Acrylonitrile-based copolymers: Synthesis,characterization, and formation of ultrafiltration membranes utilized for the immobilization of proteins

Various high molecular weight copolymers of acrylonitrile and a vinyl comonomer containing an aryl amine, a pyridine, or an aliphatic hydroxyl group were synthesized via slurry polymerization techniques so as to contain from 1 to 15 mol % functional comonomer. The comonomer content was quantitated by ultraviolet absorbance, base titration of acid polymer salts, and/or relative chemical reactivity with trichloro-s-triazine. Thin films were cast from copolymer solutions, coagulated into unsupported ultrafiltration membrances, and characterized with respect to both water permeability and pore size distribution. Analysis by size exclusion chromatography of the membrane permeate of a pool of dextran fractions yielded a continuous distribution curve for membrane pore size over the range 1.5 to 70 nm. The ultrafiltration membranes were used for protein immobilization after appropriate chemical activation. The three distinct types of functional copolymers gave comparable results for α-chymotrypsin, with protein weight loadings of 6–12% and 40–65% retention of enzymatic specific activity.     

Desire and the couch: Perspectives from both sides of the analytic encounter.

This report summarizes the panel held at the 109th Annual Convention, American Psychological Association, August 26, 2001, San Francisco. The chair was William Glover and the speakers were Samuel Gerson, Karen Maroda, and Andre Patsalides. The invited symposium was directed at discussing different perspectives related to the presence of desire in the analytic process. (PsycINFO Database Record (c) 2010 APA, all rights reserved)     

Effect of the degree of crosslinking on penetrant transport in polystyrene

The effect of the degree of crosslinking of glassy polymers on the transport mechanism of penetrants was investigated using a series of divinyl benzene (DVB)-crosslinked polystyrenes of nominal crosslinking ratio X from 0.001 38 to 0.060 mol DVB/mol styrene. The number average molecular weight between crosslinks, $\text{M}\text{?}{}_{\mathrm{<mtext>c</mtext>}}$, was determined from equilibrium swelling experiments in cyclohexane. Dynamic swelling experiments with cyclohexane at 30°C showed that the mechanism of penetrant transport was anomalous. An overshoot in the penetrant uptake was observed, characteristic of macromolecular relaxations and of changing solubility of the cyclohexane in the continuously swelling polystyrene. Photographs of various samples during the swelling process showed that solvent crazing occurred predominantly in loosely crosslinked samples.     

Compile-time partitioning of iterative parallel loops to reducecache coherency traffic

Adaptive data partitioning (ADP) which reduces the execution time of parallel programs by reducing interprocessor communication for iterative parallel loops is discussed. It is shown that ADP can be integrated into a communication-reducing back end for existing parallelizing compilers or as part of a machine-specific partitioner for parallel programs. A multiprocessor model to analyze program execution factors that lead to interprocessor communication and a model for the iterative parallel loop to quantify communication patterns within a program are defined. A vector notation is chosen to quantify communication across a global data set. Communication parameters are computed by examining the indexes of array accesses and are adjusted to reflect the underlying system architecture by compensating for cache line sizes. These values are used to generate rectangular and hexagonal partitions that reduce interprocessor communication     

Individual differences in self-assessed health: An information-processing investigation of health and illness cognition.

In 2 studies, the relation between measures of self-assessed health (SAH) and automatic processing of health-relevant information was investigated. In Study 1, 84 male and 86 female undergraduate students completed a modified Stroop task. Results indicated that participants with poorer SAH showed enhanced interference effects for illness versus non-illness words. In Study 2, 27 male and 30 female undergraduate students completed a self-referent encoding task. Results offered a conceptual replication and extension of Study 1 by confirming the specificity of the relation between SAH measures and automatic processing of health (vs negative or positive general trait) information. These studies provide evidence that individual differences in SAH are reflected in schematic processing of health-relevant information. (PsycINFO Database Record (c) 2010 APA, all rights reserved)     

Indexing transitional knowledge.

Various indexes have been proposed to mark when a child is on the verge of acquiring new knowledge. This article described a new method for indexing this point of transition, which is based on the specificity of children's verbal explanations. The degree to which children were specific in their verbal explanations was related to whether they benefited from instruction. In particular, children who were vague in their explanations (i.e., less specific) benefited from instruction more than children who were explicit in their explanations (i.e., more specific). This index provides insights into the child's mental state prior to acquiring new knowledge. (PsycINFO Database Record (c) 2010 APA, all rights reserved)     

The dimensions underlying perceived attitudes: Liberalism and concern for traditional values.

Two studies identified and labeled the dimensions that people use to judge others' attitudes. In the 1st study, 50 male and 50 female undergraduates viewed pairs of attitude statements drawn from 1 or 2 large sets. For each pair of statements, Ss judged whether or not a person who agreed with one statement in the pair would be likely to agree with the other. The dimensions of liberalism and traditional values were found to underlie perceived attitudes. Validity was confirmed in a 2nd study with 60 male and 60 female undergraduates who rated the characteristics of hypothetical people who agreed strongly with particular statements. Results suggest that there is a common structure to people's perceptions of others' attitudes. (French abstract) (PsycINFO Database Record (c) 2010 APA, all rights reserved)     

Verbal and spatial working memory in school-age children: Developmental differences in susceptibility to interference.

The development of verbal and spatial working memory was investigated with an interference paradigm. Memory spans were obtained from 3 groups (8-, 10-, and 19-yr olds) under 6 different conditions: Two primary memory tasks (1 verbal, 1 spatial) were administered in isolation and in conjunction with 2 versions of a secondary task. The primary tasks required recalling a series of visually presented digits and recalling the locations of Xs in a series of visually presented grids. The secondary tasks required reporting the color of the stimuli as they were presented using either a verbal or a spatial response. Analyses revealed that all age groups showed domain-specific interference (i.e., interference by a secondary task from the same domain as the primary task), but only the 8-yr-olds also showed nonspecific interference (i.e., interference by a secondary task from a domain different than the primary memory task), suggesting that at least some executive functions do not reach adult levels of efficiency until approximately age 10. (PsycINFO Database Record (c) 2010 APA, all rights reserved)     

Test data compression and test time reduction using an embedded microprocessor

Systems-on-a-chip (SOCs) with many complex intellectual property cores require a large volume of data for manufacturing test. The computing power of the embedded processor in a SOC can be used to test the cores within the chip boundary, reducing the test time and memory requirements. This paper discusses techniques that use the computing power of the embedded processor in a more sophisticated way. The processor can generate and reuse random numbers to construct test patterns and selectively apply only those patterns that contribute to the fault coverage, significantly reducing the pattern generation time, the total number of test applications and, hence, the test time. It can also apply deterministic test patterns that have been compressed using the characteristics of the random patterns as well as those of the deterministic patterns themselves, which leads to high compression of test data. We compare three fast run-length coding schemes which are easily implemented and effective for test-data compression. We also demonstrate the effectiveness of the proposed approach by applying it to some benchmark circuits and by comparing it with other available techniques.