Optimised immobilisation of microbial lipase on hydrous niobium oxide

The aim of this work was to establish appropriate conditions for immobilising Candida rugosa lipase on a low‐cost inorganic matrix, hydrous niobium oxide, using a multivariate statistical approach. A 2³ full factorial design was employed to determine the effects of support activation with glutaraldehyde (concentration 2.5–4.5%, pH 7–10) and lipase loading (200‐700 U g^?1 matrix) on the hydrolytic and synthetic activities of the immobilised derivatives. From the results the following conditions were established: lipase loading of 450 U g^?1 matrix and niobium oxide activation with glutaraldehyde at a concentration of 2.5% and pH 8. Under these conditions, high activity recovery (47.21%) and esterification yield (86.90%) were attained. The results also show that hydrous niobium oxide can be a valid alternative to replace high‐cost, commercially available inorganic matrices such as controlled pore silica. Copyright © 2006 Society of Chemical Industry     

Treatment of paper and pulp wastewater and removal of odorous compounds by a Fenton‐like process at the pilot scale

A Fenton‐like process, involving oxidation and coagulation, was evaluated for the removal of odorous compounds and treatment of a pulp and paper wastewater. The main parameters that govern the complex reactive system [pH and Fe(III) and hydrogen peroxide concentrations] were studied. Concentrations of Fe(III) between 100 and 1000 mg L^?1 and of H₂O₂ between 0 and 2000 mg L^?1 were chosen. The main mechanism for color removal was coagulation. The maximum COD, color and aromatic compound removals were 75, 98 and 95%, respectively, under optimal operating conditions ([Fe(III)] = 400 mg L^?1; [H₂O₂] = 500–1000 mg L^?1; pH = 2.5; followed by coagulation at pH 5.0). The biodegradability of the wastewater treated increased from 0.4 to 0.7 under optimal conditions and no residual hydrogen peroxide was found after treatment. However, partially or non‐oxidized compounds present in the treated wastewater presented higher acute toxicity to Artemia salina than the untreated wastewater. Based on the optimum conditions, pilot‐scale experiments were conducted and revealed a high efficiency in relation to the mineralization of organic compounds. Terpenes [(1S)‐α‐pinene, β‐pinene, (1R)‐α‐pinene and limonene] were identified in the wastewater and were completely eliminated by the Fenton‐like treatment. Copyright © 2006 Society of Chemical Industry     

Group Cohesiveness, Group-Derived Collective Self-Esteem, Group-Derived Hope, and the Well-Being of Group Therapy Members.

I. D. Yalom's (1995) hypothesis that group therapy cohesiveness is the precursor to the development of group-derived collective self-esteem (CSE), hope for the self (HS), and psychological well-being (personal self-esteem and depression) was tested. Participants were 102 university counseling center group therapy clients from process (n = 54) and theme (n = 48) groups. Path analyses supported Yalom's theory that cohesiveness is the primary group factor and that it directly related to curative group factors such as CSE and HS. Additional path analyses showed that the relationship between group therapy CSE and personal self-esteem was moderated by HS, such that a significant relationship between CSE and personal self-esteem was no longer found once HS was entered into the model. Implications of these findings for research and practice are discussed. (PsycINFO Database Record (c) 2010 APA, all rights reserved)     

DSM-III—R, treatment validity, and functional analysis: Further considerations for school psychologists.

Comments on an article by F. Gresham and K. Gansle (see record 1993-11574-001) on the irrelevance of Diagnostic and Statistical Manual of Mental Disorders-III-Revised (DSM-III-R) for the practice of school psychology, and elaborates on issues surrounding the treatment validity construct. The issues in need of clarification are treatment validity, dimensions of DSM-III—R that would not permit analysis of its treatment utility; concern over whether DSM-III—R is useful in presenting differential treatments as a function of classification; and the manner in which treatments are designed and implemented. Because functional analysis represents an advance in the technology of assessment of academic and behavioral problems in applied and clinical settings, treatment utility has considerable potential in advancing school psychological assessment. (PsycINFO Database Record (c) 2010 APA, all rights reserved)     

Potential of diffuse scatterer interferometry for monitoring CO2 storage sites in European contexts (land cover types)

This article proposes to test the feasibility of long-term surface deformation monitoring based on synthetic aperture radar (SAR) interferometry on carbon dioxide (CO₂) storage sites with land cover representative of potential European injection sites (agricultural or forests with minimum built-up land cover). Because no operational injection site is currently active in Europe, a SAR data set (based on EnviSAT–ASAR spaceborne data) is simulated by combining SAR scenes acquired over a potential future European injection site with deformation measurements from SAR analysis carried out on the In-Salah (Algeria) CO₂ injection demonstrator site. The study shows that under such conditions, both persistent scatterer interferometry (PSI) and diffuse scatterer (DS) interferometry appear insufficient to provide a sufficiently dense measurement network to characterize surface deformation correctly. Alternative solutions, to be investigated in further studies, include the use of data archives with shorter acquisition time spans (e.g. Sentinel-1 data when available) or installation of corner reflectors. The cost of the latter mixed space/ground solution must be evaluated with respect to conventional ground-based measurement methods in the proposed context.     

A numerical model for the oscillation frequency,the amplitude and the phase‐noise of MOS‐current‐mode‐logic ring oscillators

This paper presents a new model for the frequency of oscillation, the oscillation amplitude and the phase‐noise of ring oscillators consisting of MOS‐current‐mode‐logic delay cells. The numerical model has been validated through circuit simulations of oscillators designed with a typical 130 nm CMOS technology. A design flow based on the proposed model and on circuit simulations is presented and applied to cells with active loads. The choice of the cell parameters that minimize phase‐noise and power consumption is addressed. Copyright © 2009 John Wiley & Sons, Ltd.     

An haptic-based immersive environment for shape analysis and modelling

Currently, the design of aesthetic products is a process that requires a set of activities where digital models and physical mockups play a key role. Typically, these are modified (and built) several times before reaching the desired design, increasing the development time and, consequently, the final product cost. In this paper, we present an innovative design environment for computer-aided design (CAD) surface analysis. Our system relies on a direct visuo-haptic display system, which enables users to visualize models using a stereoscopic view, and allows the evaluation of sectional curves using touch. Profile curves are rendered using an haptic device that deforms a plastic strip, thanks to a set of actuators, to reproduce the curvature of the shape co-located with the virtual model. By touching the strip, users are able to evaluate shape characteristics, such as curvature or discontinuities (rendered using sound), and to assess the surface quality. We believe that future computer-aided systems (CAS)/CAD systems based on our approach will contribute in improving the design process at industrial level. Moreover, these will allow companies to reduce the product development time by reducing the number of physical mockups necessary for the product design evaluation and by increasing the quality of the final product, allowing a wider exploration and comparative evaluation of alternatives in the given time.     

On the Convergence of Multicast Games in Directed Networks

We investigate the convergence of the price of anarchy after a limited number of moves in the classical multicast communication game when the underlying communication network is directed. Namely, a subset of nodes of the network are interested in receiving the transmission from a given source node and can share the cost of the used links according to fixed cost sharing methods. At each step, a single receiver is allowed to modify its communication strategy, that is to select a communication path from the source, and assuming a selfish or rational behavior, it will make a best response move, that is it will select a solution yielding the minimum possible payment or shared cost. We determine lower and upper bounds on the price of anarchy, that is the highest possible ratio among the overall cost of the links used by the receivers and the minimum possible cost realizing the required communications, after a limited number of moves under the fundamental Shapley cost sharing method. In particular, assuming that the initial set of connecting paths can be arbitrary, we show an $O(r\sqrt{r})We investigate the convergence of the price of anarchy after a limited number of moves in the classical multicast communication game when the underlying communication network is directed. Namely, a subset of nodes of the network are interested in receiving the transmission from a given source node and can share the cost of the used links according to fixed cost sharing methods. At each step, a single receiver is allowed to modify its communication strategy, that is to select a communication path from the source, and assuming a selfish or rational behavior, it will make a best response move, that is it will select a solution yielding the minimum possible payment or shared cost. We determine lower and upper bounds on the price of anarchy, that is the highest possible ratio among the overall cost of the links used by the receivers and the minimum possible cost realizing the required communications, after a limited number of moves under the fundamental Shapley cost sharing method. In particular, assuming that the initial set of connecting paths can be arbitrary, we show an O(r?r)O(r\sqrt{r}) upper bound on the price of anarchy after 2 rounds, during each of which all the receivers move exactly once, and a matching lower bound, that we also extend to W(r^k?{r})\Omega(r\sqrt[k]{r}) for any number k≥2 rounds, where r is the number of receivers. Similarly, exactly matching upper and lower bounds equal to r are determined for any number of rounds when starting from the empty state in which no path has been selected. Analogous results are obtained also with respect to other three natural cost sharing methods considered in the literature, that is the egalitarian, path-proportional and egalitarian-path proportional ones. Most results are also extended to the undirected case in which the communication links are bidirectional.