A Brief Survey of our Contribution to Stable Carbene Chemistry

This personal account summarizes our work, beginning with the discovery of the first stable carbene in 1988 up until the recent isolation of mesoionic carbenes. It explains why we have moved our focus from acyclic to cyclic carbenes, and shows that these stable species are not limited to the role of ligand for transition metals, but that they are also powerful agents for the activation of small molecules, and for the stabilization of highly reactive diamagnetic and paramagnetic species.     

A New Traffic Sign Recognition Technique Taking Shuffled Frog-Leaping Algorithm into Account

Everyday humans use cars to move faster, and the world is a chaotic place, and a little distraction or a mistake could be the reason for an accident and bring people great pain. An assistance system that can distinguish and detect signs on the roads and brings the driver's attention to road signs and make them aware of their meaning could be beneficial. The most important part of the Traffic Sign Recognition System is the algorithm. In this paper, a new way toward Traffic Sign Recognition algorithm taking the advantages of Color Segmentation, support vector machines, and histograms of oriented gradients on the GTSRB dataset is proposed. The unsupervised shuffled frog-leaping algorithm is employed for segmenting the images. The results show remarkable improvements by using meta-heuristic algorithms.

     

Slotted ALOHA and CDPA: A comparison of channel accessperformance in cellular systems

The paper compares the performance of two channel-access schemes suitable for the cellular environment, which, in particular, allow the packet capture and can deal with inter-cell interference. The first scheme is the well known S-ALOHA while the second one is the Capture Division Packet Access, recently proposed. The comparison is analytically performed over a common system with a common analytical model. Despite the many analyses appeared on S-ALOHA, the one we develop is new because a throughput density uniformly distributed on the plane is considered in a multiple cell environment. The analysis clearly shows the effect of intra-cell and inter-cell interference on the ALOHA system and quantifies the throughput gain achieved by CDPA, which completely avoids intra-cell interference. Our analysis also provides insight about the effectiveness of power control on both systems. This revised version was published online in July 2006 with corrections to the Cover Date.     

On the impact of physical layer awareness on scheduling and resource allocation in broadband multicellular IEEE 802.16 systems [Radio Resource Management and Protocol Engineering for IEEE 802.16]

Multicellular networks based on the IEEE 802.16 standard appear to be very promising candidates to provide end users with broadband wireless access. However, they also pose interesting challenges in terms of radio resource management, where several design choices are not specified in the standard, intentionally left open to implementors. For this reason, we focus in this article on scheduling and resource allocation, and investigate how they could operate in a cross-layer fashion. In particular, we describe the principles of joint scheduling and resource allocation for IEEE 802.16 operating in AMC mode, and discuss the critical role played by physical layer considerations, especially intercell interference estimation and channel state awareness, in the obtained performance. This leads to identifying key open issues and possible general solutions     

An Investigation of the Electrical Degradation of GaN High-Electron-Mobility Transistors by Numerical Simulations of DC Characteristics and Scattering Parameters

The effects of direct-current (DC) stress on GaN high-electron-mobility transistors (HEMTs) are investigated by means of numerical simulations, by which the creation of an acceptor trap in the AlGaN barrier layer was correlated to the observed experimental degradation. An increase in the trap concentration induces a worsening of the saturated current I _DSS, transconductance g _m, and output conductance g _O. An increase in the length of the trapping region induces a degradation of I _DSS and g _m, but can reduce g _O. Analysis of scattering parameters in the saturation region shows that the cutoff frequency f _T matches the trend of g _m.     

Fiber-optic confocal reflectance microscope with miniature objective for in vivo imaging of human tissues

We have built a fiber-optic confocal reflectance microscope capable of imaging human tissues in near real time. Miniaturization of the objective lens and the mechanical components for positioning and axially scanning the objective enables the device to be used in inner organs of the human body. The lateral resolution is 2 micrometers and axial resolution is 10 micrometers. Confocal images of fixed tissue biopsies and the human lip in vivo have been obtained at 15 frames/s without any fluorescent stains. Both cell morphology and tissue architecture can be appreciated from images obtained with this microscope.     

Optimal design of Service Overlay Networks with economic and performance constraints

In the last years, Service Overlay Networks (SONs) have emerged as a promising means to address some of the issues (e.g. end‐to‐end QoS) affecting the current Internet and to favor the development and deployment of new value‐added Internet services. The deployment of an SON is a capital‐intensive investment, since bandwidth with certain QoS guarantees must be purchased from the individual network domains through bilateral Service Level Agreements. Thus, minimizing the economic cost of the logical end‐to‐end service delivery infrastructure is one of the key objectives for the SON provider. When a SON is aimed at end‐to‐end QoS provisioning, its topology must be designed so as to also satisfy the specific requirements of QoS‐sensitive applications. This paper deals with the problem of planning the SON topology in order to take into account both cost and QoS constraints. More specifically, the paper proposes a set of new algorithms for the design of an optimized SON topology, which minimizes the economic cost while simultaneously meeting bandwidth and delay constraints. A performance comparison among such algorithms is finally carried out. Copyright © 2009 John Wiley & Sons, Ltd.     

Fast-acquisition PLL synthesizer using a parallel N-stage cycleswallower with low power consumption and low phase noise

A phase-locked loop (PLL) frequency synthesizer with an N-stage cycle swallower (NSCS) is one of the fastest frequency switching synthesizers, but the use of the NSCS results in high power consumption and phase noise in the UHF band. This paper elucidates these problems and proposes a fast-acquisition PLL synthesizer using a novel type of NSCS with low power consumption and low phase noise. Experimental results confirm that the use of a parallel NSCS and a prescalar results in greatly reduced power consumption and phase noise     

FIR Laser Lines from CH3OD: A Review

The methanol isotopic species CH₃OD has also proved to be an efficient and powerful medium to generate radiation in the far infrared (FIR) region. After the critical review of 1994, six papers have been published dealing with new FIR laser lines from this molecule. As a consequence of the use of wide tunability waveguide CO₂ lasers as well as a new pulsed CO₂ laser operating at hot and sequential bands, as of optical pumping sources, the total number of the FIR laser lines increased from 122 in 1994 to 227 today. In this communication we present an updated and complete catalogue of FIR laser lines generated from CH₃OD. Information on wavelength, offset, relative polarization, intensity, and optimum operation pressure is generally available.