxyls reacted with ester groups in the PMMA or the methylmethacrylate monomer produced upon pyrolysis. The DRIFTS results showed that titaniumrich samples are less reactive and produce less surfacebound organic groups. Interestingly, titanium-rich samples contained more surface hydroxyls. Isoelectric point measurements, however, show that titanium-rich samples are more acidic. Thus, the reactivity of the surface hydroxyls is determined primarily by their acid-base characteristics rather than their concentration. Lead titanate powder was exposed to MMA vapor in a tube furnace at the indicated temperatures using nitrogen carrier gas as a model experiment. DRIFTS difference spectroscopy and Raman spectroscopy were performed on these samples after the exposure. MMA reacts with lead titanate powder in manner similar to PMMA. Analysis for sp ² and sp ³ absorbance of Raman spectra of these exposed powders at 400°–600°C showed pyrolysis behavior of surface-reacted species. The relative amount of sp ² bonded carbon decreases with increasing exposure temperature.     

Autoxidation of saturated fatty acids. II. The determination of the site of hydroperoxide groups in autoxidizing methyl palmitate

The monohydroperoxides of methyl palmitate oxidized at 150C were concentrated, purified, and reduced to yield a mixture of isomers of monohydroxy palmitate. No evidence of unsaturation in these molecules could be obtained, and no direct method for the resolution or identification of the individual isomers was found. Nuclear magnetic resonance (NMR) spectroscopy of the reduced esters suggested that the hydroxy groups were not located at either end of the chain of the fatty ester. To establish the location of the initial oxidative attack on saturated esters, the reduced esters of oxidized methyl palmitate were chemically cleaved at the location of the hydroxy group by means of chromium trioxide oxidation and by the Beckmann transformation. The resulting mono- and dibasic fatty acids were methylated and analyzed by gas chromatography. This analysis indicated that the oxidation of methyl palmitate did not occur selectively at one location along the ester. Although all carbon atoms can apparently be oxidized, preferential oxidation was observed toward the center of the molecule.     

Mass determination of the fatty acids released from tannin-stimulated rabbit alveolar macrophages

Previous studies with macrophages that had been prelabeled with [¹⁴C]arachidonic acid (20∶4) have shown that condensed tannin is a potent agonist for the release of arachidonic acid. However, it has not been demonstrated that the percentage release of [¹⁴C]20∶4 accurately reflects the metabolic activity of the endogenous 20∶4 pool. In order to measure the 20∶4 mass release relative to the total cellular 20∶4 pool, the free fatty acids of freshly isolated alveolar macrophages were derivatized with a fluorescent reagent, and then separated and quantified by high-performance liquid chromatography. The amounts of esterified fatty acids were measured by gas chromatography of the methyl esters. Free fatty acid levels were compared to those of the total esterified plus unesterified fatty acids to determine the actual percentage released of each fatty acid. Tannin-stimulated release of 20∶4 mass reflected that previously reported for the release of [¹⁴C]20∶4 label but at a slower rate and at a much lower percentage indicating that [¹⁴C]20∶4 had been incorporated into part of a more reactive pool. The specificity of the fatty acid release induced by tannin and β-1,3-glucan, a known agonist for 20∶4 release, was also examined. Both agonists promoted an increase in the levels of free 20∶4 and of other fatty acids. A comparison of the absolute increases of each of the fatty acids indicated that tannin caused a preferential increase in the mass of free 20∶4, whereas β-1,3-glucan evoked a selective increase in the mass of 16∶0. Deceased.     

Activated gas plasma surface treatment of polymers for adhesive bonding

Polyethylene, polypropylene, poly(vinyl fluoride) (Tedlar), polystyrene, nylon 6, poly(ethylene terephthalate) (Mylar), polycarbonate, cellulose acetate butyrate, and a poly(oxymethylene) copolymer were treated with activated helium and with activated oxygen. Mechanical strengths of adhesive-bonded specimens prepared from treated and from untreated coupons were compared. Polyethylene (PE) and polypropylene (PP) showed the greatest increases in bond strength. Oxygen and helium were both effective with polyethylene, but polypropylene showed no improvement when treated with activated helium. The results with excited helium parallel the effects of ionizing radiation on these two polymers, as does the appearance of unsaturation bands in the infrared (965 cm^?1 in PE, and 887 and 910 cm^?1 in PP). Active nitrogen produced excellent bond strength with polyethylene but not with polypropylene. Of the remaining polymers examined, Tedlar, polystyrene, and nylon 6 showed the greatest improvement in bondability after treatment, and Mylar showed moderate improvement. Polycarbonate, cellulose acetate butyrate, and the poly(oxymethylene) copolymer gave approximately two-fold increases in lap-shear bond strength. In several cases, significant differences in response to time of treatment and type of excited gas were found.     

NN-based Prediction Interval for Nonlinear Processes Controller

Neural networks (NNs) are extensively used in modelling, optimization, and control of nonlinear plants. NN-based inverse type point prediction models are commonly used for nonlinear process control. However, prediction errors (root mean square error (RMSE), mean absolute percentage error (MAPE) etc.) significantly increase in the presence of disturbances and uncertainties. In contrast to point forecast, prediction interval (PI)-based forecast bears extra information such as the prediction accuracy. The PI provides tighter upper and lower bounds with considering uncertainties due to the model mismatch and time dependent or time independent noises for a given confidence level. The use of PIs in the NN controller (NNC) as additional inputs can improve the controller performance. In the present work, the PIs are utilized in control applications, in particular PIs are integrated in the NN internal model-based control framework. A PI-based model that developed using lower upper bound estimation method (LUBE) is used as an online estimator of PIs for the proposed PI-based controller (PIC). PIs along with other inputs for a traditional NN are used to train the PIC to predict the control signal. The proposed controller is tested for two case studies. These include, a chemical reactor, which is a continuous stirred tank reactor (case 1) and a numerical nonlinear plant model (case 2). Simulation results reveal that the tracking performance of the proposed controller is superior to the traditional NNC in terms of setpoint tracking and disturbance rejections. More precisely, 36% and 15% improvements can be achieved using the proposed PIC over the NNC in terms of IAE for case 1 and case 2, respectively for setpoint tracking with step changes.